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- Oxygen reduction reaction (6)
- Electrodeposition (5)
- Proton exchange membrane fuel cell (5)
- Electrocatalysis (4)
- Electrochemical performance (4)
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- Fuel cells (4)
- Anode materials (3)
- Atomic force microscopy (3)
- Cathode (3)
- Cyclic voltammetry (3)
- Electrocatalysts (3)
- Oxygen evolution reaction (3)
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- Anode (2)
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- Copper sulfide (2)
- Dynamic plastic deformation (2)
- Electric wire explosion (2)
- Electrochemical impedance spectroscopy (2)
- Electrochemistry (2)
- Electrolyte (2)
- Electrospinning (2)
- Fluorescence (2)
- Lithium ion batteries (2)
- Lithium ion battery (2)
- Low temperature performance (2)
- Magnetic pulse compaction (2)
- Manganese oxide (2)
- Metal matrix composite (2)
- Nanotubes (2)
Articles 1 - 30 of 106
Full-Text Articles in Physical Sciences and Mathematics
Progress Of Self-Humidifying Membrane Electrode Assembly For Low Temperature Proton Exchange Membrane Fuel Cell, Bin Chi, Yue-Kun Ye, Shi-Jie Jiang, Shi-Jun Liao
Progress Of Self-Humidifying Membrane Electrode Assembly For Low Temperature Proton Exchange Membrane Fuel Cell, Bin Chi, Yue-Kun Ye, Shi-Jie Jiang, Shi-Jun Liao
Journal of Electrochemistry
The self/non-humidification membrane electrode assembly（SH-MEA）is an important pathway towards the self- humidification fuel cell and plays a crucial role for the large scale commercialization of low temperature proton exchange membrane fuel cell (LT-PEMFC), because it not only can reduce the volume and complexity of fuel cell system, resulting in the decrease of the cost, but also can improve the output power density of the fuel cell system. Currently, the researches on the self-humidifying MEA of LT-PEMFC mainly focus on three aspects: the preparation of self-humidification proton exchange membrane, the construction of self-humidification catalyst layer, and the construction of composite self-humidifying …
A Review Of Proton Exchange Membrane Fuel Cell Catalyst Layer By Electrospinning, Yong Liu, Han Ding, De-Chun Si, Jie Peng, Jian-Bo Zhang
A Review Of Proton Exchange Membrane Fuel Cell Catalyst Layer By Electrospinning, Yong Liu, Han Ding, De-Chun Si, Jie Peng, Jian-Bo Zhang
Journal of Electrochemistry
The limitation of catalyst layer for proton exchange membrane fuel cell (PEMFC) in cost, durability and performance constitutes the bottleneck for the commercialization of fuel cell vehicles. Electrospun catalyst layer, with high catalyst utilization, increased triple phase boundary (TPB) and triple phase channel (TPC), has been developed by many researchers. This paper reviews the research progress in the electrospun catalyst layer for PEMFC, combined with the author’s work. Firstly, the development progress of catalyst layer is summarized, and the catalyst layer is classified and analyzed based on its fabrication method and structure character. Next, the fabrication process, physical property characterization, …
Effects Of So2 In Air On Performance Of Direct Methanol Fuel Cell, Bin Qin, Fen-Ning Jing, Xue-Jing Sun, Gong-Quan Sun, Hai Sun
Effects Of So2 In Air On Performance Of Direct Methanol Fuel Cell, Bin Qin, Fen-Ning Jing, Xue-Jing Sun, Gong-Quan Sun, Hai Sun
Journal of Electrochemistry
Direct methanol fuel cells (DMFC) generally use oxygen as an oxidant. Contaminants such as sulfides and nitrides in the air can affect the performance of the DMFC. In this work, the effects of SO2 on the performance of DMFC were investigated and the mechanism of poisoning was analyzed, by means of constant current discharge curve, polarization performance curve, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). In the CV scan, the permeated methanol was oxidized at a low potential to eliminate its effect on the SO2 poisoning behavior test. The results showed that the SO2 poisoning resulted …
