Physical Sciences and Mathematics Commons^™

A Comparison Of No And N20 Production By The Autophic Nitrifier Nitrosomonas Europaea And The Heterotrophic Nitrifier Alcaligenes Faecalis, Iris C. Anderson, Mark Poth, Julie Homstead, David J. Burdige

OES Faculty Publications

Soil microorganisms are important sources of the nitrogen trace gases NO and N₂O for the atmosphere. Present evidence suggests that autotrophic nitrifiers such as Nitrosomonas europaea are the primary producers of NO and N₂O in aerobic soils, whereas denitrifiers such as Pseudomonas spp. or Alcaligenes spp. are responsible for most of the NO and N₂O emissions from anaerobic soils. It has been shown that Alcaligenes faecalis, a bacterium common in both soil and water, is capable of concomitant heterotrophic nitrification and denitrification. This study was undertaken to determine whether heterotrophic nitrification might be …

Circulation, Fall 1993, Center For Coastal Physical Oceanography, Old Dominion University

CCPO Circulation

Fall 1993 issue of CCPO Circulation featuring article "Palmer Long-Term Ecological Research (LTER)"

Identification And Quantitation Of Volatile Amines In Chesapeake Bay Sediments, Neeraja Y. Krishna

Chemistry & Biochemistry Theses & Dissertations

Sediments from different parts of the Chesapeake Bay were analyzed to determine the presence of volatile amines. A HF-HCl extraction method was used to extract both exchangeable and fixed amines from the sediments and a purge-and-trap technique was used to concentrate the amines. Following derivatization with heptafluorobutyric anhydride (HFBA), the HFBA-amines were analyzed by gas chromatography with electron capture detection and with mass spectrometric detection. One primary amine, i-amylamine with a concentration ranging from 0. 78 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty seven samples collected on three different dates in 1993. Another primary amine, 2-methylbutylamine with a concentration ranging from 0.18 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty three samples collected on three different dates in 1993. A secondary amine, diethylamine was detected but could not be quantified in a total of seven samples collected in September 1993. The concentrations of these amines varied with location in the Bay, depth in the sediment, and time of year the sediments were collected. The origin of i-amylamine and 2-methylbutylamine might be from the biological decarboxylation of amino acids leucine and isoleucine, respectively. The origin of diethylamine is unknown.

Description, Distribution, And Abundance Of The Blue Crab, Callinectes Sapidus (Rathbun), Spawning Stock Of The Lower Chesapeake Bay, Patrick John Geer

OES Theses and Dissertations

The lower Chesapeake Bay spawning stock of the blue crab, Callinectes sapidus, (Rathbun), is examined for seven years (1986 - 1992) in an attempt to better understand stock behavior. Three methods of post-stratification are used to describe the distribution and movement of the population over time. The three methods, density strata, geographic zones, and depth strata, did well in explaining movements of the population, indicating a trend of increased concentration of blue crabs near the eastern Bay late in the spawning season - October. The data suggest a bimodal period of spawning and a trimodal period of abundance. The …

Effect Of Wind Changes During The Last Glacial Maximum On The Circulation In The Southern Ocean, John M. Klinck, David A. Smith

CCPO Publications

Present-day surface wind stress climatology is manipulated to simulate wind conditions during the last glacial maximum. These estimated wind fields force a one-layer, wind-driven numerical model of the southern ocean to determine if a change in the strength of the surface wind stress can shift the location of the Antarctic Polar Front, which is part of the Antarctic Circumpolar Current. A change in the forcing by a factor of 0.5-2.0 results in a change in the speed of the flow by an identical factor with no change in position. However, if the present-day wind climatology is shifted meridionally there is …

Age, Growth, And Mortality Of Atlantic Croaker, Micropogonias Undulatus, In The Chesapeake Bay Region, With A Discussion Of Apparent Geographic Changes In Population Dynamics, Luiz R. Barbieri, Mark E. Chittenden Jr., Cynthia M. Jones

OES Faculty Publications

Atlantic croaker, Micropogonias undulatus, collected from commercial catches in Chesapeake Bay and in Virginia and North Carolina coastal waters during 1988-1991 (n=1,967) were aged from transverse otolith sections. Ages 1-8 were recorded, but eight-year-old fish were rare. Marginal increment analysis showed that for ages 1-7, annuli are formed once a year during the period April-May. Otolith age readings were precise: >99% agreement within and between readers. Observed lengths-at-age were highly variable and growth rate decreased after the first year. Despite the high variability in sizes-at-age, observed lengths for ages 1-7 fit the von Bertalanffy growth model (r2=0.99; n=753) well. …

