Physical Sciences and Mathematics Commons^™

Non-Covalent Functionalization Of Graphene Films For Uniform Nanoparticle Deposition Via Atoic Layer Deposition, Ty Seiwert

Mechanical Engineering Undergraduate Honors Theses

Graphene functionalized with platinum (Pt) and palladium (Pd) has proven to be highly effective as a hydrogen sensor. Deposition methods such as Atomic layer deposition (ALD) can be further enhanced by pretreating the graphene with a non-covalent surfactant prior to nanoparticle deposition. In this study, graphene-based sensing devices will be fabricated by ALD deposition. The graphene will be non-covalently functionalized using sodium dodecyl sulfate (SDS) anionic surfactant prior to ALD deposition. The aim of this study is to test the deposition pattern achieved by varying the amount of time that graphene is treated with the SDS surfactant. Initially, ALD deposition …

Lithium And The Foreseeable Future, Paolo Vargas

Mechanical Engineering Undergraduate Honors Theses

This paper aims to clarify the uncertainties regarding worldwide lithium resource availability in the years to come. Previous studies made on the subject are presented with some ambiguity and this work intends to fill the gaps. The information and data presented throughout this script with respect to global lithium resources and reserves are mostly based on data released by the United States Geological Survey (USGS). Lithium resource availability in the future is a point of paramount significance primarily for the automotive, portable electronics, and the power generation industry. Since, a change of supply would ultimately affect the price of lithium, …

A Comparative Life Cycle Assessment Of Nutritionally Equivalent Meals With And Without Pork, Kelli Young

Graduate Theses and Dissertations

The following report details a life cycle assessment of several dietary and meal scenarios with and without pork. The goal of the LCA was to identify the impacts of greenhouse gas emissions, water use, and land use of pork containing and porkless diets and meal plans in a field-to-fork analysis. The dietary and meal plan scenarios are iso-caloric meaning they contain the same number of calories. The first set of diets is based on a USDA consumption pattern, 2000 kcal per day. This diet was used to create three other dietary scenarios with and without pork. The USDA recommended food …

A Comparative Analysis Of Feed And Environmental Factors On Broiler Growth In The United States, Alexandra Gulli

Graduate Theses and Dissertations

Broiler production in the United States has become an important industry within the last half century. As the demand for poultry continues to increase and the concern of climate change also increases, it will become an important part of the industry to become more sustainable. This study uses a feed optimization model, a broiler growth model, and a life cycle assessment (LCA) to determine how feed ingredients and the barn environment can affect the broiler’s growth and production emissions. A multi-criteria ration optimization model is used to produce feeds based on carbon footprint and cost. A growth model is used …

Creating Sustainable Supply Chains: Influencing Sustainable Practices In The Supply Chain, Saif Mir

Graduate Theses and Dissertations

Organizations worldwide are reporting their commitment to create sustainable supply chains. Ultimately, supply chain professionals are the drivers of change within their respective organizations, so this dissertation examines the role of communication as a tool to persuade supply chain professionals to create sustainable supply chains. The three studies within this dissertation employ different methodologies to examine the role of communication in the development and implementation of sustainability initiatives. The first study, a grounded theory investigation, highlights the network, communication, and structural factors that provide a strong business case for the development of sustainability initiatives. A strong business case influences the …

Essays On Common-Pool Resources: Evaluation Of Water Management And Conservation Programs, Kuatbay K. Bektemirov

Graduate Theses and Dissertations

This dissertation is comprised of three essays that examine water management and conservation programs through the context of sustainable development. These essays are distinct case studies of national, state and local policies. Their common approach is that they all use common-pool resources theory to generate specific recommendations for policymaking and water management.

The first essay explores opportunities for developing policy measures to prevent the collapse of the vital irrigation infrastructure in the Aral Sea region. The paper looks at the economic efficiency of various policy options, impacts on the country’s agricultural sector, and the regulations needed to make the cost-sharing …

Tailings Dust Emissions, Emily Degner, Sam Horn, Zakary Galligan, Ryan Bernard, Julie Jameson, Josh Mueller, Natalie Tucker, Joe Griffin

Chemical Engineering Undergraduate Honors Theses

Fugitive dust emissions from the storage and handling of mine tailings presents environmental and safety concerns, which must be addressed to promote the land sustainability and the health and safety of individuals around a tailings storage facility (TSF). The investigated dust control methods were agglomeration, binder slurry injection, and topical spray.

