Physical Sciences and Mathematics Commons^™

High-Power Laser Cooling And Temperature-Dependent Fluorescence Studies Of Ytterbium Doped Silica, Brian Topper

Optical Science and Engineering ETDs

Experimental observation of optical refrigeration using ytterbium doped silica glass in recent years has created a new solution for heat mitigation in high-power laser systems, nonlinear fiber experiments, integrated photonics, and precision metrology. Current efforts of different groups focus on compositional optimization, fiber fabrication, and investigating how much silica can be cooled with a laser. At the start of this work, the best effort in laser cooling ytterbium doped silica saw cooling by 6 K from room temperature. This dissertation follows the experimental efforts that culminated in the increase of this initial record by one order of magnitude. Comprehensive spectroscopic …

Assessing Ecological Relationships Among Late Triassic Vertebrates In Petrified Forest National Park, Alexandra Davis Apgar

Earth and Planetary Sciences ETDs

The complex vertebrate ecosystem of the Late Triassic has not yet been fully understood, largely due to oversimplification of hypothesized trophic hierarchies and limited preservation of direct evidence of faunal interaction. Paleocommunity reconstruction attempts can also fall victim to taphonomic biases, time-averaging inaccuracies, and non-analogue paleoecologies. Utilizing a combination of PAIRS analysis and NMDS ordination, we highlight vertebrate faunal relationships within the Adamanian and Revueltian faunachrons of Petrified Forest National Park, assess the likelihood that these patterns have ecological rather than preservational drivers, and examine how these potential interactions may have been impacted by the Adamanian-Revueltian turnover event. We are …

Photophysical Properties Of Synthetic Oligomeric Phenylene Ethynylene, Hugh F. Fritz Jr.

Chemistry and Chemical Biology ETDs

Oligomeric Phenylene Ethynylenes (OPEs) are a class of synthetically prepared compounds with the basic structure of phenylene rings connected by triple-bonded carbon atoms, also known as an ethyne link. This structure can be modified by incorporating functional groups onto one or more of the phenylene rings. The addition of functional groups, such as sulfoxide or imidazole, may alter the photophysical properties in detectable ways. The photophysical techniques used in this report include fluorescence, spectroscopy in the ultraviolet and visible light range (UVVIS), and photon-based excitation using a photo chamber.

One attractive function of OPEs is their antimicrobial property. Previously published …

Dynamic Fallowing In The Middle Rio Grande: A Look At The Environmental Water Leasing Program, Jared Wood

Water Resources Professional Project Reports

The Environmental Water Leasing Program (EWLP) is a federally-funded collaborative effort of the Middle Rio Grande Conservancy District and the U.S. Bureau of Reclamation that has paid irrigators in the Middle Rio Grande to temporarily lease water rights and forgo their water use so that it may be used to provide environmental flows for the endangered Rio Grande Silvery Minnow. The program operates in a sometimes socially contentious context, in a region with an overallocated, legally constrained water system, to offer much needed water management flexibility. While dynamic fallowing payments for ecosystem services programs like the EWLP are common policy …

Irrigation And Innovation: Understanding Barriers To Innovative Actions To Manage Drought On Middle Rio Grande Farms, Eleanor C. Hasenbeck

Water Resources Professional Project Reports

The Rio Grande has irrigated agricultural land in central New Mexico since time immemorial. Today, agriculture in New Mexico’s Middle Rio Grande valley is adapting to an increasingly scarce water supply due to long-term drought and climate change (Dunbar et al., 2022). As supply is decreasing, demands are increasing because of several factors: an increase in evapotranspiration (Dunbar et al., 2022); population growth in the Middle Rio Grande valley (NM LFC, 2021); and legal obligations to provide water for endangered species and to Texas and Mexico (NM ISC, 2017). Agriculture is largest water use by sector in the Rio Grande …

Groundwater Budgeting And Climate Change Vulnerability Assessment Of Water Supply At Bosque Del Apache National Wildlife Refuge, Maximiliano Trujillo