Fe-N Doped Hollow Carbon Nanospheres Linked By Carbon Nanotubes For Oxygen Reduction Reaction, Ya-Lin Zhang, Chi Chen, Liang-Liang Zou, Zhi-Qing Zou, Hui Yang
Fe-N Doped Hollow Carbon Nanospheres Linked By Carbon Nanotubes For Oxygen Reduction Reaction, Ya-Lin Zhang, Chi Chen, Liang-Liang Zou, Zhi-Qing Zou, Hui Yang
Journal of Electrochemistry
The development of non-precious metal catalysts for oxygen reduction reaction (ORR) is essential for large-scale application of proton exchange membrane fuel cells. Herein, we present the in situ formed Fe-N doped hollow carbon nanospheres linked by carbon nanotubes composite, synthesized by using ZIF-8 as sacrificed template to form polydopamine (PDA) hollow nanospheres, followed by complexing with FeCl3, high temperature heat-treatment and NH3-etching. ZIF-8 was gradually decomposed simultaneously with PDA coating due to the loss of Zn2+ grabbed by PDA. NH3 etching resulted in the improved surface area, while the reducibility of NH3 resulted in …
Acid Treated Carbon As Anodic Electrocatalysts Toward Direct Ascorbic Acid Alkaline Membrane Fuel Cells, He-Mu Chen, Chen-Xi Qiu, Yuan-Yuan Cong, Hui-Yuan Liu, Zi-Hui Zhai, Yu-Jiang Song
Acid Treated Carbon As Anodic Electrocatalysts Toward Direct Ascorbic Acid Alkaline Membrane Fuel Cells, He-Mu Chen, Chen-Xi Qiu, Yuan-Yuan Cong, Hui-Yuan Liu, Zi-Hui Zhai, Yu-Jiang Song
Journal of Electrochemistry
In order to improve the hydrophilicity and electrocatalytic activity, commercial carbon black (BP 2000) was subjected to acid treatment to obtain acid-treated carbon (ATC). The generation of rich oxygen-containing groups on the surface of the ATC was proved by X-ray photoelectron spectra (XPS), Fourier transform-infra red spectra (FTIR), thermogravimetric analysis (TG) and contact angle measurement. UV-vis spectra were firstly recorded to calculate activation energy (Ea) of ascorbic acid (AA) chemical oxidation in alkaline conditions by oxygen in air and the Ea value was determined to be 37.1 kJ·mol-1. Additionally, electrochemical impedance spectra (EIS) were used to evaluate unprecedented …
Durability Performance Of The High-Power Fuel Cell System, Ke-Yong Wang, Wei-Yu Shi, Ren-Fang Wang, Jia Liu, Zhong-Jun Hou
Durability Performance Of The High-Power Fuel Cell System, Ke-Yong Wang, Wei-Yu Shi, Ren-Fang Wang, Jia Liu, Zhong-Jun Hou
Journal of Electrochemistry
Fuel cell durability is the crucial challenge in fuel cell vehicle, and the lifetime of more than 5000 hours is believed to be necessary for vehicle application. Few works on durability test of the full fuel cell system have been reported. In this work, the long lifetime HySYS-30 fuel cell system was developed in Sunrise Power based on the improved MEA durability and system control strategy. The durability performance of the system was investigated under vehicle duty cycle for more than 6000 hours, and only 8.1% performance loss was observed, implying that the durability of HySYS-30 fuel cell system could …
Recent Progress In Pt-Based Catalysts For Oxygen Reduction Reaction, Jing Li, Xin Feng, Zi-Dong Wei
Recent Progress In Pt-Based Catalysts For Oxygen Reduction Reaction, Jing Li, Xin Feng, Zi-Dong Wei
Journal of Electrochemistry
One major challenge for a large-scale commercialization of the proton-exchange membrane fuel cells (PEMFCs) technologies that enable a shift to ‘zero-emission’ personal transportation, is the expensive and unstable Pt catalysts, which are mainly used to catalyze the sluggish kinetics of the oxygen reduction reaction (ORR) occurred on the air electrode of PEMFCs. Many research works have targets to improve the stability of Pt-based catalysts and to construct Pt/transitional metal alloys with low Pt loading amount. Herein, we provide a minireview for the Pt-based ORR catalysts based on our recent work, which covers a brief background introduction, the stability improvement of …
