Physical Sciences and Mathematics Commons^™

Wicked Ideas For Wicked Problems: Marine Debris And The Complexity Of Governance, Dawn Helene Driesbach

Graduate Program in International Studies Theses & Dissertations

Myriad challenges regarding earth's common spaces, those unregulated by sovereign state authorities, mount and intensify as resources diminish and competition for commercial, scientific and security advantages increases; the pollution and degradation of those spaces simultaneously expands. Threats to the global commons complicate efforts to achieve international consensus which impedes attempts to develop effective governance. As an example, marine debris is a growing problem and is an existential threat to the global commons.

This dissertation aims to characterize marine debris as a wicked problem and explores the complexity of governance in the global ocean commons by answering two fundamental questions. Under …

Constraining Respired Carbon Storage In The Eastern Tropical Pacific Over The Last 25 Thousand Years Using Benthic Foraminiferal Boron/Calcium Ratios, Brian James Close

OES Theses and Dissertations

The storage of inorganic carbon in the deep Pacific Ocean is thought to play an important role in regulating both glacial-interglacial and millennial-scale atmospheric CO₂ concentrations (Broecker and Barker 2007; Sigman et al., 2010). A recent study by Loveley et al. (2017) showed that sedimentary authigenic uranium (aU) concentrations, a proxy for suboxic bottom-water conditions, increased significantly in the Eastern Equatorial Pacific (EEP) during the Last Glacial Maximum (LGM, 18 kyr – 23 kyr). If this is correct, the low-oxygen, CO_2-rich waters would also have a lower pH and a lower carbonate ion concentration ([CO₃^{2- …}

Deeply Virtual Compton Scattering At Hall A, Jefferson Lab, Mohamed Nuhman Hashir Rashad

Physics Theses & Dissertations

The Standard Model of particle physics defines quarks and leptons as the basic building blocks of all matter. The interaction between them are mediated by force carrying gauge bosons. Quantum ChromoDynamics (QCD), the theory that explains the strong interaction is still not complete enough to derive the physical observables of a Quark-Gluon system from the fundamental degrees of freedom of it’s constituents. Experimentally observable single particle densities provide important insights into our understanding of the quark-gluon system and hence help fill in the gaps of QCD. Generalized Parton Distributions (GPDs) provide simultaneous information of both spacial and longitudinal momentum distributions …

Enhanced Traffic Incident Analysis With Advanced Machine Learning Algorithms, Zhenyu Wang

Computational Modeling & Simulation Engineering Theses & Dissertations

Traffic incident analysis is a crucial task in traffic management centers (TMCs) that typically manage many highways with limited staff and resources. An effective automatic incident analysis approach that can report abnormal events timely and accurately will benefit TMCs in optimizing the use of limited incident response and management resources. During the past decades, significant efforts have been made by researchers towards the development of data-driven approaches for incident analysis. Nevertheless, many developed approaches have shown limited success in the field. This is largely attributed to the long detection time (i.e., waiting for overwhelmed upstream detection stations; meanwhile, downstream stations …

Onboard Autonomous Controllability Assessment For Fixed Wing Suavs, Brian Edward Duvall

Mechanical & Aerospace Engineering Theses & Dissertations

Traditionally fixed-wing small Unmanned Arial Vehicles (sUAV) are flown while in direct line of sight with commands from a remote operator. However, this is changing with the increased popularity and ready availability of low-cost flight controllers. Flight controllers provide fixed-wing sUAVs with functions that either minimize or eliminate the need for a remote operator. Since the remote operator is no longer controlling the sUAV, it is impossible to determine if the fixed-wing sUAV has proper control authority. In this work, a controllability detection system was designed, built, and flight-tested using COTS hardware. The method features in-situ measurement and analysis of …

Parallelization Of The Advancing Front Local Reconnection Mesh Generation Software Using A Pseudo-Constrained Parallel Data Refinement Method, Kevin Mark Garner Jr.

