Zebra Limestone From The Gypsum Valley Salt Diapir, Colorado, Rebecca Navarrette

Open Access Theses & Dissertations

Zebra rocks displaying alternating light and dark-colored millimeter to centimeter thick bands of crystals have been found at the Gypsum Valley salt diapir, Colorado in the Paradox Basin where they are associated with gypsic diapiric caprock. Elucidating their origin may provide crucial information about intermittent fluid flow at the margin of salt diapirs and about Zebra rock formation, which often is associated with carbonate-hosted lead-zinc mineralization (Mississippi Valley Type, MVT) and hydrothermal dolomite -hosted hydrocarbon reservoirs.

The Gypsum Valley Zebra rocks consist of calcite, i.e., it is a Zebra limestone. It shows a finely crystalline light banding and coarsely crystalline …

Experimental Study Of The Thermal Cracking Mechanism Of Limestones During Burning, Zhang Weiqiang, Cao Zhicheng, Zhou Qizhong, Wang Zuoquan, Wu Yun

Coal Geology & Exploration

Spontaneous combustion of coal seams will cause different degrees of structural damage to surrounding rocks at different high temperatures, significantly altering their physical and mechanical properties and engineering geological effects. To delve into the structural evolution patterns of rocks during burning, this study investigated the limestones from the floor of a coal mine in Xuzhou. It conducted thermal cracking experiments under different temperatures, exploring the thermal cracking patterns of rocks on multiple scales. Furthermore, this study revealed the genetic mechanism of thermal cracking by combining numerical simulations and microstructure tests. Key findings are as follows: (1) The thermal cracking temperature …

Use Of Carbonation For Treatment Of Coal Mine Drainage To Increase Limestone Dissolution And Generate Alkalinity, Dietrich Henry Kuhlmann Iv

Graduate Theses, Dissertations, and Problem Reports

Abstract

Use of Carbonation for Treatment of Coal Mine Drainage to Increase Limestone Dissolution and Generate Alkalinity

Dietrich Kuhlmann IV

Anoxic limestone drains (ALDs) are a common component used within passive treatment systems for coal mine drainage (CMD). Contact between limestone aggregate and CMD results in limestone dissolution, producing carbonate alkalinity. Though ALDs are one of the least expensive CMD treatment technologies, alkalinity generation is limited by limestone solubility. This necessitates a long retention time (>12 hours) and sometimes results in net acidic effluent which requires additional alkalinity generation steps downstream. One way to increase calcite dissolution and alkalinity …

Investigation Of Thermal Transformation Of Composite Material Obtained From Granite And Recrystallized Limestone Natural Stone Wastes., Gökhan Erol, Devrim Pekdemi̇r

Bulletin of the Mineral Research and Exploration

In this study, the usability of granite (magmatic) and recrystallized limestone (metamorphic) natural stone wastes as alternative raw materials in ceramic tile production was investigated. Based on the CaO, SiO2, and Al2O3 compounds found in waste powders, mixtures containing 65% granite and 35% recrystallized limestone (by mass) were prepared to obtain the ceramic phases of gehlenite, wollastonite and anorthite as a result of thermal transformation. The grain size of both raw materials is -149 μm (d90 = 110.957 μm). The first series samples are called natural building stone (DYT), and the second series samples, in which wood chips of 2% …

The Human Natural Resource Endowment Of Limestone For Cement Manufacturing, Vanya Marie North

Graduate Theses and Dissertations

This study investigates the total per-capita allocation of limestone globally. Termed the Human Natural Resource Endowment (HNRE), it is calculated by subtracting the cumulative annual production from the ultimately recoverable reserve (URR) of limestone and dividing the difference by global population. HNRE represents a unique way of visualizing resource depletion by asking how much of a given resource can be allocated to each person on earth, and how long that allocation can last given multiple population and usage scenarios. The average American, born in 2021, will use approximately 23,930 kgs of cement in their lifetime, with similar demands globally. Demand …