The Dust Busters determined that pelletizing was the most practical method of agglomeration. In order to produce durable pellets from the mine tailings, which consist primarily of silica, a binder must be added. A variety of binders were considered including magnesium and calcium chloride, bentonite, barite, cement, vinyl polymers, …

A Study Of Short-Season Winter Cover Crops For Organic High Tunnel Production Systems, Luke Riley Freeman

Graduate Theses and Dissertations

This two-year study investigated short-season winter cover crops to improve soil quality and growth of subsequent vegetable crops in an organic high tunnel production system. Five winter cover crop treatments including a nontreated control, Austrian winter peas (Pisum arvense), bell beans (Vicia faba), mustard (Brassica juncea cv. Kodiak), and Daikon radish (Raphanus sativus var. longipinnatus) were grown in a high tunnel in a randomized complete block design from mid-November to mid-March, mowed and incorporated into the soil, and followed by a succession of vegetable crops including tomato (Lycopersicon lycopersicum, cv. ‘Plum Dandy’) and broccoli (Brassica oleracea var. italica, cv. ‘Bay …

How Do Designers Of The Built Environment Attempt To Make Ecological Sustainability Sensory Legible?, Carly L. Bartow

Architecture Undergraduate Honors Theses

This paper attempts to provide a theoretical framework for making ecosystem function and ecologically sustainable design more perceptible or sensible to people through architecture and the built environment. Design features of the Bertschi School Science Wing and the Bullitt Center in Seattle, Washington are incorporated to illustrate the sensory legibility of ecological sustainability criteria.The criteria are available to designers to help educate a building's occupants on environmentally sustainable design and motivate more sustainable behavior.

Haul Truck Tires Recycling, Jessica N. Lizarazu

Chemical Engineering Undergraduate Honors Theses

The disposal of large Off-the-Road (OTR) tires is an increasingly important concern. These tires can weigh up to 8,450 pounds with an overall diameter and width of approximately 140.7 inches and 45.1 inches respectively. OTR tires are used for mining vehicles such as haul trucks, wheel loaders, backhoes, graders, and trenchers. These new tires cost between $38,000 and $50,000 each, depending on multiple factors including oil prices and the cyclical nature of the industry. Haul trucks contain six tires per vehicle, and mines replace these tires around every 9-12 months. Statistics regarding discarded OTR tires are not provided by the …

Applications Of Cultural Theory And Empirical Analysis Of Sustainable Energy Policy Preferences In Arkansas, John Henry Kester Iii

Graduate Theses and Dissertations

The local policy arena is ripe for research on policy elite decisionmaking because where policy diffusion is concerned, previous studies focus on state-to-state and city-to-city dynamics. Therefore, there is a significant opportunity to expand understanding about the adoption of policies and policy diffusion at the local level. Identification of individual level determinants that signify policy adoption is a cornerstone to fostering this knowledge. This study examines such preference indicators found among policy elites in select Arkansas cities. For this research, the primary theoretical perspective for evaluating individual determinants is cultural theory, which has shown strong correlation to individual policy preference …

Grass Finishing Systems For Lambs, Erin Leigh Smyth

Graduate Theses and Dissertations

There is strong interest in sustainably produced meat. Grass-fed lamb could fulfill this market by reducing off-farm inputs. The objective was to examine the effect of grass-finishing or minimal supplementation on performance of lambs in the southeastern US. Katahdin lambs born in October 2013 and 2014 and February 2014 were weaned in January 2014/2015 and May 2014, respectively. Lambs were blocked by gender (fall; winter included only ram lambs) and randomly assigned to receive no (NON) or grain co-product supplement (SUP; 15% CP) at 0.5% of BW/d. Lambs were rotationally grazed on predominantly grass. Body weight, fecal egg counts (FEC), …

Life Cycle Assessment Of Alternative Swine Management Practices, Prathamesh Avadhut Bandekar

Graduate Theses and Dissertations

Life Cycle Assessments (LCAs) are quantitative analyses of complex systems for evaluation of impacts and risk associated with management decisions. LCAs can be effective tools for determining comparative advantages of management strategies across specific impact concern. In this study, life cycle assessments of pork production management alternatives was performed. The alternative management practices included in this study were production of entire males (boars), use of pens for gestation housing, immunocastration, production without growth promoting antimicrobials, production without growth promoting and preventive antimicrobials, and production without ractopamine. These LCAs evaluated the impact of each management strategy on greenhouse gas emission (GHG), …

A Cradle To Farm Gate Life Cycle Analysis Of Land Use In U.S. Pork Production, William Benjamin Putman

Graduate Theses and Dissertations

The goal of this study was to conduct a detailed Life Cycle Assessment (LCA) of the U.S. live swine production supply chain to quantify land use requirements and to assess the impact associated with various ration compositions. The functional unit was defined as one kilogram (2.2 pounds) of live swine at the farm gate, ready for transport to the abattoir. This assessment focused on the three highest producing USDA regions, which encompassed the Midwest (Regions 5 and 7) and the Southeast (Region 4), representing 86% of U.S. market hog production.