Caging Porous Co-N-C Nanocomposites In 3d Graphene As Active And Aggregation-Resistant Electrocatalyst For Oxygen Reduction Reaction, Lu-Yang Xiu, Meng-Zhou Yu, Peng-Ju Yang, Zhi-Yu Wang, Jie-Shan Qiu
Caging Porous Co-N-C Nanocomposites In 3d Graphene As Active And Aggregation-Resistant Electrocatalyst For Oxygen Reduction Reaction, Lu-Yang Xiu, Meng-Zhou Yu, Peng-Ju Yang, Zhi-Yu Wang, Jie-Shan Qiu
Journal of Electrochemistry
Oxygen reduction reaction (ORR) is the cornerstone reaction of many renewable energy technologies such as fuel cells and rechargeable metal-air batteries. The Pt-based electrocatalysts exhibit the highest activity toward ORR, but their large implementation is greatly prohibiting by unaffordable cost and inferior durability. During electrode manufacturing and electrochemical reaction, severe aggregation of catalyst nanoparticles induced by size effect further limits the operational performance of electrocatalysts. We report a new strategy for fabrication of active and aggregation-resistant ORR electrocatalyst by caging metal-organic frameworks derived Co-N-C nanocomposites in permeable and porous 3D graphene cages via sprayed drying the mixed colloids of ZIF-67 …
Palladium Adatoms On Gold Nanoparticles As Electrocatalysts For Ethanol Electro-Oxidation In Alkaline Solutions, Hui-Mei Chen, Shang-Qian Zhu, Jia-Le Huang, Min-Hua Shao
Palladium Adatoms On Gold Nanoparticles As Electrocatalysts For Ethanol Electro-Oxidation In Alkaline Solutions, Hui-Mei Chen, Shang-Qian Zhu, Jia-Le Huang, Min-Hua Shao
Journal of Electrochemistry
Palladium (Pd) is a good catalyst for ethanol electro-oxidation in alkaline solutions. The activity of Pd is further improved in this study by modifying the gold (Au) nanoparticles with Pd adatoms using a simple spontaneous deposition process. The Pd overlayer on the Au core (Au@Pd) is un-uniform with some Au atoms exposed to the electrolyte. The activity of Au@Pd/C toward ethanol oxidation reaction (EOR) is much higher than that of Pd/C in an alkaline solution. The peak current density of Au@Pd/C is 4.6 times higher than that of Pd/C with a 100 mV lower onset potential. The enhanced activity may …
Stabilization Strategies Of Pt Catalysts Forproton Exchange Membrane Fuel Cells, Da-Ping He, Shi-Chun Mu
Stabilization Strategies Of Pt Catalysts Forproton Exchange Membrane Fuel Cells, Da-Ping He, Shi-Chun Mu
Journal of Electrochemistry
The low service lifetime of proton exchange membrane fuel cells (PEMFCs) is the main bottleneck for their commercial applications. One of the main factors is that the expensive metal Pt catalyst is easy to degradation under the harsh working environment of PEMFC (such as variable voltage, strong acidity, gas-liquid two-phase flow), which leads to the inevitable decay of the catalytic performance, thus, seriously restricting the lifetime of PEMFC. Therefore, the electrochemical stability of Pt-based electrocatalysts has become an important and hot topic to improve the PEMFC lifetime. In this paper, we review the recent development in enhancing the stability of …
Research Progress In Hydrogen Evolution Low Noble/Non-Precious Metal Catalysts Of Water Electrolysis, Yang Li, Zhao-Yan Luo, Jun-Jie Ge, Chang-Peng Liu, Wei Xing
Research Progress In Hydrogen Evolution Low Noble/Non-Precious Metal Catalysts Of Water Electrolysis, Yang Li, Zhao-Yan Luo, Jun-Jie Ge, Chang-Peng Liu, Wei Xing
Journal of Electrochemistry
Hydrogen energy technology with hydrogen as an energy carrier is gaining more and more attention due to its cleanliness and high energy density. Hydrogen fuel cell vehicles have been listed as one of the ultimate energy technologies in the 21st century. Among them, sustainable hydrogen production technology is a necessary prerequisite for the future development of hydrogen energy economy. Electrolyzed water technology driven by renewable resources represents an important way to support the sustainable development of hydrogen energy economy. The development and utilization of high activity, low cost hydrogen evolution catalysts is a key factor in improving the efficiency and …