Water Resources Professional Project Reports

Water resources management is becoming increasingly complex in the Middle Rio Grande Valley, where the negative impacts of climate change and growing demand for a fully allocated river put further strain on diminishing water supply. The precarity of future water availability emphasizes the importance of fully accounting for existing water rights allocations and understanding how ever changing social and ecological processes might hinder those rights from being fully realized. This study aimed at improving knowledge of the groundwater budget at Bosque del Apache National Wildlife Refuge, New Mexico by utilizing experimental methods of Darcy Flow analysis to estimate groundwater flow …

Motivations And Barriers To Participation In Community Outreach And Engagement Among Environmental And Water Resources Students And Postdocs, Sydney Donohue

Water Resources Professional Project Reports

There is a need to utilize knowledge exchange avenues between academia and non-academic communities in order to advance environmental science and engineering education. Many universities and research centers attempt to enhance knowledge sharing by organizing broader impact outreach events such as lab tours, demonstrations, hands-on activities, and public presentations. Anecdotally, at two NSF-funded centers, the Transformation Network and Center for Water and the Environment, we have seen that only the same small subset of students and postdocs frequently participate while over 70% of those invited never volunteer. This study aims to survey environmentally-focused undergraduate students, graduate students, and postdocs’ motivations …

Modified Geometries, Clifford Algebras And Graphs: Their Impact On Discreteness, Locality And Symmetr, Roman Sverdlov

Mathematics & Statistics ETDs

In this dissertation I will explore the question whether various entities commonly used in quantum field theory can be “constructed". In particular, can spacetime be “constructed" out of building blocks, and can Berezin integral be “constructed" in terms of Riemann integrals.

As far as “constructing" spacetime out of building blocks, it has been attempted by multiple scientific communities and various models were proposed. But the common downfall is they break the principles of relativity. I will explore the ways of doing so in such a way that principles of relativity are respected. One of my approaches is to replace points …

Methods Of Magneto-Optical Spectroscopy And Analysis For Porphyrins And Polymer Thin-Films, Emigdio E. Turner

Chemistry and Chemical Biology ETDs

This dissertation describes the construction of two high precision magneto-polarimeters for performing Faraday rotation and Magnetic Circular Dichroism (MCD) measurements of polymer thin-films. There is a focus in materials science on the development of thin-film magneto-optically active materials. These materials could allow for the construction of a thin-film optical diode, an important device for next-generation photonic technology. Upon completion of the Faraday rotation spectrometer, two publications were generated from Faraday rotation measurements of novel polymer thin-film materials.

With growing interest by materials scientists in magneto-optically active transition-metal containing materials, an MCD spectrometer was constructed to study these materials. This spectrometer …

Filaments And Their Application To Air Lasing, Spectroscopy, And Guided Discharge, Ali Rastegari

Optical Science and Engineering ETDs

Laser filamentation is a fascinating phenomenon that occurs when an intense laser beam travels through transparent materials, in particular air. At sufficiently high power (TW in the near IR, GW in the UV), instead of spreading out like a regular laser beam, something remarkable happens: the laser beam becomes tightly focused, creating a thin and intense column of light called a laser filament. Laser filamentation is characterized by two main properties: (I) a high-intensity core that remains narrow over long distances beyond the Rayleigh range and (II) a low-density plasma channel within the core. In recent years, laser filamentation has …

The Affective Landscapes Of Herbalism In New Mexico, Samantha Angelou Stroud

Geography ETDs

Herbalism, or practices which use plants for medicinal purposes, is tied to traditions in several cultures of the American Southwest, including Indigenous herbal medicine, Mexican-American curanderismo, and Western herbal traditions. Herbalism has been steadily gaining mainstream popularity since the late 1960s, alongside counterculture, holistic health, and back-to-nature movements, introducing many newcomers to the practice. This study asks: How does herbalism create and attach meaning to plants, cultures, and place in New Mexico? What are the affective landscapes produced by herbalism in New Mexico? And, to what extent do meaningful attachments manifest in ethics and actions of care? I argue that …

Mechanisim Of Plasmon-Driven Photochemical Reactions, Hamed Kookhaee

Chemistry and Chemical Biology ETDs

Understanding a photocatalytic reaction condition that selectively leads to a desired product on metal surfaces is a longstanding research problem in heterogeneous catalysis. Here, using plasmon enhanced N-demethylation of methylene blue (MB) as model reaction, we show that high degree of product selectivity can be achieved by switching the mechanism from charge transfer to adsorbate electronic excitation and vice versa using surface ligands. In the presence of cetyl trimethyl ammonium bromide (CTAB) surface ligand on gold nanoparticles, MB is selectively transformed to thionine at 633 nm excitation wavelength that overlaps with the electronic transition of the adsorbate. At resonant excitation …

