Physical Sciences and Mathematics Commons^™

Near-Ir Spectroscopic Analysis Of The Primary Volatile Composition Of Long And Short-Period Comets, Younas Khan

Dissertations

Comets are among the most well-preserved objects that formed in the protosolar nebula ∼4.5 Gyr ago. Hence, they are important for understanding various aspects of the formation, evolution, and habitability of the solar system. Multiple primary volatiles (molecules directly sublimating into the coma from the nucleus) emit via rovibrational transitions in the near-IR, providing opportunities to calculate their abundances. To date, only ∼50 comets have been characterized for their primary volatiles, with the short-period Jupiter-family comets (JFCs) being significantly underrepresented. In contrast, hundreds of comets have been sampled at optical/UV wavelengths, primarily for the composition of daughter species, leading to …

Instrumentation For Routine Analysis Of Acrylamide In French Fries: Assessing Limitations For Adoption, Mark M. Skinner, Jared T. Seale, Maranda S. Cantrell, Joseph M. Collins, Matthew W. Turner, Owen M. Mcdougal

Chemistry and Biochemistry Faculty Publications and Presentations

The purpose of this experimental review was to detect acrylamide in French fries using methods most adaptable to the food process industry for quality control assessment of products. French fries were prepared at different cook times using the same fryer oil over a five-day period to assess the influence of oil degradation and monitor trends in acrylamide formation. Acrylamide detection was performed using LC-MS, GC-MS and FT-NIR. The low levels of acrylamide produced during frying, low molecular weight of the analyte, and complexity of the potato matrix make routine acrylamide measurement challenging in a well-outfitted analytical lab with trained personnel. …

Mapping Gadolinium Contrast In A Complex Ionic And Photosynthesis Environment Of Pineapple By Near-Infrared And X-Ray Imaging, Subhendra Sarkar, Zoya Vinokur, Chen Xu, Tetiana Soloviova, Amina Shahbaz, Aldona Gjoni

Publications and Research

This work explores the diffusivity of a lanthanide complex, Eovist (Gadolinium-Ethoxy Benzyl Diethylenetriamine pentaacetate) that is stable in neutral media but is not in acidic environment. In the current work an acidic fruit model like pineapple that is rich in transition metals was used and a possible transmetallation reaction among Eovist and transition metal complexes was tested using X-ray imaging. Another goal of this work was to perturb the usual and the unusual photosynthesis systems that pineapple has maintained for millions of years during the evolution of circadian genes for efficient water conservation by dark photosynthesis. To detect such photosynthesis …

Understanding Ice Mixtures Under Pluto Simulated Conditions And Their Implications For Geophysical Processes, Caitlin Joannah Ahrens

Graduate Theses and Dissertations

New Horizons at Pluto has given the planetary science community the first images of Pluto’s surface, including geologic wonders and compositional variability. Methane, nitrogen, and carbon monoxide make up the bulk of the volatile plutonian surface along with water ice. In this work, these three main volatiles are specifically investigated in the laboratory setting to understand the spectral properties and behavior of binary and ternary mixtures. The spectra are taken in the near-infrared wavelengths (1 – 2.5 µm) using Fourier transform infrared (FTIR) spectroscopy techniques utilizing the Pluto Simulation Chamber housed at the University of Arkansas, which can reach conditions …

Estimating Δ15n And Δ13c In Barley And Pea Mixtures Using Near-Infrared Spectroscopy With Genetic Algorithm Based Partial Least Squares Regression, Hyo-Won Lee, Hyo-Jin Lee, Han-Jong Ko, Chang Yoon

IGC Proceedings (1997-2023)

Stable isotope measurements have been increasingly used as a method to obtain information on relationships between plants and their environment (Dawson et al., 2002). Stable isotopes are seen as a powerful tool for advancing our knowledge on stock cycling and, nitrogen and carbon isotopic compositions have provided key insights into biogeochemical interactions between plants, soils and the atmosphere (Robinson, 2001). For the stable isotope measurements, the δ¹³C isotopic signature has been used successfully to disentangle physiological, ecological and biogeochemical processes and, δ¹⁵N studies have significantly improved our knowledge on nitrogen cycling pathways and nitrogen acquisition by …

Detecting Special-Cause Variation 'Events' From Process Data Signatures, Timothy M. Young, Olga Khaliukova, Nicolas André, Alexander Petutschnigg, Timothy G. Rials, Chung-Hao Chen

Electrical & Computer Engineering Faculty Publications

The ability to detect the special-cause variation of incoming feedstocks from advanced sensor technology is invaluable to manufacturers. Many on-line sensors produce data signatures that require further off-line statistical processing for interpretation by operational personnel. However, early detection of changes in variation in incoming feedstocks may be imperative to promote early-stage preventive measures. A method is proposed in this applied study for developing control bands to quantify the variation of data signatures in the context of statistical process control (SPC). Control bands based on pointwise prediction intervals constructed from the Bonferroni Inequality and Bayesian smoothing splines are developed. Applications using …

Spectroscopic And Spectro-Astrometric Analysis Of T Tauri Stars, Logan Ryan Brown

Dissertations

To understand our own solar origins, we must investigate the composition of the protoplanetary disk from which the solar system formed. To infer this, we study analogs to the early solar system called T Tauri stars. These objects are low-mass, pre-main sequence stars surrounded by circumstellar disks of material from which planets are believed to form. We present high-resolution, near-infrared spectroscopic data for the T Tauri stars DR Tau and AA Tau using NIRSPEC at the Keck II telescope. For DR Tau, a spectro-astrometric analysis was performed, obtaining sub-seeing spatial information on water emission. Alongside a disk model, we constrained …

Correlation Analysis Between Surface Electromyography And Continuous-Wave Near-Infrared Spectroscopy Parameters During Isometric Exercise To Volitional Fatigue, Ömer Şayli̇, Ata Akin, Hasan Bi̇rol Çotuk

Turkish Journal of Electrical Engineering and Computer Sciences

In this study, the process of muscular fatigue was examined using surface electromyography (sEMG) and continuous-wave near-infrared spectroscopy (cw-NIRS) simultaneously during an isometric hand grip exercise at 50% and 75% of the maximal voluntary contraction (MVC), sustained until volitional fatigue. The mean frequency of the sEMG decreased during the whole exercise, whereas the root mean square had a tendency to increase. Oxyhemoglobin/deoxyhemoglobin concentration changes computed with cw-NIRS were found to exhibit a fast linear decrease/increase in the first 10--20 s of the exercise, the so-called fast phase, followed by a plateau-like slow phase. The change rates were higher at 75% …

Concurrent Neurological And Behavioral Assessment Of Number Line Estimation Performance In Children And Adults, Joseph Michael Baker

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Understanding the brain’s response to common math-learning activities may help improve math education. For example, by imaging the brains of typically developing children and adults throughout a number line estimation task, it is possible to establish a baseline of what “typical” brains do in such situations. Thus, comparisons may be made to determine the degree to which brain functioning differs between typical and atypical math learners. Moreover, by identifying methods that may increase the brain’s response to real-world math activities, it may be possible to improve the math learning process for typical and atypical learners alike.

Brain imaging devices such …