Fuel Cells Reactor For Chemicals And Electric Energy Cogeneration, Zhi-Lin Heng, Xiao-Zi Yuan, Yi-Mei Yin, Zi-Feng Ma
Fuel Cells Reactor For Chemicals And Electric Energy Cogeneration, Zhi-Lin Heng, Xiao-Zi Yuan, Yi-Mei Yin, Zi-Feng Ma
Journal of Electrochemistry
As an energy conversion device, fuel cells can efficiently convert chemical energy into electrical energy. With the developing of technology, it is used as a reactor to conduct the synthesis of high value-added chemicals while generating electrical energy. Having benefits such as mild reaction conditions, controllability of the reaction process, high selectivity of the product, as well as high efficiency of energy utilization, it is widely used in many fields such as preparation of high value-added industrial products, gas separation, water treatment, etc. This paper introduces the current trends and statuses of fuel cell reactors in the cogeneration of chemicals …
The Pilot Application Of Electrochemical Impedance Spectroscopy On Dynamic Proton Exchange Membrane Fuel Cell, Jian-Wei Guo, Jian-Long Wang
The Pilot Application Of Electrochemical Impedance Spectroscopy On Dynamic Proton Exchange Membrane Fuel Cell, Jian-Wei Guo, Jian-Long Wang
Journal of Electrochemistry
By analyzing Electrochemical Impedance Spectroscopy (EIS) in applications of dynamic proton exchange membrane fuel cell (PEMFC), bottlenecks which restrict EIS tool development have been pointed out in this paper. Though the high-frequency resistance in EIS is largely accepted as cell inner-resistance, this can only be applied for cell with low current. The low-frequency resistance is difficult to be realized due to its relation with mass transfer. Furthermore, the improved Randles equivalent circuits are built up preliminarily, thus, penetrating into studies for mass transfer reaction, cell operation/degeneration, and high temperature fuel cell. Inspiringly, EIS is becoming an analyzing tool for stack …
Facile Synthesis Of Pt-Cu Alloy Nanodendrites As High-Performance Electrocatalysts For Oxygen Reduction Reaction, Liu-Xuan Luo, Guang-Hua Wei, Shui-Yun Shen, Feng-Juan Zhu, Chang-Chun Ke, Xiao-Hui Yan, Jun-Liang Zhang
Facile Synthesis Of Pt-Cu Alloy Nanodendrites As High-Performance Electrocatalysts For Oxygen Reduction Reaction, Liu-Xuan Luo, Guang-Hua Wei, Shui-Yun Shen, Feng-Juan Zhu, Chang-Chun Ke, Xiao-Hui Yan, Jun-Liang Zhang
Journal of Electrochemistry
Structures and compositions have significant effects on the catalytic properties of nanomaterials. Herein, a facile etching-based method was employed to synthesize Pt-Cu nanodendrites (NDs) with uniform and homogeneous alloy structures for enhancing oxygen reduction reaction (ORR). The formation of dendritic morphology was ascribed to the etching effect caused by the oxidative etchants of the Br-/O2 pair. The atomic ratio of Pt/Cu in Pt-Cu NDs could be easily tuned by altering the ratio of the Pt/Cu precursors, without deteriorating the dendritic morphology. The most active carbon-supported Pt1Cu1 NDs (Pt1Cu1 NDs/C) exhibited the …
Pd/C Catalysts For Co2 Electroreduction To Co:Pd Loading Effect, Dun-Feng Gao, Cheng-Cheng Yan, Guo-Xiong Wang, Xin-He Bao
Pd/C Catalysts For Co2 Electroreduction To Co:Pd Loading Effect, Dun-Feng Gao, Cheng-Cheng Yan, Guo-Xiong Wang, Xin-He Bao
Journal of Electrochemistry
Nanostructured heterogeneous catalysts have been widely used in the electrochemical carbon dioxide (CO2) reduction reaction (CO2RR), which can simultaneously achieve the electrocatalytic conversion of CO2 to fuels and the storage of renewable energy sources. Carbon supported palladium nanoparticles (Pd/C) catalysts have been previously reported to show excellent CO2RR performance. However, the crucial role of the metal loading in supported electrocatalysts has been rarely reported. In this work, we study the Pd loading effect on the structure of Pd/C catalysts as well as their activity and selectivity of CO2RR to CO. The …