Echoed Sites And The Unknowable Object, Joseph Canizales

MFA in Visual Art

This thesis will discuss the expanded field of sculpture, simulacra, digital technology, and two terms I’ve devised: the unknowable object, and echoed sites. Within these two terms, I’m concerned with the complicated relationship between humans and geology and how we extract material from the ground without reflecting on the geologic history of the site. In echoed sites I create sculptures with and without a geologic site or object, by way of digital technology. These forms display two states paradoxically in balance, where what’s presented leaves more questions than answers. Thus, as part of echoed sites, exists the unknowable object. …

Animal Production From Tropical Pastures Renovated By Subsoiling And Fertilization In The Cerrados Of Brazil, Valéria P. B. Euclides, Manuel C. M. Macedo, M. P. Oliveira

IGC Proceedings (1993-2023)

A grazing trial was conducted, to study the effects of fertilization on the maintenance of the productivity of four tropical grasses. The paddocks were subsoiled, and dived into halves: one (LF1) received 400 kg/ha of a fertilizer formula 0-20-20.and the other (LF2) 800 kg/ha of the same fertilizers, in January 1995. Annually, 50 kg/ha of N was applied. The productivity on LF2 pastures was greater than that on FL1 pastures, averaging 520 and 410 kg of liveweight gain/ha/year. A double strategy should be followed to sustain animal production in the savanna: maintain soil P over a critical value of 3.0 …

The Effect Of H$_{2}$O On The Sulfation Of Havelock Limestone Under Oxy-Fuel Conditions In Athermogravimetric Analyser, Murat Varol, Edward John Anthony, Arturo Macchi

Turkish Journal of Chemistry

A gas mixture representing oxy-fuel combustion conditions was employed in a thermogravimetric analyser to determine the effect of water vapor and SO$_{2}$ concentration on limestone sulfation kinetics over the temperature range of 800 to 920 °C. Here, experiments used small samples of particles (4 mg), with small particle sizes (d$_{p}$ < 38 μm) and large gas flow rates (120 mL/min@ NTP) in order to minimize mass transfer interferences. The gas mixture contained 5000 ppm$_{v}$ SO$_{2}$, 2% O$_{2}$, and the H$_{2}$O content was changed from 0% to 25% with the balance CO$_{2}$. When water vapor was added to the gas mixture at lower temperatures (800-870 °C), the limestone SO$_{2}$ capture efficiency increased. However, as the temperature became higher, the enhancement in total conversion values decreased. As expected, Havelock limestone at higher temperatures (890 °C, 920 °C, and 950 °C) experienced indirect sulfation and reacted at a faster rate than for lower temperatures (800-870 °C) for direct sulfation over the first five minutes of reaction time. However, the total conversion of Havelock limestone for direct sulfation was generally greater than for indirect sulfation.

Destabilizing Effects On A Classic Tri-Trophic Oyster Reef Cascade, Virginia R. Schweiss, Chet F. Rakocinski

Faculty Publications

How interactions among multiple predators affect the stability of trophic cascades is a topic of special ecological interest. To examine factors affecting the stability of the classic tri-trophic oyster reef cascade within a different context, configurations of three predators, including the Gulf toadfish, Gulf stone crab, and oystershell mud crab, were manipulated together with either oyster shell or limestone gravel substrate within a multiple predator effects (MPE) experiment. Additionally, a complimentary set of trait-mediated-indirect interaction (TMII) experiments examined the inhibition of oyster consumption relative to mud-crab size and top predator identity in the absence of other cues and factors. The …

Estimating The Age And Mechanism Of Boulder Transport Related With Extreme Waves Using Lichenometry, Maria A. Oliveira, Esteve Llop, César Andrade, Cristina Branquinho, Ronald Goble, Sónia Queiroz, Maria C. Freitas, Pedro Pinho