The Isolation And Identification Of Polyphenolics From Grape Seeds And Their Activity Towards Specific Cell Lines, Joseph A. Reddy

Chemistry & Biochemistry Theses & Dissertations

Grape seed extract is being marketed in France for cardiovascular use and skin care. The active constituents of both these drugs are certain polyphenols called procyanidins. A similar seed extract has now been obtained from Virginia Chardonnay grape seeds. Ten of the major components in this extract have been isolated in their pure form by the semi-preparative HPLC separation on a YMC ODS-AQ (Octadecylsilane-AQ) column. The ODS-Aq column has been shown to have a better resolving capacity compared to the Spherisorb ODS (Octadecylsilane) column previously described in the literature. This has been attributed to the ODSAQ support which has both …

Boundary Value Problems In Rectilinearly Anisotropic Thermoelastic Solids, Gilbert Kerr

Mathematics & Statistics Theses & Dissertations

The boundary value problems which are considered are the type that arise due to the presence of a Griffith crack (or cracks) in an anisotropic thermoelastic solid. The thermoelastic field, in such materials, when the infinitesimal theory is employed, is governed by a set of elliptic partial differential equations. The general solution of these equations is expressed in terms of arbitrary analytic functions whose real parts, in turn, are expressed in terms of Fourier type integrals or Fourier series. Integral transform techniques are then used to determine the stress intensity factors (and other pertinent information) for various crack geometries. In …

Multilevel Parallel Communications, Sanjay Khanna

Computer Science Theses & Dissertations

The research reported in this thesis investigates the use of parallelism at multiple levels to realize high-speed networks that offer advantages in throughput, cost, reliability, and flexibility over alternative approaches. This research specifically considers use of parallelism at two levels: the "upper" level and the "lower" level. At the upper level, N protocol processors perform functions included in the transport and network layers. At the lower level, M channels provide data and physical layer functions. The resulting system provides very high bandwidth to an application. A key concept of this research is the use of replicated channels to provide a …

A Framework For Data Sharing In Computer Supported Cooperative Environments, Mohamed Youssef Eltoweissy

Computer Science Theses & Dissertations

Concurrency control is an indispensable part of any information sharing system. Co-operative work introduces new requirements for concurrency control which cannot be met using existing applications and database management systems developed for non-cooperative environments. The emphasis of concurrency control in conventional database management systems is to keep users and their applications from inadvertently corrupting data rather than support a workgroup develop a product together. This "insular" approach is necessary because applications that access the database have been built with the assumptions that they have exclusive access to the data they manipulate and that users of these applications are generally oblivious …

Production And Decomposition Of Hydrogen Peroxide By Marine Phytoplankton, Dong-Beom Kim

OES Theses and Dissertations

H₂0₂ in seawater has complicated sources and sinks. The relative importance of biological regulation of H₂0₂ compared to other processes is not well understood. In addition, environmental factors affecting the biological regulation of H202 are largely unknown. Marine phytoplankton was examined for the kinetics of the production and decomposition of H₂0₂ in the dark. Effects of varying environmental factors such as light, temperature, salinity, nutrients, amino acids, trace metals and growth phase, were examined. H₂0₂ was determined with the scopoletin-fluorescence decay method.

Five out of 11 species produced …

Real Time Texture Analysis From The Parallel Computation Of Fractal Dimension, Halford I. Hayes Jr.

Computer Science Theses & Dissertations

The discrimination of texture features in an image has many important applications: from detection of man-made objects from a surrounding natural background to identification of cancerous from healthy tissue in X-ray imagery. The fractal structure in an image has been used with success to identify these features but requires unacceptable processing time if executed sequentially.