Morphological Control Of Ptcu2 Octahedron And Oxygen Reduction Electrocatalytic Performance Of Ptcu For Fuel Cell, Long-Sheng Cao, Lei Wan, Zhi-Gang Shao, Hong-Mei Yu, Ming Hou, Bao-Lian Yi
Morphological Control Of Ptcu2 Octahedron And Oxygen Reduction Electrocatalytic Performance Of Ptcu For Fuel Cell, Long-Sheng Cao, Lei Wan, Zhi-Gang Shao, Hong-Mei Yu, Ming Hou, Bao-Lian Yi
Journal of Electrochemistry
Platinum acetylacetonate (Pt(acac)2) and copper acetylacetonate (Cu(acac)2) were co-reduced to prepare PtCu2 octahedron alloy catalyst in N,N-dimethylformamiade by solvothermal method. The PtCu2 showed lattice compression, and high ratio of non-oxidized Pt with high electronic binding energy. All those structural features contributed to weak adsorption strength of oxygen species on Pt and lower d-band centre position. The influence of structure-directing agent on morphology of PtCu alloy was systematically studied. In the half cell test, as a result of the uniform morphology and regular octahedron of PtCu2 formed, the mass activity and area specific activity …
Fuel Cell Performance Curve After Mea Optimization Structural Optimization Of Low Pt Membrane Electrode Assembly, Yan Rao, Shang Li, Fen Zhou, Tian Tian, Qing Zhong, Zhao-Hui Wan, Jin-Ting Tan, Mu Pan
Fuel Cell Performance Curve After Mea Optimization Structural Optimization Of Low Pt Membrane Electrode Assembly, Yan Rao, Shang Li, Fen Zhou, Tian Tian, Qing Zhong, Zhao-Hui Wan, Jin-Ting Tan, Mu Pan
Journal of Electrochemistry
Membrane electrode assemblies (MEAs) are the key component of proton exchange membrane fuel cell. For a long time, much attention has been paid to develop MEA technology. At present, the research, development and industrialization of fuel cell has entered a new era. More strict requirements for MEA, especially for the reduction of Pt loading with a challenging target of 0.125 mg·W-1 have to be met. In this paper, the performance losses under low Pt loading are analyzed in terms of activation polarization, ohm polarization and mass-transfer polarization. It is proposed that research should be focused on the activity of …
System And Process Of Thermal Neutron Flux Producing By Means Of An Accelerator Base Electron Of 18 Mev, A. Didi, A. Dadouch, H. El Bekkour, O. Jai, F. Bouhal, M. Bencheikh
System And Process Of Thermal Neutron Flux Producing By Means Of An Accelerator Base Electron Of 18 Mev, A. Didi, A. Dadouch, H. El Bekkour, O. Jai, F. Bouhal, M. Bencheikh
Eurasian Journal of Physics and Functional Materials
Neutrons are produced in accelerators by irradiating heavy targets with an electron or proton beam. Produced neutrons are of high energy. The purpose of our work is optimization the neutron flux by MCNP-6 code for production the thermal neutron flux using a moderator and for convertation the fast neutron flux into a thermal neutron flux. In this article, we are interested in a thermal neutron flux due it is useful for method of neutron activation analysis. In conventional sources, the moderator is usually a large volume of water or paraffin around the source. Initially, fast neutrons have energy above 1 …
Structure Study Of Al+Al2o3 Composite By Atomic Force Microscopy, D. S. Koleukh, A. S. Kaygorodov, S. V. Zayats, S. N. Paranin
Structure Study Of Al+Al2o3 Composite By Atomic Force Microscopy, D. S. Koleukh, A. S. Kaygorodov, S. V. Zayats, S. N. Paranin
Eurasian Journal of Physics and Functional Materials
The structure of a metal matrix composite based on aluminum containing 6, 17 and 24 wt % Al2 O3 was studied by atomic force microscopy. The composite was prepared by the method of magneticpulse compaction from aluminum nanopowder obtained by the electric wire explosion method. The samples compacted at 400 ◦ C have more clearly expressed grain boundaries than those obtained at room temperature. The structure of a composite subjected to dynamic plastic deformation is studied.