Department of Earth and Atmospheric Sciences: Faculty Publications

Tsunamis and storms cause considerable coastal flooding, numerous fatalities, destruction of structures, and erosion. The characterization of energy and frequency associated with each wave contribute to the risk assessment in coastal regions. Coastal boulder deposits represent a physical proof of extreme inundation and allow us to study the effects of marine floods further back in time than instrumental and historical records. Age estimation of these deposits is challenging due to lack of materials (such as sand, shells, corals, or organic matter) that retain information about the passage of time. Lichenometry, a simple age estimation method, which is cost effective, quick …

Test Of Mechanical Properties Of Limestone Under Hydraulic Pressure-Stress Coupling, Tian Shukun

Coal Geology & Exploration

To study the mechanical properties of limestone with water-rich saturated circumstance under water pressure-stress coupling, compression failure tests of limestone samples with different water pressure were carried out by using a self-developed permeability test device, the device can realize uniaxial compression test. Then, the stress-strain characteristics of limestone, the effect of hydraulic pressure on uniaxial compressive strength, the elastic modulus and the deformation modulus, and the correlation between breaking characteristics and hydraulic pressure were tested. The results show that the increased hydraulic pressure has a significant influence on the stress-strain curve and strength characteristics. With the increase of hydraulic strength, …

Early Mississippian Ocean Anoxia Triggering Organic Carbon Burial And Enhancing Late Paleozoic Ice Age Onset: Evidence From Uranium Isotopes Of Marine Limestones, Keyi Cheng

Earth and Planetary Sciences ETDs

The Early Mississippian (Tournaisian) positive δ¹³C excursion (or TICE) is one of the largest recorded in the Phanerozoic and the organic carbon (OC) burial associated with its development is hypothesized to have driven global cooling and increased glaciation. We are testing the hypothesis that expanded ocean euxinia/anoxia drove widespread OC burial and the TICE and we are testing this hypothesis using uranium isotopes (δ²³⁸U) of Lower Mississippian marine limestones from southern Nevada as a global seawater redox proxy.

δ²³⁸U trends record a prominent mid-Tournaisian negative excursion (~0.30‰ magnitude) lasting ~1 My. The lack of …

Modeled Affinity Constants For Phosphorus Adsorption And Desorption Due To Saltwater Intrusion, Yasemin Taşcı

USF Tampa Graduate Theses and Dissertations

It is important to understand the processes that regulate phosphorus (P) fluxes to coastal environments, because P is an important nutrient in coastal ecosystems. Phosphorus adsorbs to the surface of minerals in sediment and bedrock, and an influx of seawater can cause some of that P to desorb, raising the P concentration of ambient water. Although seawater-induced P desorption is thought to be an important source of P to coastal environments, the chemical reactions that underlie it have not been established. Previous work provides some relevant surface reactions and associated affinity constants between various aqueous P species and the surface …

Investigation Of Thermal And Mechanical Behavıors Of Construction Materials Obtained From Some Natural Stone Waste, Gökhan Erol, Devrim Pekdemi̇r

Bulletin of the Mineral Research and Exploration

In this study, thermal and mechanical behaviours of composite building materials obtained from different kinds of natural stone wastes were investigated. First of all, XRD, chemical and grain size distribution analyses were carried out to identify the natural stone wastes to be used. 60% granite (magmatic), 35% recrystallized limestone (metamorphic) and 5% pure aluminium oxide (Al₂O₃) materials were used in the prepared mixture. The prepared mixture was shaped in a steel mould 75x20x50 mm in size by adding 7% shaping water and fired at 1140 ° C, 1150 ° C and 1160 ° C. Following that …

Lithology And Depositional Environments Of A Portion Of The Clays Ferry Formation (Middle And Upper Ordovician) Exposed At Silver Creek, Madison County, Kentucky, Autumn Murray, Walter S. Borowski