The paradigm of data parallelism is presented as the best method for applying massively parallel processing to the computation of fractal dimension of an image. With this methodology, and sufficient numbers of processors, this computation can reach real time speeds necessary for many applications. A …

A Study Of The Chlorination Products Of Methionine In Model Solutions And In Wastewater, D. Scott Winters

Chemistry & Biochemistry Theses & Dissertations

Model solutions of the amino acid methionine were chlorinated to seven chlorine-to-nitrogen (Cl₂/N) molar ratios. After 30 minutes, the solutions were analyzed by high performance liquid chromatography (HPLC). At a Cl₂/N molar ratio of 1, methionine sulfoxide was found to be the main product. At Cl₂/N molar ratios ≥ 2, a mixture of methionine sulfoxide, methionine sulfone, an unidentified sulfoxide (product 1), and N-chloro-3-(methylsulfonyl) propionaldimine are formed. These products were identified by comparison to synthesized standards which were characterized by ¹H-NMR and ¹³C-NMR nuclear magnetic resonance spectroscopy, ion trap mass spectroscopy, …

The Biogeochemistry Of Iodine In Seawater, Lingsu Zhang

OES Theses and Dissertations

Iodate and iodide are the two major species of iodine in seawater. In comparison to iodate, iodide is thermodynamically unstable in oxic seawater. The conversion (or reduction) of iodate to iodide may be mediated via biological activities. Since biological activities vary with the season, the conversion of iodate to iodide may also vary seasonally. The conversion (or oxidation) of iodide to iodate is thermodynamically feasible, but the mechanism is poorly known. Hydrogen peroxide, which is ubiquitous in surface seawater, may oxidize iodide to iodate.

Water samples were collected in the middle and lower Chesapeake Bay in different seasons between 1990 …

Recognition Of Quadric Surfaces From Range Data: An Analytical Approach, Ivan X. D. D'Cunha

Electrical & Computer Engineering Theses & Dissertations

In this dissertation, a new technique based on analytic geometry for the recognition and description of three-dimensional quadric surfaces from range images is presented. Beginning with the explicit representation of quadrics, a set of ten coefficients are determined for various three-dimensional surfaces. For each quadric surface, a unique set of two-dimensional curves which serve as a feature set is obtained from the various angles at which the object is intersected with a plane. Based on a discriminant method, each of the curves is classified as a parabola, circle, ellipse, hyperbola, or a line. Each quadric surface is shown to be …

The Biogeochemistry Of Hydrogen Sulfide In The Open Ocean, Joël Radford-Knoery

OES Theses and Dissertations

Hydrogen sulfide is a poorly quantified component of the global sulfur cycle. In seawater, its dissolved species (dissolved sulfide) can react with trace metals to form dissolved complexes and insoluble compounds. Therefore, the study of dissolved° sulfide in the open ocean can yield a better understanding of the biogeochemical cycles of sulfur and trace metals.

The biogeochemical cycling of dissolved sulfide was examined using specially developed sampling and analytical methods. In the western North Atlantic and central Equatorial Pacific Oceans, total dissolved sulfide concentrations ranged from /L; they were highest, in the mixed layer and decreased with depth. The depth …

Time-Optimal Algorithms On Meshes With Multiple Broadcasting, Dharmavani Bhagavathi

Computer Science Theses & Dissertations

The mesh-connected computer architecture has emerged as a natural choice for solving a large number of computational tasks in image processing, computational geometry, and computer vision. However, due to its large communication diameter, the mesh tends to be slow when it comes to handling data transfer operations over long distances. In an attempt to overcome this problem, mesh-connected computers have recently been augmented by the addition of various types of bus systems. One such system known as the mesh with multiple broadcasting involves enhancing the mesh architecture by the addition of row and column buses. The mesh with multiple broadcasting …

The Effects Of Electron Radiation On The Glass Transition Temperature Of A Polyetherimide, Kristen Tulloch Kern

Physics Theses & Dissertations

The effects of electron radiation on a polyetherimide (PEI), Ultem*, were investigated. In particular, the changes in the glass transition temperature (T_g) with absorbed radiation dose were studied. The polymer was exposed to mono-energetic beams of 100-keV electrons and 1.0-MeV electrons for doses up to 100 megagray (MGy). Dosimetry for the exposures was based on Monte-Carlo simulations of the transfer of energy from an energetic electron to the polymer and on comparison to Nylon standards. Dynamic mechanical analysis was used to determine the (T_g) for non-exposed PEI and the changes in (T_g) resulting from …