Synthesis And Investigation Of Optical Properties Of Cdse Quantum Dots With High Quantum Luminescence Yield, A. Z. Kainarbay, T. N. Nurakhmetov, Z. M. Salikhodja, A. M. Zhunusbekov, D. K. Daurenbekov, B. Sadykova, B. Yussupbekova, K. Zhanylysov, A. Kainarbayeva, N. Adalbek, N. Shaken, A. Turmakhanbetova, K. N. Balabekov
Synthesis And Investigation Of Optical Properties Of Cdse Quantum Dots With High Quantum Luminescence Yield, A. Z. Kainarbay, T. N. Nurakhmetov, Z. M. Salikhodja, A. M. Zhunusbekov, D. K. Daurenbekov, B. Sadykova, B. Yussupbekova, K. Zhanylysov, A. Kainarbayeva, N. Adalbek, N. Shaken, A. Turmakhanbetova, K. N. Balabekov
Eurasian Journal of Physics and Functional Materials
In the present work, an attempt to obtain quantum dots with a high quantum luminescence yield has been made. For this purpose, the existing methods of synthesis have been studied; approbation of availability and reproducibility of the results and possibility of obtaining luminescent QD samples in the required spectral region has been made. The optical characteristics, the influence of the synthesis conditions, the possibility of using nanostructured materials for sensitization of solar cells have been studied.
Some Radiation Effects In Ii-Vi Quantum Dots, M. B. Sharibaev, Q. A. Ismailov
Some Radiation Effects In Ii-Vi Quantum Dots, M. B. Sharibaev, Q. A. Ismailov
Eurasian Journal of Physics and Functional Materials
The effect of electron irradiation (E=0.6-1.8 MeV) on the optical characteristics (photoluminescence, PL) of CdTe/ZnTe structures with quantum dots, QDs, was investigated in the temperature range from 4.2 to 250 K. The data on the influence of irradiation on the temperature dependence of PL intensity, energy position and PL line width, W, from QDs were obtained. The narrowing of PL band and the blue shift of the QD peak position are explained by quenching of the low energy component connected with larger QDs. A slight decrease in PL intensity for both QDs and the buffer ZnTe layer as well as …
Influence Of Structural Defects In Silicon On Formation Of Photosensitive Heterostructures Mn4si7-Si-Mn4si7 And Mn4si7-Si-M, T. S. Kamilov, A. S. Rysbaev, V. V. Klechkovskaya, A. S. Orekhov, Sh. Kh. Dzhuraev, A. S. Kasymov
Influence Of Structural Defects In Silicon On Formation Of Photosensitive Heterostructures Mn4si7-Si-Mn4si7 And Mn4si7-Si-M, T. S. Kamilov, A. S. Rysbaev, V. V. Klechkovskaya, A. S. Orekhov, Sh. Kh. Dzhuraev, A. S. Kasymov
Eurasian Journal of Physics and Functional Materials
The paper considers the influence of a transition amorphous layer at the interface between the higher manganese silicide (HMS) Mn 4 Si 7 and silicon doped with manganese (Si ) on the photoelectric properties of heterostructures. The role of the initial structural defects in the near-surface layers of the single-crystal silicon on the penetration of manganese atoms into Si upon doping from the gas phase is shown.It has been established that at high temperatures (T>1050 ◦ C) Mn atoms deposited on the silicon surface group together (due to surface diffusion), forming droplets of liquid manganese, which dissolve the near-surface …
Development Of Thermal Sensors By Implantation Ions P+ And B+ In Different Sides Of Si(111), I. R. Bekpulatov, A. S. Rysbaev, Sh. Kh. Dzhuraev, A. S. Kasymov
Development Of Thermal Sensors By Implantation Ions P+ And B+ In Different Sides Of Si(111), I. R. Bekpulatov, A. S. Rysbaev, Sh. Kh. Dzhuraev, A. S. Kasymov
Eurasian Journal of Physics and Functional Materials
In the method of high-phase ion implantation of P + and B + to different sides of monocrystal silicon we obtained p-i-n- structure, which has a high thermal sensitivity of 2.3 mV/K in a broad band temperature of (20 ÷ 550) K. We studied the distribution profile P and B atoms implanted in the Si gradually decreasing energy. The effect of the subsequent thermal and annealing IR profile on the distribution of the atoms and the characteristics of the temperature sensor was studied.