First, a literature review was conducted to summarize the most …

Using The Triple Bottom Line To Select Sustainable Suppliers For A Major Oil And Gas Company, Pandarinath Adarsh Sunkari

Graduate Theses and Dissertations

Companies have primarily been focusing on the financial bottom line i.e., on increasing profits by increasing revenues and reducing costs. With high energy usage and environmental change posing threats to the environment and business operations, companies are now considering sustainability. Since some global suppliers have low cost labor, Social well-being and human development has also emerged as major goals of a company performing global operations. Focusing on these three goals is termed the "Triple Bottom Line" (TBL). We study and explore the TBL benefits that could be realized by an oil and gas company by focusing on sustainable suppliers. A …

Incorporating Environmental And Social Factors Into Decision-Making Of An Oil And Gas Industry To Improve Sustainability, Gaurav Dabhadkar

Graduate Theses and Dissertations

The energy industry (including the oil and gas industry) is facing unparalleled scrutiny and demands from stakeholders including investors, regulators (industry and environmental), communities, and other stakeholders. Sustainable development is one of the major concerns of the oil and gas industry. Companies are seeking to increase sustainability of their operations by considering environmental and Social concerns in addition to economic concerns. Oil and gas companies need to take decisions at different stages of the product life cycle (e.g. planning, design, exploration, production, and clean-up) which have direct or indirect impact on the organization's objectives. Addressing economic, technical, Social, and environmental …

Switchgrass Cultivar, Harvest Frequency, Fertilizer Source, And Irrigation Effects On Near-Surface Soil Properties In West-Central Arkansas, Alayna A. Jacobs

Graduate Theses and Dissertations

Switchgrass (Panicum virgatum L.) has been identified as a model bioenergy feedstock crop and is expected to become an important feedstock for future renewable fuel generation. Agronomic management combinations that maximize monoculture switchgrass yield are generally well understood; however, little is known about corresponding effects of differing switchgrass management combinations on near-surface soil properties. The objective of this research was to determine the residual near-surface soil property effects of three years (2008 to 2011) of consistent management combinations to maximize switchgrass biomass production, including cultivar (‘Alamo’ and ‘Cave-in-Rock’), harvest frequency (1-cut and 2-cut systems per year), fertilizer source (poultry …

Carbon Dioxide Emissions From Switchgrass And Cottonwood Grown As Bioenergy Crops In The Lower Mississippi Alluvial Valley, Michele Lea Helton

Graduate Theses and Dissertations

Marginal land of the Lower Mississippi Alluvial Valley (LMAV) has the potential to be utilized for the production of bioenergy feedstocks. Soil respiration is the gaseous emission of carbon dioxide (CO₂) from microbes and plant roots in the soil, and these emissions play an important role in the global cycling of carbon. Soil respiration can act as a positive feedback affecting climate change, and has been shown to vary depending on soil moisture, temperature, and vegetation. The objectives of this study where to evaluate the effects of land use [switchgrass (Panicum virgatum), cottonwood (Populus deltoides …

Life Cycle Assessment Projection Of Photovoltaic Cells: A Case Study On Energy Demand Of Quantum Wire Based Photovoltaic Technology Research, Shilpi Mukherjee

Graduate Theses and Dissertations

With increasing clean-energy demand, photovoltaic (PV) technologies have gained attention as potential long-term alternative to fossil fuel energy. However, PV research and manufacture still utilize fossil fuel-powered grid electricity. With continuous enhancement of solar conversion efficiency, it is imperative to assess whether overall life cycle efficiency is also being enhanced. Many new-material PV technologies are still in their research phase, and life cycle analyses of these technologies have not yet been performed. For best results, grid dependency must be minimized for PV research, and this can be accomplished by an analytical instrument called Life Cycle Assessment (LCA).