Fast Fourier Transforms On Distributed Memory Parallel Machines, Anshu Dubey

Computer Science Theses & Dissertations

One issue which is central in developing a general purpose subroutine on a distributed memory parallel machine is the data distribution. It is possible that users would like to use the subroutine with different data distributions. Thus there is a need to design algorithms on distributed memory parallel machines which can support a variety of data distributions. In this dissertation we have addressed the problem of developing such algorithms to compute the Discrete Fourier Transform (DFT) of real and complex data. The implementations given in this dissertation work for a class of data distributions commonly encountered in scientific applications, known …

A Performance Prediction Model For A Fault-Tolerant Computer During Recovery And Restoration, Rodrigo A. Obando

Electrical & Computer Engineering Theses & Dissertations

The modeling and design of a fault-tolerant multiprocessor system is addressed in this dissertation. In particular, the behavior of the system during recovery and restoration after a fault has occurred is investigated. Given that a multicomputer system is designed using the Algorithm to Architecture To Mapping Model (ATAMM) model, and that a fault (death of a computing resource) occurs during its normal steady-state operation, a model is presented as a viable research tool for predicting the performance bounds of the system during its recovery and restoration phases. Furthermore, the bounds of the performance behavior of the system during this transient …

Petrology Of A Large Granophyre-Rich Mesozoic Diabase Dike Near Farmville, Virginia, Philip Thomas Rogan

OES Theses and Dissertations

Up to 37% granophyre occurs in the center of a 150m-wide Mesozoic diabase dike near Farmville, Virginia. The exceptional abundance of granophyre compared with other Mesozoic diabase dikes suggests unusual petrogenetic processes are involved in formation of the dike. Petrographic analyses show that granophyre increases from 5-10% near the flanks of the dike to a maximum of 37% in the core of the dike, and that granophyre distribution is approximately symmetrical about the center of the dike. Major and trace element concentrations parallel variations in the modal abundance of granophyre, with SiO₂ , Na₂O and K_{2 …}

Paleobathymetric Interpretation Of Pleistocene Sediments In The South Padre Island Area, Northwestern Gulf Of Mexico, Using Benthic Foraminiferal Morphology, Karen Ianthe Kruebbe-Belwood

OES Theses and Dissertations

This study tested the validity of using intraspecific variation in benthic foraminifera as a means for determining Pleistocene paleobathymetry. Canonical variate analysis was used as a means for determining visually undetectable but statistically significant differences in the morphology of selected species. Two species, Cassidulina subglobosa and Uvigerina peregrina, were collected from Pleistocene well cuttings from the northwest Gulf of Mexico. The canonical analysis involved comparing the intraspecific variation of these Pleistocene species to their counterparts occurring in the modern Gulf of Mexico, where intraspecific variation was previously analyzed and found to be sufficient to allow detection of bathymetric differences …

Paleocene To Miocene Foraminifera From A Well Near Gloucester, Virginia, Nelson Stanley Ford

OES Theses and Dissertations

Lithologic analysis of twenty-one core samples from a well near Gloucester, Virginia, when compared to published descriptions of formations occurring in the study area, indicates the presence of five formations. From oldest to youngest these units are the Aquia (late Paleocene), Nanjemoy (early Eocene), Chickahominy (late Eocene), Old Church (late Oligocene and early Miocene), and Eastover (late Miocene) formations. Comparison of the stratigraphic ranges of key planktic and benthic foraminifera from each of the core samples shows chronological agreement with previously published ages for each of these formations.

Paleoenvironmental analysis of each of the formations in the well is based …

Chlorination Products Of Glycylphenylalanine In Model Solutions And A Wastewater, Daniel J. Keefe

Chemistry & Biochemistry Theses & Dissertations

Model solutions of the dipeptide glycylphenylalanine were chlorinated to five different chlorine-to-amino nitrogen (Cl/N) mole ratios and analyzed after 30 min by high performance liquid chromatography. At mole ratios of ≤ 1, N-chloroglycylphenylalanine (I) appeared to be the only major product. At a mole ratio ≤ 2, N, N-dichloroglycylphenylalanine (II) was the only product. Compound II decomposes in model solutions (t_1/2= 6.4 hr) at pH 7.0 to form a compound tentatively identified as an H-chloroaldimine (III). Compound III in turn decomposes (t_1/2= 36 hr) in model solutions at pH 7. o to (IV) . From ^{13 …}

Lithofacies Of The Pliocene-Pleistocene Lucayan Limestone, Great Abaco Island, Little Bahama Bank, Mary K. Mullen

OES Theses and Dissertations

Petrographic and sedimentologic analyses of eleven shallow subsurface cores (3 to 19 meters in length) from the Lucayan Limestone where it occurs along northeastern Great Abaco Island (little Bahama Bank) are used to delineate five carbonate lithofacies. The most prevalent lithofacies is a mottled, nonskeletal, peloidal packstone to grainstone. Other lithofacies include a rudstone, a laminated nonskeletal grainstone, a crossbedded grainstone and a mudstone-wackestone.

