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Full-Text Articles in Physical Sciences and Mathematics

Three-Dimensional-Network Li3v2(Po4) 3/C Composite As High Rate Lithium Ion Battery Cathode Material And Its Compatibility With Ionic Liquid Electrolytes, Jiantie Xu, Shulei Chou, Cuifeng Zhou, Qinfen Gu, Hua-Kun Liu, S X. Dou Mar 2014

Three-Dimensional-Network Li3v2(Po4) 3/C Composite As High Rate Lithium Ion Battery Cathode Material And Its Compatibility With Ionic Liquid Electrolytes, Jiantie Xu, Shulei Chou, Cuifeng Zhou, Qinfen Gu, Hua-Kun Liu, S X. Dou

Shi Xue Dou

A high performance Li3V2(PO4)3 cathode material for lithium ion batteries was synthesized by the microwave-assisted hydrothermal method followed by a post annealing process. The synchrotron X-ray diffraction analysis results confirmed that single-phase Li3V2(PO4)3 with monoclinic structure was obtained. Scanning electron microscope and transmission electron microscope images revealed that the as-prepared Li3V 2(PO4)3 was composed of nanowires and microsized particles. Electrochemical results demonstrated that the Li 3V2(PO4)3 electrode measured at 10 C after 500 cycles can deliver discharge capacities of 85.4 mAh g-1 and 103.4 mAh g-1, with a capacity retention of 99.3% and 95.9%, in the voltage ranges of 3.0-4.3 …


A Study On The Charge-Discharge Mechanism Of Co3o4 As An Anode For The Li Ion Secondary Battery, Yong-Mook Kang, Min-Sang Song, Jin-Ho Kim, Hyun-Seok Kim, Min-Sik Park, Jai-Young Lee, Hua-Kun Liu, S X. Dou Jun 2013

A Study On The Charge-Discharge Mechanism Of Co3o4 As An Anode For The Li Ion Secondary Battery, Yong-Mook Kang, Min-Sang Song, Jin-Ho Kim, Hyun-Seok Kim, Min-Sik Park, Jai-Young Lee, Hua-Kun Liu, S X. Dou

Shi Xue Dou

Co3O4 has shown acceptable electrochemical properties as the anode material of Li secondary batteries. In detail, its capacity reached about 700 mAh/g, twice as high as graphite, and 93.4% of initial capacity was retained after 100 cycles. EIS (electrochemical impedance spectroscopy) analyses revealed that after the 1st cycle, the insertion or extraction of Li ions in Co3O4 can occur homogeneously and reversibly (randless-like behavior, homogeneous mixture: Co + Li2O (in the state of Li insertion), Co3O4 (in the state of Li extraction)). In fact, the coulombic efficiency of Co3O4 was almost 100% except for the 1st cycle. According to P. …


A Battery Composed Of A Polypyrrole Cathode And A Magnesium Alloy Anode-Toward A Bioelectric Battery, Yong Kong, Caiyun Wang, Yang Yang, Chee O. Too, Gordon G. Wallace Mar 2013

A Battery Composed Of A Polypyrrole Cathode And A Magnesium Alloy Anode-Toward A Bioelectric Battery, Yong Kong, Caiyun Wang, Yang Yang, Chee O. Too, Gordon G. Wallace

Gordon Wallace

A bioelectric battery can be implanted into the human body and relies on oxygen in the internal body fluid to produce electrical energy. In this work, a battery that uses polypyrrole doped with a biological polyelectrolyte (dextran sulfate, an anti-coagulant) as the cathode and bioresorbable Mg alloy (AZ61) as the anode was developed. This battery exhibited a discharge capacity of 565 mA h g-1 in phosphate buffered saline (PBS, pH = 7.4), a commonly used electrolyte in biological research; offering a specific energy density of similar to 790W h kg-1. The electrochemical properties of the cathode, anode and battery itself …


All-Polymer Battery System Based On Polypyrrole (Ppy)/Para (Toluene Sulfonic Acid) (Pts) And Polypyrrole (Ppy)/Indigo Carmine (Ic) Free Standing Films, Irin Sultana, Md. Mokhlesur Rahman, Jiazhao Wang, Caiyun Wang, Gordon G. Wallace, Hua-Kun Liu Mar 2013

All-Polymer Battery System Based On Polypyrrole (Ppy)/Para (Toluene Sulfonic Acid) (Pts) And Polypyrrole (Ppy)/Indigo Carmine (Ic) Free Standing Films, Irin Sultana, Md. Mokhlesur Rahman, Jiazhao Wang, Caiyun Wang, Gordon G. Wallace, Hua-Kun Liu

Gordon Wallace

In this study, we introduce a novel all-polymer battery system based on conducting polymer (polypyrrole, PPy) doped with dopants of para (toluene sulfonic acid) (pTS) and indigo carmine (IC), respectively. The performance of the systems consisting of polypyrrole-para (toluene sulfonic acid) (PPy-pTS) as cathode and polypyrrole-indigo carmine (PPy-IC) as anode in conjunction with either a polymer based electrolyte or a commercial organic electrolyte of 1M LiPF6 in a 50:50 (v/v) mixture of ethylene carbonate (EC) and dimethyl carbonate (DMC) was evaluated. In the system, all the free-standing PPy-pTS and PPy-IC films were directly used without needing any metal substrate support …


Paper-Like Free-Standing Polypyrrole And Polypyrrole-Lifepo4 Composite Films For Flexible And Bendable Rechargeable Battery, Jun Chen, Sau Yen Chew, S. Dou, Jiazhao Wang, Guoxiu Wang, Hua Liu, Konstantin Konstantinov, Jian Wu, Shulei Chou Nov 2012

Paper-Like Free-Standing Polypyrrole And Polypyrrole-Lifepo4 Composite Films For Flexible And Bendable Rechargeable Battery, Jun Chen, Sau Yen Chew, S. Dou, Jiazhao Wang, Guoxiu Wang, Hua Liu, Konstantin Konstantinov, Jian Wu, Shulei Chou

Shulei Chou

Highly flexible, paper-like, free-standing polypyrrole and polypyrrole-LiFePO4 composite films were prepared using the electropolymerization method. The films are soft, lightweight, mechanically robust and highly electrically conductivity. The electrochemical performance of the free-standing pure PPy electrode was improved by incorporating the most promising cathode material, LiFePO4, into the PPy films. The cell with PPy-LiFePO4 composite film had a higher discharge capacity beyond 50 cycles (80 mA h/g) than that of the cell with pure PPy (60 mA h/g). The free-standing films can be used as electrode materials to satisfy the new market demand for flexible and bendable batteries that are suitable …


The Impact Of Driving Conditions On Phev Battery Performance, Nathan Christensen, John Patten, Steven Srivastava, Gary P. Nola Nov 2011

The Impact Of Driving Conditions On Phev Battery Performance, Nathan Christensen, John Patten, Steven Srivastava, Gary P. Nola

john a patten

The battery performance of a modified Prius with a 5 kWh plug-in battery was documented for a year to determine the impact of environmental conditions and user attributes on vehicle performance. Both fuel economy and pure electrical efficiency were compared to ambient temperature. The fuel economy has a positive relationship with ambient temperature until approximately 70˚F where the efficiency begins to drop. Electrical performance has a positive linear relationship with ambient temperature. With the emergence of electric vehicles (EVs) and PHEVs from a variety of automotive manufacturers, information on EV and PHEV performance for consumers will become more important.