Bulk Hydrogen Isotopes In Ordinary Chondrites, Michael J. Cato

Earth and Planetary Sciences ETDs

Bulk hydrogen isotopes in nominally anhydrous meteorites are a key component in our understanding of the distribution of hydrogen in our solar system, including the provenance of water on the Earth. Here, we develop a step-heated continuous-flow method to measure the bulk hydrogen isotopes in nominally anhydrous rocks and use this method to significantly increase the dataset of bulk hydrogen isotopes in ordinary chondrites, nearly doubling the number of equilibrated members. We found that as thermal alteration increases from petrologic type 3.0 to 4, there is a correlated decrease in both hydrogen content and isotope ratio, followed by no significant …

Rigorous Analysis Of Markov Processes With Applications To Quantum Information, Samuel Edwin Slezak

Physics & Astronomy ETDs

We present a rigorous analysis of the rapid convergence of techniques based on Markov chains for the simulation of thermal quantum systems. We show that a classical computing algorithm called path integral Monte Carlo is capable of simulating thermal states of transverse field Ising models above a threshold temperature by demonstrating the existence of a rapidly mixing Markov chain. We then turn to quantum computing algorithms and show that an idealized version of quantum Metropolis sampling can efficiently simulate systems that satisfy the eigenstate thermalization hypothesis. In a related result, we find a class of stoquastic frustration free Hamiltonians that …

Synthesis, Characterization And Spectroscopic Studies Of Novel Donor-Acceptor Complexes, Shiyue Gao

Chemistry and Chemical Biology ETDs

Square-planar compounds of the (dichalcogenolene)Pt(diimine) series are possess unique photophysical properties that include long-lived excited state lifetimes, which result in their being potential candidates for numerous applications. These applications include solar energy conversion, photocatalysis, nonlinear optics, and photoluminescent probes of biological systems. The most interesting feature of the (dichalcogenolene)Pt(diimine) series of molecules is the bpydichalcogenolene ligand-to-ligand charge transfer (LL’CT) band. To better understand their photoluminescent decay mechanism, and understand their excited dark state properties, we have synthesized and characterized new compounds that include (Thp-bpy)Pt(CAT), (Thp2-bpy)Pt(CAT), (Thp-bpy)Pt(bdt), and (Thp2-bpy)Pt(bdt). Through interpretation of electronic absorption, resonance Raman, XAS, photoluminesce spectroscopy, in addition …

Deformation At Uturuncu Volcano, Bolivia: Modeling The Effect Of Volatile Movement In The Hydrothermal System, Karissa Rosenberger

Earth and Planetary Sciences ETDs

Deformation at volcanos is often a precursor to an eruption, but sometimes volcanos experience uplift without actually erupting. Determining the mechanisms behind this deformation and whether it will lead to an eruption is an important part of understanding volcanic systems. Uturuncu volcano in Bolivia has been experiencing deformation for decades, but the last time it erupted was 250,000 years ago. The reason behind this deformation is unknown, but one possible cause is volatiles moving into the hydrothermal system and getting trapped, causing the volume to increase and the surface to uplift. To test this hypothesis, the current volume change of …

The Quantum Computational Utility Of Symmetry-Protected Topological Order: From Near-Term Advantages To Universal Measurement-Based Quantum Computing, Austin Kevin Daniel

Physics & Astronomy ETDs

Quantum computers offer new avenues to approach difficult problems by taking advantage of the strange and often nonintuitive phenomena present in quantum physics. Though many quantum algorithms are believed or known to outperform the best known classical algorithms, the fundamental mechanism granting them their power remains elusive. In measurement-based quantum computation (MBQC), two key resources have been show to enable universal and provably nonclassical quantum computations, respectively. These are symmetry-protected topological order (SPTO), a notion describing a class of quantum magnets with hidden long-range correlations in their entanglement structure, and quantum contextuality, the fact that a quantum measurement outcome inherently …