Cementation varies from poor to very well cemented core intervals. Cements observed included equant granular, equant blocky, drusy, meniscus, and needle fiber "whisker" cements. These cements reflect a variety of diagenetic environments such as the vadose, …

Recent Benthic Foraminifera, Petrology, And Implications For Recent Transport In Wilmington And South Heyes Submarine Canyons, U.S. Atlantic Continental Margin, Jason James Lundquist

OES Theses and Dissertations

Two hundred and forty-six species of benthic foraminifera have been recognized in fourteen short cores (≤ 24cm) taken from within the Wilmington and South Heyes submarine canyons along the slope and rise of the United States Atlantic Continental Margin. Of these one hundred and forty-five species were identified to the species level, thirty were closely related to known species, sixty-six could not be assigned specific names, and five species were of uncertain generic placement. The petrologic character of the sediments was determined for each of the seventy-eight micropaleontogical samples.

Cluster analysis of benthic foraminiferal data identified twelve groups which, together …

Modeling Nutrient And Plankton Processes In The California Coastal Transition Zone, John Roland Moisan

OES Theses and Dissertations

Two time- and space-dependent, physical-bio-optical models have been developed for the California Coastal Transition Zone (CTZ) region with the overall objective of understanding and quantifying the processes th at contribute to the spatial and temporal development of nutrient and plankton distributions in the CTZ. The first of these models considers only time- and vertical processes at specific locations in the CTZ. The model food web components include: silicate, nitrate, ammonium, two phytoplankton size fractions, copepods, doliolids, euphausiids and a detritus pool. The wavelength dependent attenuation of the subsurface irradiance field, due to sea water, phytoplankton pigment concentrations and dissolved organic …

Measurement Of The Casimir-Polder Force, C. I. Sukenik, M. G. Boshier, S. Cho, V. Sandoghdar, E. A. Hinds

Physics Faculty Publications

The authors have studied the deflection of ground-state sodium atoms passing through a micron-sized parallel-plate cavity by measuring the intensity of a sodium atomic beam transmitted through the cavity as a function of cavity plate separation. This experiment provides clear evidence for the existence of the Casimir-Polder force, which is due to modification of the ground-state Lamb shift in the confined space of a cavity. The results confirm the magnitude of the force and the distance dependence predicted by quantum electrodynamics.

A Comparison Of Gulf Stream Sea Surface Height Fields Derived From Geosat Altimeter Data And Those Derived From Sea Surface Temperature Data, Tal Ezer, George L. Mellor, Dong-Shan Ko, Ziv Sirkes

CCPO Publications

Two types of satellite data, Geosat altimeter data and sea surface temperature data (SST), are compared and evaluated for their usefulness in assimilation into a numerical model of the Gulf Stream region. Synoptic sea surface height (SSH) fields are derived from the SST data in the following way: first three-dimensional temperature and salinity analysis fields are obtained through the Optimum Thermal Interpolation System (OTIS), and then SSH fields are calculated using a primitive equation, free-surface, numerical model running in a diagnostic mode. The aforementioned SSH fields are compared with SSH fields obtained from the Geosat altimeter data. Use of Geosat …

A Comparison Of Queueing, Cluster And Distributed Computing Systems, Joseph A. Kaplan, Michael L. Nelson

Computer Science Faculty Publications

Using workstation clusters for distributed computing has become popular with the proliferation of inexpensive, powerful workstations. Workstation clusters offer both a cost effective alternative to batch processing and an easy entry into parallel computing. However, a number of workstations on a network does not constitute a cluster. Cluster management software is necessary to harness the collective computing power. A variety of cluster management and queuing systems are compared: Distributed Queueing Systems (DQS), Condor, Load Leveler, Load Balancer, Load Sharing Facility (LSF - formerly Utopia), Distributed Job Manager (DJM), Computing in Distributed Networked Environments (CODINE), and NQS/Exec. The systems differ in …