EKU Faculty and Staff Scholarship

We measure, describe, and interpret a carbonate stratigraphic section within the Clays Ferry Formation (Middle and Upper Ordovician) cropping out in Madison County, Kentucky (USGS Kirksville 7.5” quadrangle). Outcrops are exposed within the bed of Silver Creek along Ky 876 (Barnes Mill Road) from ~100 m downstream of where a bridge crosses the stream, then upstream and upsection for a distance of ~300 m over several sets of falls until bedrock exposure becomes sporadic to absent. We sampled the stratigraphic section at approximately half-meter intervals, also taking samples at lithology changes. We collected a total 18 samples, all of which …

Lithology And Depositional Environments Of A Portion Of The Clays Ferry Formation (Middle And Upper Ordovician) Exposed At Silver Creek, Madison County, Kentucky, Autumn Murray

EKU Faculty and Staff Scholarship

We measure, describe, and interpret a carbonate stratigraphic section within the Clays Ferry Formation (Middle and Upper Ordovician) cropping out in Madison County, Kentucky (USGS Kirksville 7.5” quadrangle). The total thickness of the measured section is 4.76 m. We sampled the stratigraphic section at approximately half-meter intervals, also taking samples at lithology changes. We collected a total 20 samples, all of which were slabbed, and then selected 12 samples for thin section analysis.

Observed lithologies represent discrete depositional environments. The rocks are dominantly limestones with some carbonate shales deposited in shallow-water depositional environments that are generally open-marine, subtidal with perhaps …

Facies Analysis, Sedimentary Petrology, And Reservoir Characterization Of The Lower Triassic Sinbad Limestone Member Of The Moenkopi Formation, Central Utah: A Synthesis Of Surface And Subsurface Data, Kristopher Michael Powell

Theses and Dissertations

Lower Triassic strata in the Wellington Flat and Tully cores reflect a lateral transition from shallow water strata (Wellington Flats core) to strata that indicate deposition on a relatively more distal, storm-dominated ramp (Tully core). The Sinbad Member, along with the upper part of the underlying Black Dragon Member and the lower part of the overlying Torrey Member (Moenkopi Formation), are composed of ten carbonate, siliciclastic and mixed carbonate/siliciclastic facies deposited on a west-facing ramp/shelf that reached maximum flooding during Smithian time. Individual beds and facies display a large degree of lateral homogeneity and regional persistence in the study area. …

Speleogenesis Of Critchfield Bat Caves And Associated Hydrogeology Of The Northern Edwards Aquifer, Williamson County, Texas, Ashley N. Landers

Electronic Theses and Dissertations

Karst development in the Edwards Aquifer has been significantly studied in the San Antonio and Barton Spring Segments; however, karst development remains poorly studied in the Northern Segment. Detailed characterization of the Northern Segment is vital for future water conservation because of increasing urban sprawl along the Interstate 35 corridor. The Northern Segment of the Edwards Aquifer consists of Lower Cretaceous strata of the Comanche Peak, Edwards, and Georgetown formations. The stratigraphy is dominated by Edwards Limestone as it is the only formation that crops out in the study area.

Karst, stratigraphic, GIS, and geochemical studies were conducted to evaluate …

Experimental Limestone Dissolution And Changes In Multiscale Structure Using Small- And Ultra Small- Angle Neutron Scattering, Chad Alan Novack

Masters Theses

Small angle neutron scattering (SANS), ultra-small angle neutron scattering (USANS), and backscatter electron (BSE) imaging, along with neutron computed tomography (NCT) were used in this study to experimentally quantify pore size, distribution, and connectivity of dissolved limestone geometries. Eight samples of Indiana limestone of two different initial permeabilities (2-4 mD and 70 mD ) [millidarcy] were reacted with HCl [hydrochloric acid] solutions at differing pH (2 and 4), and flow rates (0.1 and 10 cm³/min) [cubic centimeters per minute] to describe a broad range of parameters that affect limestone dissolution. NCT was first used to image the dissolution …

Carbon Isotope Variations Associated With A Middle Ordovician Karstic Unconformity, Patricia Suzanne Williams