LCA is the …

A Roadmap To Mindful Consumption Through Informative Labeling Practices: The Effects Of Sustainability Disclosure Formats On Consumer Product Evaluations, Yoon-Na Cho

Graduate Theses and Dissertations

Despite the interest of consumers in sustainable and environmentally friendly products, only a limited number of studies have focused on sustainability level disclosures for consumer packaged goods. The general overarching purpose of this dissertation is to extend the internal reference point and information processing literatures to better understand how consumers will process sustainability disclosures. Applying the theoretical lens of assimilation bias in conjunction with self-enhancement offers an important extension to prior work. Across two retail lab studies and four online experiments, I demonstrate that the perceived sustainability utility (i.e., the difference between a specific brand's level of sustainability and category-level …

The Use Of Non-Traditional Technologies To Improve The Efficiency And Sustainability Of Modern Poultry Production, Christopher Pixley

Graduate Theses and Dissertations

Historically, major driving factors for the animal agriculture industry have been efficiency and profitability. As demand for efficient food production has increased, the industry has focused research efforts on ways to improve the rearing process. Current market demands are requiring the industry to abandon some of the traditional tools it has used to maximize productivity. However, developing alternative technologies are available which may fill the void. Unfortunately, these alternatives are less well-described and the beneficial impacts they can have are not fully understood. As the animal agriculture industry matures it is becoming evident that consumers will continue to demand methods …

A Critical Examination Of The Stormwater Education, Based On Sites Parameters, In Landscape Architecture Departments In The Sec, Brandon Doss

Landscape Architecture Undergraduate Honors Theses

The amount of accessible natural resources is dwindling and water could be the next world crisis. One response to this issue is the creation of methodologies which evaluate sustainability of new land development. A system to address the issues is the Sustainable Sites Initiative. This method was created in 2009 by the American Society of Landscape Architects, the Lady Bird Johnson Wildflower Center, and the United States Botanic Garden. Their primary goal was to create a metric for rating development to encourage a more sustainable approach. A piece of this evaluation is water management. Landscape architecture is poised to address …

Student Motivation For Pursuing A Minor In Environmental Sustainability, Luanne Woods Lewis

Graduate Theses and Dissertations

Environmental sustainability dominates the global conversation seeking to increase awareness and change the culture of thinking concerning the relationship between humans and the Earth. Because many universities offer programs relative to environmental sustainability, a need exists to understand why students pursue these programs. This study examined student motivation for pursuing an environmental sustainability minor in one institution of higher education. Career, learning, monetary, and Social responsibility were the motivational factors considered in this study. The results of this study indicated significant differences among the motivational factors for pursuing a minor in sustainability among those students surveyed. Significant differences existed for …

Role Of Vegetation And Environmental Characteristics On Slope Stability In Northwest Arkansas, Michael Maguigan

Graduate Theses and Dissertations

Slope failure continues to pose risks to society because knowledge of environmental factors and their interactions are unclear and possibly misunderstood. This misunderstanding leads to generalizations about slope failure susceptibility mapping, despite knowing that slope failures are likely the result of an extensively complex set of interactions among a number of environmental, edaphic, and geomorphic characteristics. Therefore a series of experiments were conducted to investigate the effects of slope, soil texture, vegetation cover, bedrock permeability, and compaction,. A wooden flume with a slope face 1 m wide by 1.5 m long with a 10 cm toe was constructed to contain …

Identifying Optimal Cellulosic Biomass Feedstock Supply Areas For Potential Biorefineries In Arkansas, Mark Cooper

Graduate Theses and Dissertations

In February 2010, the U.S. Environmental Protection Agency released the revised Renewable Fuel Standard (RFS2), mandating at least 36 billion gallons of renewable fuels to be produced annually in America, and blended into all on/off road, locomotive, and marine gasoline and diesel by the year 2022. America's existing biorefineries fall significantly short of being able to meet this mandate, resulting in the need for rapid expansion in the near future if this goal is to be met. The state of Arkansas has abundant resources to offer the renewable energy industry, if properly utilized. The goal of this thesis is to …

Subcritical Water Hydrolysis Of Whey Proteins, Ashley Dawn Espinoza

Graduate Theses and Dissertations

Hydrolyzing food by-products is a unique approach to potentially increase by-product value and reduce waste. An abundant by-product of cheese production, whey, contains all essential amino acids and some distinctive peptides with functional and nutraceutical properties. Typically, proteins from whey are tailored for specific uses by chemical or enzymatic hydrolysis; however, subcritical water hydrolysis is a novel alternative used successfully to hydrolyze various substrates. Nevertheless, minimal research exists on: (1) the hydrolysis of whey protein; (2) the incorporation of additives; (3) the hydrolysis of whole whey; and (4) the production of volatiles when using subcritical water hydrolysis.

Therefore, whey protein …