Computer Science Theses & Dissertations

Preliminary results of a long-term project entailing the parallelization of an industrial strength sequential mesh generator, called Advancing Front Local Reconnection (AFLR), are presented. AFLR has been under development for the last 25 years at the NSF/ERC center at Mississippi State University. The parallel procedure that is presented is called Pseudo-constrained (PsC) Parallel Data Refinement (PDR) and consists of the following steps: (i) use an octree data-decomposition scheme to divide the original geometry into subdomains (octree leaves), (ii) refine each subdomain with the proper adjustments of its neighbors using the given refinement code, and (iii) combine all subdomain data into …

Not Too Hot, Not Too Cold, But Moderately Variable: The Influence Of Environmental Variability On Coral Thermal Tolerance, Courtney Nicole Klepac

Biological Sciences Theses & Dissertations

Anthropogenic climate change is causing an increase in the frequency and severity of marine heat waves, resulting in declining health of coral reef ecosystems worldwide. Coral bleaching events – the breakdown in symbiosis between the coral host and their intracellular photosynthetic algae – are increasingly common in recent years and contribute to widespread losses in coral cover. However, bleaching and heat stress responses vary across spatial scales both within and among coral species. Coral populations native to highly variable environments can have greater bleaching resistance than corals from more stable habitats and corals transplanted into these variable reef sites can …

Climate Change Games As Boundary Objects: Fostering Dialogic Communication Within Stakeholder Engagement, Megan L. Mckittrick

English Theses & Dissertations

Rising waters and the increasing devastation of flood events make coastal resilience a significant issue in the Hampton Roads region of Virginia, particularly in the city of Norfolk. Enhancing resilience requires ongoing stakeholder engagement designed to invite dialogue while encouraging cross-jurisdictional collaboration and comprehensive problem-solving. Climate change games have been employed to support these endeavors. This dissertation provides a response to the following research questions: 1) What is the origin of the climate change game genre? 2) Why are key stakeholders in coastal resilience using climate change games? And 3) how do these games operate for these key stakeholders? To …

Assessment Of Factors Influencing Migratory Landbird Use Of Forested Stopover Sites Along The Delmarva Peninsula During Autumn Migration, J. Andrew Arnold

Biological Sciences Theses & Dissertations

Autumn migration is a time when billions of birds move from breeding grounds in North America to wintering grounds in Central and South America, with many individuals relying on stopover habitats en route for resting and refueling purposes. These stopover sites are critical to the survival of the hundreds of species of migratory landbirds that migrate annually, and thus identifying important stopover sites is a high priority for conserving such taxa. The Delmarva Peninsula; a coastal region of Delaware, Maryland, and Virginia along the mid-Atlantic flyway; consists of forested habitats with ample food and shelter that likely serves as quality …

In The Margins: Reconsidering The Range And Contribution Of Diazotrophs In Nearshore Environments, Corday R. Selden

OES Theses and Dissertations

Dinitrogen (N₂) fixation enables primary production and, consequently, carbon dioxide drawdown in nitrogen (N) limited marine systems, exerting a powerful influence over the coupled carbon and N cycles. Our understanding of the environmental factors regulating its distribution and magnitude are largely based on the range and sensitivity of one genus, Trichodesmium. However, recent work suggests that the niche preferences of distinct diazotrophic (N₂ fixing) clades differ due to their metabolic and ecological diversity, hampering efforts to close the N budget and model N₂ fixation accurately. Here, I explore the range of N₂ fixation …

Synthesis, Characterization, Spectroscopic, And Mesomorphic Studies Of New Schiff Base Ligands And Titanium, Cobalt, Nickel And Copper Metal Centers, Raj K. Gurung

Chemistry & Biochemistry Theses & Dissertations

Transition metal complexes with Schiff base ligands offer a wide application in the field of development of catalysis and material. The straightforward synthesis allowed the structural modification and helped to optimize in various application of such complexes. Titanium-containing complexes have been reported to be important for their catalytic and material applications through the coordination of a tetradentate Schiff base ligand, viz. N, N’-ethylene bis(salicylideneiminate) dianion (salen). Studies reporting the characterization of achiral titanium(IV) salen complexes are scarce due to their intricate nature. Such complexes would be comparatively less expensive and easier to prepare synthetically and thus could represent an …

The Effects Of Security Framing, Time Pressure, And Brand Familiarity On Risky Mobile Application Downloads, Cody Parker

Psychology Theses & Dissertations

The current study examined the effects of security system framing, time pressure, and brand familiarity on mobile application download behaviors, with an emphasis on risk taking. According to the Prospect Theory, people tend to engage in irrational decision making, and make qualitatively different decisions when information is framed in terms of gains and losses (i.e., the framing effect). Past research has used this framing effect to guide the design of a risk display for mobile applications (apps), with the purpose of communicating the potential risks and minimizing insecure app selections. Time pressure has been shown to influence the framing effect …