UNLV Theses, Dissertations, Professional Papers, and Capstones

Large negative carbon isotope (δ¹³C) excursions have been documented from late Neoproterozoic-Paleozoic successions. These δ¹³C excursions have been widely used for regional and global stratigraphic correlation, particularly in strata with limited paleontological and radiometric age controls. Recent studies, however, argued that some negative δ¹³C excursions from stratigraphic record may have been resulted from meteoric/burial diagenesis, which commonly shifts both carbon and oxygen isotopes toward lower values. Testing the diagenetic origin of δ¹³C excursions in stratigraphic successions without independent stratigraphic framework has been difficult because it evolves into circular arguments about stratigraphic completeness …

Validity Of Holocene Analogs For Ancient Carbonate Stratigraphic Successions: Insights From A Heterogeneous Pleistocene Carbonate Platform Deposit, Colby Hazard

Theses and Dissertations

Observations of modern carbonate depositional environments and their accompanying depositional models have been used for decades in the reconstruction and interpretation of ancient carbonate depositional environments and stratigraphic successions. While these Holocene models are necessary for interpreting their more ancient counterparts, they inherently exclude important factors related to the erosion, diagenesis, and ultimate preservation of sediments and sedimentary structures that are ubiquitous in shallow marine carbonate environments. Andros Island, Bahamas is an ideal location to examine the validity of Holocene conceptual models, where geologically young (Late Pleistocene) limestones can be studied immediately adjacent to their well-documented modern equivalents. For this …

Rare Earth Element Geochemistry Of The Upper Permian Limestone: The Kanigorgeh Mining District, Nw Iran, Ali Abedini, Ali Asghar Calagari

Turkish Journal of Earth Sciences

The limestone of the Ruteh Formation of Upper Permian age in the Kanigorgeh district (northeast of Bukan, NW Iran) contains several layers and lenses of bauxitic ores. Mineralogical data show that this limestone consists of calcite and quartz as major and plagioclase, kaolinite, and hematite as minor mineral phases. Geochemical analyses reveal that the proportions of ?REEs (La-Lu) in this limestone vary from 35.28 to 160.78 ppm. The values of Eu and Ce anomalies (normalized to PAAS) of the limestone have ranges of 1.11-1.68 and 0.89-1.16, respectively. The high values of ?REEs; low values of Y/Ho; strong and positive correlations …

Economic Geology Of The San Bernardino Mountains, California, Nicolette Deannah Grill

Electronic Theses, Projects, and Dissertations

The San Bernardino Mountains are well known for their rich mining history, especially, gold in the mid-1800s and the current mining of one of the world’s largest deposits of high purity limestone. The purpose of this study was to compile new, current, and historical data of the major economic resources that are present and mining that has gone on in the San Bernardino Mountains. It is estimated that historical mining of the Holcomb Valley recovered $457,660,000 of gold or about 350,000 troy ounces based on samples collected for this study and 2013 gold price. The current major geologic resource is …

Subsurface Sequence Stratigraphy And Reservoir Characterization Of The Mississippian Limestone (Kinderhookian To Meramecian), South Central Kansas And North Central Oklahoma, Thomas Cahill

Graduate Theses and Dissertations

Both conventional and unconventional Mississippian reservoirs in the mid-continent are largely comprised of chert-rich carbonates of Osagean and Meramecan age. The conventional reservoir target is the Mississippian "chat," a high porosity, chert residuum interval found immediately beneath the Mississippian-Pennsylvanian unconformity. The unconventional reservoir target occurs in the lower porosity, cherty, mud-rich intervals that occur in the lower portion of the Mississippian succession.