Femtotesla Magnetometry And Nanoscale Imaging With Color Centers In Diamond, Yaser Silani

Optical Science and Engineering ETDs

Intriguing photophysical properties of color centers in diamond make them ideal candidates for many applications from imaging and sensing to quantum networking. In the first part of this work, we have studied the silicon vacancy (SiV) centers in diamond for nanoscale imaging applications. We showed that these centers are promising fluorophores for Stimulated Emission Depletion (STED) microscopy, owing to their photostable, near-infrared emission and favorable photophysical properties. In the second part, we built a femtotesla Radio-Frequency (RF) magnetometer based on the diamond nitrogen vacancy (NV) centers and magnetic flux concentrators. We used this sensor to remotely detect Nuclear Quadrupole Resonance …

Impacts Of Urban Renewal On Community Identity And Sense Of Place In Las Cruces, New Mexico, Savannah Lorraine Quintana-Eddins

Geography ETDs

Las Cruces is the second largest city in New Mexico which has experienced exponential growth in the last three decades. The city has been cultivated by a rich history of Native populations, Spanish colonialism, and American democratic government. The culmination of these influences on Las Cruces had much influence on the Mesquite Historic District, the original townsite of Las Cruces. This area is home to many generational families and is adjacent to the downtown Main Street corridor. Downtown was built from the destruction of the Mesquite Historic District caused by waves of urban renewal projects. Through organizing, legislative action and …

Multilevel Optimization With Dropout For Neural Networks, Gary Joseph Saavedra

Mathematics & Statistics ETDs

Large neural networks have become ubiquitous in machine learning. Despite their widespread use, the optimization process for training a neural network remains com-putationally expensive and does not necessarily create networks that generalize well to unseen data. In addition, the difficulty of training increases as the size of the neural network grows. In this thesis, we introduce the novel MGDrop and SMGDrop algorithms which use a multigrid optimization scheme with a dropout coarsening operator to train neural networks. In contrast to other standard neural network training schemes, MGDrop explicitly utilizes information from smaller sub-networks which act as approximations of the full …

Evaluation Of Fluvial Package Amalgamation In Medial Dfs Deposits, Angel Peak Area, Nacimineto Formation, Sarah R. Rysanek

Earth and Planetary Sciences ETDs

Fluvial packages are the hypothetical groupings of facies that make up the fluvial succession consisting of channel belt sandstones and associated levee, floodplain, and avulsion deposits. This study attempted to describe a single fluvial package laterally using the new technologies of UAV imaging and 3D photogrammetry; however, amalgamation of channel belts and erosion from this amalgamation made long-distance lateral correlation difficult. This analysis of medial deposits in the Nacimiento Formation in the Angel Peak Area, Northwestern New Mexico evaluates the degree of amalgamation of fluvial packages across the study area while identifying facies associated with the hypothetical fluvial package. This …

Performance Of The Mineral Recovery Enhanced Desalination Pilot Water Treatment Plant, Samantha Valentine

Water Resources Professional Project Reports

There is a growing interest in treating brackish groundwater to supplement freshwater resources for inland communities in arid climates. Water recovery by desalination of brackish groundwater is challenging due to mineral scaling from ions which form carbonate and sulfate minerals, dissolved silica which forms silicates, iron, manganese, and other constituents along with the difficulties and cost of disposing of large volumes of brine from the desalination process. The MRED process consists of a pretreatment process to increase water recovery and decrease waste production from brackish groundwater. The MRED process uses a unique sequence of unit processes consisting of: (1) Air …

Toward The Yeast Surface Display Of Microviridin B, Jillian Leigh Stafford

Chemistry and Chemical Biology ETDs

Humans have turned to natural products for medicinal therapeutics for millennia. In recent years, the ribosomally synthesized and post-translationally modified peptide (RiPP) class of natural products have garnered a lot of attention due to their ability for heterologous expression, relative ease of mutation, and vast biological activates. Microviridins are a family of RiPPs that contain a tricyclic cage-like structure through the formation of two lactone rings and one lactam ring catalyzed by two ATP-grasp ligase family enzymes. Microviridins are potent inhibitors of serine proteases and mutational studies of a small number of residues indicates the potential of peptide engineering protease …