Measurement Of Pion-Pion Final State Interactions In Η → Π +Π −Γ With Clas At Jefferson Lab, Torri C. Jeske

Physics Theses & Dissertations

Decays of pseudoscalar mesons proceed from the chiral anomaly, which arises from spontaneous chiral symmetry breaking. In the limit of massless quarks (chiral limit), the η → π +π −γ the decay width is determined solely by the box anomaly term in the Wess Zumino Witten Lagrangian. Since the physical quarks are not massless, the decay region of the η meson is far from the chiral limit and thus proper inclusion of the momentum dependence is essential to reproduce the measured decay width. Several theoretical frameworks have been proposed to describe these interactions. We report a new measurement of the …

Conical Orbital Mechanics: A Rework Of Classic Orbit Transfer Mechanics, Cian Anthony Branco

Mechanical & Aerospace Engineering Theses & Dissertations

Simple orbital maneuvers obeying Kepler’s Laws, when taken with respect to Newton’s framework, require considerable time and effort to interpret and understand. Instead of a purely mathematical approach relying on the governing relations, a graphical geometric conceptual representation provides a useful alternative to the physical realities of orbits. Conic sections utilized within the full scope of a modified cone (frustum) were employed to demonstrate and develop a geometric approach to elliptical orbit transformations. The geometric model in-question utilizes the rotation of a plane intersecting the orbital frustum at some angle β (and the change in this angle) in a novel …

Synthesis, Characterization, And Kinetics Studies Of New Cobalt Complexes For The Production Of H2 In Acidic Media, Michael John Celestine

Chemistry & Biochemistry Theses & Dissertations

The kinetics and mechanism of the oxidation of [Co(dmgBF₂)₂(OH₂)₂] (where dmgBF₂ = difluoroboryldimethylglyoximato) by sodium hypochlorite (NaOCl), sodium bromate (NaBrO₃), and bromine (Br₂₎ was investigated by stopped-flow spectrophotometry at 450 nm over a wide temperature range. The pK_a1 value for [Co(dmgBF₂)₂(OH₂)₂] was calculated as 5.27 ± 0.14 at I = 0.60 (NaCl). From the variation in pH studies, the activation parameters were derived from the proposed mechanisms for NaOCl, ΔH_1*, ΔH_2*, ΔS_1*, and …

Mementomap: A Web Archive Profiling Framework For Efficient Memento Routing, Sawood Alam

Computer Science Theses & Dissertations

With the proliferation of public web archives, it is becoming more important to better profile their contents, both to understand their immense holdings as well as to support routing of requests in Memento aggregators. A memento is a past version of a web page and a Memento aggregator is a tool or service that aggregates mementos from many different web archives. To save resources, the Memento aggregator should only poll the archives that are likely to have a copy of the requested Uniform Resource Identifier (URI). Using the Crawler Index (CDX), we generate profiles of the archives that summarize their …

Sodium-Calcium Ratios In The Planktic Foraminifera Trilobatus Sacculifer As A Proxy For Sea Surface Salinity, Colton Steele Watkins

OES Theses and Dissertations

Recent culture and field studies have found a significant positive correlation between seawater salinity and the incorporation of sodium into foraminiferal calcite, suggesting a potential new proxy for reconstructing past changes in sea surface salinity (SSS) (Mezger et al., 2016 and Bertlich et al., 2018). In order to test the applicability of this new proxy in an open-ocean setting, Na/Ca ratios in the planktic foraminifera Trilobatus sacculifer (T. sacculifer Na/Ca) were measured from a suite of sediment core tops spanning a natural salinity gradient from the North Atlantic subtropical gyre to the South Atlantic subtropical gyre. Initial results from …

Global Conservation Status Of Croaker And Drum (Family: Sciaenidae) And Role Of The Maw Trade, Claire E. Gorman

Biological Sciences Theses & Dissertations

Understanding threats and drivers of extinction risk is critical to conserving marine biodiversity. Although marine bony fishes are some of the most diverse and abundant vertebrates in the world, overexploitation is the major threat to these taxa. Species in the family Sciaenidae are important marine resources in many parts of the world, supporting small- and large-scale fisheries for consumption and the international maw (dried swimbladder) trade. Sciaenids exhibit a diverse array of life history characteristics, such as high fecundity, large body size, formation of spawning aggregations, and longevity. Some characteristics increase their susceptibility to anthropogenic stressors. Despite being ecologically and …