There has been considerable debate surrounding the sequence stratigraphic interpretations, depositional models, and formation names applied to the reservoir intervals within the subsurface. Another major issue with regard to the subsurface is the stratigraphic position and origin of …

Impacts Of Carbonate Mineral Weathering On Hydrochemistry Of The Upper Green River Basin, Kentucky, Laura Leigh Osterhoudt

Masters Theses & Specialist Projects

Kentucky’s Upper Green River Basin has received significant attention due to the area’s high biodiversity and spectacular karst development. While carbonate bedrock is present throughout the watershed, it is more extensive and homogenous along the river between Greensburg and Munfordville than upstream from Greensburg where the geology is more heterogeneous. This research quantitatively evaluated how lithological differences between the two catchment areas impact hydrochemistry and inorganic carbon cycling. This first required correcting catchment boundaries on previous US Geological Survey Hydrologic Unit Maps to account for areas where the boundaries cross sinkhole plains. Basin boundaries using existing Kentucky Division of Water …

Photomicrograph Analysis Of Marcellus Well-Cuttings From Northeast Pennsylvania, Ethan Shula

The Research and Scholarship Symposium (2013-2019)

Often times, when an oil or gas well is drilled in an area with limited geophysical and mud logs, the geologist or mudlogger describing the drill cuttings may wonder about the veracity of their work. Such an uncertainty may initiate a decrease in the rate of the mudlogging process, or in determining how far drilling has advanced in relation to the target zone. If a descriptive guide containing photomicrographs was available early in the development of a new gas field, mudloggers would be more certain in their analysis of the cuttings. In order to test this idea, a descriptive guide …

Geoanalytical Analysis Of Speleogenetic Development In The Owl Mountain And Nolan Creek Provinces: Fort Hood Military Installation, Texas (Abstract], Melinda G. Shaw-Faulkner, Kevin W. Stafford, Aaron W. Bryant

Faculty Presentations

No abstract provided.

Limetstone And Dolomite Resources Of Kentucky, Garland R. Dever Jr., Gerald A. Weisenfluh

Map and Chart--KGS

Large quantities of limestone and dolomite suitable for construction, agriculture, and industrial uses are available in Kentucky. Deposits of hard and durable stone are quarried and mined for construction. The stone is crushed to produce aggregate for concrete and asphalt used in the construction of highways, streets, and buildings. Much of the state’s stone being produced for construction also meets the chemical and physical specifications for aglime, which is used to adjust the pH of soils for agricultural crops and pastures. Deposits of chemically pure stone are used for the manufacture of lime and cement, and for industrial applications such …

Microbialitic Structures In The Sarmatian Carbonate Deposits From Simleu Basin, Hyam Daoud, Ioan I. Bucur, CăLin Bruchental

Studia UBB Geologia

The Sarmatian deposits from the Şimleu basin are developed in two facies: terrigenous and calcareous. An attempt to distinguish the main types of Sarmatian limestone microfacies was made by Bucur et al. (1992). The present study provides more detail of the sedimentary facies and fabrics of these limestones, emphasizing the essential contribution of microbialites to their formation. The following types of microbialite and microbial structure were found: (1) thrombolites with clotted fabric and fenestral structures; (2) microbial crusts on bioclasts; (3) peloidal microbialites (4) agglutinated microbialites; (5) stromatolites and laminoid-fenestral structures. All these structures played an important role in the …

The Olenekian Carbonates Of The Bucovinian Nappe (The Central Sector Of The Haghimas Syncline, Eastern Carpathians). Lithology And Microfacies, Daniela Alexandra Popescu, Liviu Gheorghe Popescu

Studia UBB Geologia

Early Triassic carbonate outcrops were studied in the central sector of the Hăghimaş Syncline with regard to stratigraphy, microfacies and facies interpretation.This is the first microfacies study of these deposits. Early Triassic carbonates in the Hăghimaş Syncline are represented by two stratified successions: limestones and dolomites. The limestones overlie very rarely the detritic basal deposits (Induan) which marks the beginning of the alpine transgression. The stratified dolomites underlie frequently the Early Anisian massive dolomites. The contact between the stratified limestones and stratified dolomites is only exposed on Calu brook outcrop (the western flank of the Hăghimaş Syncline). The age of …