Physical Sciences and Mathematics Commons^™

Preliminary Model Development Of Metal Complexation Of Polyester Derivatives Of 2,2'-Biimidazole, Shelonda Rena Taylor Finch

Doctoral Dissertations

"The objective of this study was to develop a chemical model for metal ion complex formation by a macroligand system with multi-metal binding sites using 2,2'-biimidazole as the starting molecule of the ligand system. Prior studies in this laboratory guided the selection of diesters and hydroxyethyl derivatives of 2,2'-biimidazole as model monomers. In addition, metal ion complexation studies with 2,2'-biimidazole derivatives were conducted. As a result, crystal structures of 1,1'-di(methylpropionato)-2,2-biimidazole, 2,2'-bis(1H-imidazolium) dinitrate and silver 2,2'-bis(1H-imidazolium) trinitrate, were reported. The crystal structures indicated a dependence upon the binding ability of the protonated 2,2'-biimidazole and counter ions. transesterification of the diesters and …

Quantum Phase Transitions In The Presence Of Disorder And Dissipation, Chetan Kotabage

Doctoral Dissertations

"A quantum phase transition is a phase transition at absolute zero occurring under variations in an external non-thermal parameter such as magnetic field or pressure. Quantum phase transitions are one among the important topics currently investigated in condensed matter physics. They are observed in various systems, e.g., in the ferromagnetic-paramagnetic phase transition in LiHoF₄ or in the superconductor-metal phase transition in nanowires.

A particular class of quantum phase transitions, which is phase transitions in the presence of disorder and dissipation, is investigated here. An example of this class is the ferromagnetic-paramagnetic phase transition in Ni₁₋ₓVₓ or CePd_1-xRhₓ caused …

Quantum Electrodynamics And Fundamental Constants, Benedikt J. Wundt

Doctoral Dissertations

"The unprecedented precision achieved both in the experimental measurements as well as in the theoretical description of atomic bound states make them an ideal study object for fundamental physics and the determination of fundamental constants. This requires a careful study of the effects from quantum electrodynamics (QED) on the interaction between the electron and the nucleus.

The two theoretical approaches for the evaluation of QED corrections are presented and discussed. Due to the presence of two energy scales from the binding potential and the radiation field, an overlapping parameter has to be used in both the approaches in order to …

Ceeme: Compensating Events Based Execution Monitoring Enforcement For Cyber-Physical Systems, Thoshitha T. Gamage

Doctoral Dissertations

"Fundamentally, inherently observable events in Cyber-Physical Systems with tight coupling between cyber and physical components can result in a confidentiality violation. By observing how the physical elements react to cyber commands, adversaries can identify critical links in the system and force the cyber control algorithm to make erroneous decisions. Thus, there is a propensity for a breach in confidentiality leading to further attacks on availability or integrity. Due to the highly integrated nature of Cyber-Physical Systems, it is also extremely difficult to map the system semantics into a security framework under existing security models. The far-reaching objective of this research …

Interfacial Effects On Dielectric Properties Of Polymer-Particle Nanocomposites, Sasidhar Siddabattuni

Doctoral Dissertations

"Dielectric materials that are capable of efficiently storing large amounts of electrical energy are desirable for many electronic and power devices. Since the electrical energy density in a dielectric material is limited to εV_b²/2, where ε is the dielectric permittivity of the material and V_b is the breakdown strength, increased permittivity and breakdown strength are required for large energy storage density. Interfacial effects can influence the dielectric properties, especially dielectric breakdown resistance in polymer-particle nanocomposites. Several functional organophosphates were used to modify the surface of titania and barium titanate nanofiller particles in order to achieve covalent interface …

One Pot Synthesis Of Metal, Carbides And Polymeric Aerogels, Naveen K. Chandrasekaran