Rural Water Manager Challenges In New Mexico, Amy "Aj" Jones

Water Resources Professional Project Reports

New Mexico poses a valuable set of circumstances to study the challenges faced by drinking water systems. A general lack of resources for small systems, be it personnel and funding issues, lack of community engagement, lack or loss of institutional knowledge, ability to meet regulations, and aging managers were found to be very common and widespread. Rural water manager positions that are unsupported financially do not assist in alleviating rural poverty or draw the workforce. Therefore, the negative state demographic statistics are reinforced, further complicating rural water management rather than helping the issues. To look at drinking water management comprehensively, …

Securing Environmental Flows For The Rio Grande Silvery Minnow, Ashley Veihl

Water Resources Professional Project Reports

Since 1997, the Bureau of Reclamation (Bureau) has been leasing water to provide habitat for the now-endangered Rio Grande silvery minnow (Minnow). The majority of leased water comes from the San-Juan Chama project, a trans-basin water delivery system that was originally implemented to secure flows to the Rio Grande for municipal and agricultural use. Limitations on water storage within reservoirs incentivize contractors that are allocated more surface water than they can use to lease the extra quantity. It is through this water leasing market that the Bureau has established the largest environmental flow program in the state of New Mexico. …

The Role Of Citizen Science In Ecosystem Management: A Case Study Of The Middle Rio Grande Bosque Ecosystem Monitoring Program, Hannah Miller

Water Resources Professional Project Reports

Rapid advances in technology, especially smart phones, have changed citizen science around the world. Citizen science-generated data are growing exponentially, so there is increasing interest about what is happening with all this data. Some research suggests that governmental agencies are not using citizen science data to make ecosystem management decisions, although other studies contradict this finding. Regionally, the Middle Rio Grande bosque ecosystem extends for 162 miles along the Rio Grande in New Mexico. The Bosque Ecosystem Monitoring Program, or BEMP, was founded in 1996 following the efforts of the Bosque Initiative and the development of the Bosque Biological Management …

Using Physics-Informed Neural Networks For Multigrid In Time Coarse Grid Equations, Jonathan P. Gutierrez

Mathematics & Statistics ETDs

For parallel-in-time integration methods, the multigrid-reduction-in-time (MGRIT) method has shown promising results in both improved convergence and increased computational speeds when solving evolution problems. However, one problem the MGRIT algorithm currently faces is it struggles solving hyperbolic problems efficiently. In particular, hyperbolic problems are generally solved using explicit methods and this causes issues on the coarser multigrid levels, where larger (coarser) time step sizes can violate the stability condition. In this thesis, physics-informed neural networks (PINNs) are used to evaluate the coarse grid equations in the MGRIT algorithm with the goal to improve convergence for problems with hyperbolic behavior, as …

Machine Learning Methods For Computational Phenotyping Using Patient Healthcare Data With Noisy Labels, Praveen Kumar

Computer Science ETDs

Positive and Unlabeled (PU) learning problems abound in many real-world applications. In healthcare informatics, diagnosed patients are considered labeled positive for a specific disease, but being undiagnosed does not mean they can be labeled negative. PU learning can improve classification performance, and estimate the positive fraction, α, among unlabeled samples. However, algorithms based on the Selected Completely At Random (SCAR) assumption are inadequate when the SCAR assumption fails (e.g., severe cases overrepresented), and when class imbalance is substantial. This dissertation presents and evaluates new algorithms to overcome these limitations. The proposed methods outperform the state-of-art for α-estimation, enhance classification performance, …

An Overview Of Plithogenic Set And Symbolic Plithogenic Algebraic Structures, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

This paper is devoted to Plithogeny, Plithogenic Set, and its extensions. These concepts are branches of uncertainty and indeterminacy instruments of practical and theoretical interest. Starting with some examples, we proceed towards general structures. Then we present definitions and applications of the principal concepts derived from plithogeny, and relate them to complex problems.

Nidus Idearum. Scilogs, Xii: Seed & Heed, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

In this twelfth book of scilogs – called seed & heed –, one may find topics on Neutrosophy, Superluminal Physics, Mathematics, Information Fusion, Philosophy, or Sociology – email messages to research colleagues, or replies, notes, comments, remarks about authors, articles, or books, spontaneous ideas, and so on.