Advances In The Understanding Of Sourcing And Fate Of Pyrogenic Organic Matter In The Environment, Aleksandar Ivaylov Goranov

Chemistry & Biochemistry Theses & Dissertations

With higher occurrences of forest fires worldwide, there has been an increase in scientific interest surrounding the chemistry of pyrogenic organic matter (pyOM). The main structural components of pyOM, the condensed aromatic compounds (ConAC), exhibit intriguing physico-chemical properties and have been one of the main focuses of biogeochemical research. The overwhelmingly large number of scientific articles regarding pyOM and ConAC are guided by the assumption that ConAC in the environment are exclusively of pyrogenic origin, even though some recent studies have suggested that some of these ConAC could also be derived from non-pyrogenic radical-driven processes. To evaluate this controversial proposition, …

Synthesis And Characterization Of Carbohydrate Based Molecular Gelators And Macrocycles Through Cycloaddition Reactions, Dan Wang

Chemistry & Biochemistry Theses & Dissertations

Carbohydrate based low molecular weight gelators (LMWGs) are biocompatible and have many potential applications. They have been used for drug delivery, environmental clean-up, and for reaction catalysis. In recent years, copper catalyzed azide alkyne cycloaddition reactions (CuAACs) also termed “Click reactions” have shown great applications in the synthesis of various glycoconjugates and carbohydrate derivatives.

In this research, three diverse classes of glycoconjugates (I, II, III) have been designed and synthesized. The first class of compounds (I) in Chapter 2 are D-glucosamine based amide and triazole derivatives with different spacers between the amide and triazole (n=2-5) function groups. These compounds were …

Inference And Estimation In Change Point Models For Censored Data, Kristine Gierz

Mathematics & Statistics Theses & Dissertations

In general, the change point problem considers inference of a change in distribution for a set of time-ordered observations. This has applications in a large variety of fields and can also apply to survival data. With improvements to medical diagnoses and treatments, incidences and mortality rates have changed. However, the most commonly used analysis methods do not account for such distributional changes. In survival analysis, change point problems can concern a shift in a distribution for a set of time-ordered observations, potentially under censoring or truncation.

In this dissertation, we first propose a sequential testing approach for detecting multiple change …

Deep Learning For Remote Sensing Image Processing, Yan Lu

Computational Modeling & Simulation Engineering Theses & Dissertations

Remote sensing images have many applications such as ground object detection, environmental change monitoring, urban growth monitoring and natural disaster damage assessment. As of 2019, there were roughly 700 satellites listing “earth observation” as their primary application. Both spatial and temporal resolutions of satellite images have improved consistently in recent years and provided opportunities in resolving fine details on the Earth's surface. In the past decade, deep learning techniques have revolutionized many applications in the field of computer vision but have not fully been explored in remote sensing image processing. In this dissertation, several state-of-the-art deep learning models have been …

Towards Dynamic Vehicular Clouds, Aida Ghazizadeh

Computer Science Theses & Dissertations

Motivated by the success of the conventional cloud computing, Vehicular Clouds were introduced as a group of vehicles whose corporate computing, sensing, communication, and physical resources can be coordinated and dynamically allocated to authorized users. One of the attributes that set Vehicular Clouds apart from conventional clouds is resource volatility. As vehicles enter and leave the cloud, new computing resources become available while others depart, creating a volatile environment where the task of reasoning about fundamental performance metrics becomes very challenging. The goal of this thesis is to design an architecture and model for a dynamic Vehicular Cloud built on …

Simulation And Development Of The Radial Time Projection Chamber For The Bonus12 Experiment In Clas12, Nathan M. Dzbenski

Physics Theses & Dissertations

Knowledge of the structure of nucleons (i:e: protons and neutrons) is a central topic of interest to nuclear/particle physicists. Much more is known about the structure of the proton than the neutron due to the lack of high-density free neutron targets. The Barely Off-shell Nucleon Structure experiment (BONuS12) at Jefferson Lab (JLab) is a second generation experiment upgraded/optimized to advance our knowledge of the neutron's structure using the deep-inelastic scattering of electrons off deuterium. Typically, since deuterium is a nuclear target, corrections for off-shell and nuclear binding effects must be taken into account in order to extract results on the …