Doctoral Dissertations

"Ultra-low density, three-dimensional assemblies of nanoparticles are referred to as aerogels, and typically are derived from supercritical fluid (SCF) drying of wet-gels. Aerogels are generally fragile materials, but that issue has been addressed successfully by X-aerogels, in which the inorganic nanoparticle framework plays the role of the template for the accumulation of polymer that connects covalently and crosslinks the nanoparticles. The resulting materials can be 300x stronger than the native network, for a nominal increase in density by a factor of 3x. Since the exceptional mechanical properties of X-aerogels are traced to the conformal polymer coating, it was reasonable to …

Crustal Structure And Evolution Beneath The Colorado Plateau And The Southern Basin And Range Province, Lamuail Bashir

Doctoral Dissertations

"Stacking of about 15,500 P-to-S receiver functions recorded at 72 USArray and other broadband seismic stations placed on the Colorado Plateau and the SBRP in Arizona revealed systematic spatial variations in crustal Vp/Vs, crustal thickness and amplitude of P-to-S converted phases. Our results reveal that the BRP is characterized by a thin crust (28.2 ± 0.5 km), a mean Vp/Vs of 1.761 ± 0.014 and a mean amplitude (R) of P - to - S converted wave (relative to that of the direct P wave) of 0.181 ± 0.014 that are similar to a typical continental crust, consistent with the …

Modeling Hourly Electricity Prices: A Structural Time Series Approach Incorporating Modified Garch Innovations, Edirisinghe Mudiyanselage Asitha Edirisinghe

Doctoral Dissertations

"The main objective of this research is to develop time series based procedures for modeling day-ahead and real-time hourly electricity prices. Such empirical processes exhibit features that make the direct application of standard time series models infeasible. Four years of hourly day-ahead and real-time electricity price data from the region supplied by the American Electric Power (AEP) company through the PJM Regional Transmission Organization (RTO) and one half years of real-time electricity prices from the MISO RTO are utilized as an empirical basis for developing such procedures. The price data show several features, such as irregular seasonal behavior, weekly and …

Minimal And Near Minimal Congruence Lattice Representations Of Finite Lattices By Finite Algebras On Sets Of Integers, Roger Lee Bunn

Doctoral Dissertations

"We give finite congruence lattice representations of some finite distributive, modular and nonmodular lattices by means of finite algebras on sets of integers. These representations are minimal or near minimal as determined by ρ, a mapping from the class R of finitely representable lattices into the natural numbers N"--Abstract, page iii.

Scattering-Angle Dependence Of Doubly Differential Cross Sections For Fragmentation Of H₂ By Proton Impact, Kisra N. Egodapitiya, Sachin D. Sharma, Aaron C. Laforge, Michael Schulz

Physics Faculty Research & Creative Works

We have measured double differential cross sections (DDCS) for proton fragment formation for fixed projectile energy losses as a function of projectile scattering angle in 75 keV p + H₂ collisions. An oscillating pattern was observed in the angular dependence of the DDCS with a frequency about twice as large as what we found earlier for nondissociative ionization. Possible origins for this frequency doubling are discussed.

Detailed Mapping Of The Local Ir⁴⁺ Dimers Through The Metal-Insulator Transitions Of Cuir₂S₄ Thiospinel By X-Ray Atomic Pair Distribution Function Measurements, Emil S. Bozin, Ahmad S. Masadeh, Yew San Hor, J. F. Mitchell, Simon J. Billinge

Physics Faculty Research & Creative Works

The evolution of the short-range structural signature of the Ir ⁴⁺ dimer state in CuIr₂S₄ thiospinel has been studied across the metal-insulator phase transitions as the metallic state is induced by temperature, Cr doping, and x-ray fluence. An atomic pair distribution function (PDF) approach reveals that there are no local dimers that survive into the metallic phase when this is invoked by temperature and doping. The PDF shows Ir⁴⁺ dimers when they exist, regardless of whether or not they are long-range ordered. At 100 K, exposure to a 98 keV x-ray beam melts the long-range dimer …