Structural Characterization Of Organic Matter In Oil Shales Using Multiple Nuclear Magnetic Resonance Spectroscopic Techniques, Wenying Chu

Chemistry & Biochemistry Theses & Dissertations

Oil shale is a promising source of hydrocarbon fuel that is distributed throughout the world. The petroleum generating potential of oil shale is related to the molecular structure of the organic matter in source rock. The major fraction of organic matter of oil shale is termed kerogen, and due to its insolubility in organic solvents, ¹³C solid-state nuclear magnetic resonance (NMR) spectroscopy is one of the best ways to directly measure the insoluble organic matter without changing its chemical structures. This dissertation investigated oil shale samples using advanced solid-state ¹³C NMR spectroscopy techniques and high resolution magic angle …

Secure Mobile Computing By Using Convolutional And Capsule Deep Neural Networks, Rui Ning

Electrical & Computer Engineering Theses & Dissertations

Mobile devices are becoming smarter to satisfy modern user's increasing needs better, which is achieved by equipping divers of sensors and integrating the most cutting-edge Deep Learning (DL) techniques. As a sophisticated system, it is often vulnerable to multiple attacks (side-channel attacks, neural backdoor, etc.). This dissertation proposes solutions to maintain the cyber-hygiene of the DL-Based smartphone system by exploring possible vulnerabilities and developing countermeasures.

First, I actively explore possible vulnerabilities on the DL-Based smartphone system to develop proactive defense mechanisms. I discover a new side-channel attack on smartphones using the unrestricted magnetic sensor data. I demonstrate that attackers can …

Automatic Linear And Curvilinear Mesh Generation Driven By Validity Fidelity And Topological Guarantees, Jing Xu

Computer Science Theses & Dissertations

Image-based geometric modeling and mesh generation play a critical role in computational biology and medicine. In this dissertation, a comprehensive computational framework for both guaranteed quality linear and high-order automatic mesh generation is presented. Starting from segmented images, a quality 2D/3D linear mesh is constructed. The boundary of the constructed mesh is proved to be homeomorphic to the object surface. In addition, a guaranteed dihedral angle bound of up to 19:47^o for the output tetrahedra is provided. Moreover, user-specified guaranteed bounds on the distance between the boundaries of the mesh and the boundaries of the materials are allowed. The …

Innovative Approaches In The Discovery Of Aquatic Mycobacteriophages, Janis H. Doss

Biomedical Sciences Theses & Dissertations

Bacteriophages (phages), viruses that infect bacteria, have many applications in medicine, agriculture, molecular biology, and other fields. As antibiotic resistance becomes an increasing problem, interest in phages has grown. The traditional techniques of phage discovery are successful for some phages, but others require modified procedures to achieve detectable host infection.

Mycobacterium is a diverse bacterial genus characterized by a unique cell wall containing mycolic acids, which aids in survival and pathogenesis. The aims of the present research were to isolate mycobacteriophages, use bioinformatics techniques to analyze mycobacterial prophages, and combine genetic analysis with multi-well plate host range studies to identify …

A Framework For Verifying The Fixity Of Archived Web Resources, Mohamed Aturban

Computer Science Theses & Dissertations

The number of public and private web archives has increased, and we implicitly trust content delivered by these archives. Fixity is checked to ensure that an archived resource has remained unaltered (i.e., fixed) since the time it was captured. Currently, end users do not have the ability to easily verify the fixity of content preserved in web archives. For instance, if a web page is archived in 1999 and replayed in 2019, how do we know that it has not been tampered with during those 20 years? In order for the users of web archives to verify that archived web …

Bootstrapping Web Archive Collections From Micro-Collections In Social Media, Alexander C. Nwala

Computer Science Theses & Dissertations

In a Web plagued by disappearing resources, Web archive collections provide a valuable means of preserving Web resources important to the study of past events. These archived collections start with seed URIs (Uniform Resource Identifiers) hand-selected by curators. Curators produce high quality seeds by removing non-relevant URIs and adding URIs from credible and authoritative sources, but this ability comes at a cost: it is time consuming to collect these seeds. The result of this is a shortage of curators, a lack of Web archive collections for various important news events, and a need for an automatic system for generating seeds. …