New Mocd2 Phase In Film Coatings Of Molybdenum-Cadmium System, Yu. Zh. Tuleushev, V. N. Volodin, Y. A. Zhakanbaev
New Mocd2 Phase In Film Coatings Of Molybdenum-Cadmium System, Yu. Zh. Tuleushev, V. N. Volodin, Y. A. Zhakanbaev
Eurasian Journal of Physics and Functional Materials
Ion-plasma sputtering and code position of Mo and Cd ultrafine particles have been used for the first time to prepare solid solutions that are alloys with a concentration up to 57.3 at. % Cd in the film; this confirms the thermal-fluctuation and coalescence of small particles. When coatings are formed by molyb-denum and cadmium nanolayers less than 2 nm in the concentrations range of 60-66 at. % Cd, a new phase was found that was prepared directly in the course of film coating formation; it was identified as the MoCd2 compound with a tetragonal face-centered lattice, with the parameters …
Different Methods Of Correcting The Readings Of The Dvgn-01 Albedo Neutron Dosimeter Placed Behind The Ibr-2m Protection, Yu. V. Mokrov, S. V. Morozova, G. N. Timoshenko, V. A. Krylov, O. B. Badunov, G. A. Seilkhanova
Different Methods Of Correcting The Readings Of The Dvgn-01 Albedo Neutron Dosimeter Placed Behind The Ibr-2m Protection, Yu. V. Mokrov, S. V. Morozova, G. N. Timoshenko, V. A. Krylov, O. B. Badunov, G. A. Seilkhanova
Eurasian Journal of Physics and Functional Materials
The paper presents the results of correction of readings of DVBN-01 albedo dosimeters behind IBR-2M protection, the Neutron Physics Laboratory of the Joint Institute for Nuclear Research (JINR), Dubna, byvarious methods. The neutron spectra were measured at two points behind the IBR-2M protection in the experimental halls, and measurements were carried out with the spherical albedo system at these points. The correction coefficients for DVGN-01 were calculated from the measured spectra based on the data of the spherical albedo system. A good agreement of the coefficients calculated by different methods is shown, which indicates the reliability of the obtained values …
Analysis Of (11li+9be)-Reaction In The Framework Of The Time-Dependent Schrodinger Equation, A. K. Azhibekov, K. A. Kuterbekov, V. V. Samarin
Analysis Of (11li+9be)-Reaction In The Framework Of The Time-Dependent Schrodinger Equation, A. K. Azhibekov, K. A. Kuterbekov, V. V. Samarin
Eurasian Journal of Physics and Functional Materials
Neutron transfer and nucleus breakup cross sections in (11Li + 9Be) -reaction are calculated at energy range up to 32 MeV/nucleon. The evolution of probability density of external weakly bound neutrons of 11Li and the probabilities of neutron transfer and nucleus breakup are determined based on a numerical solution of the time-dependent Schrodinger equation. Our calculation results are agree with the experiment.
Recent Process In Transition-Metal-Oxide Based Catalysts For Oxygen Reduction Reaction, Yao Wang, Zi-Dong Wei
Recent Process In Transition-Metal-Oxide Based Catalysts For Oxygen Reduction Reaction, Yao Wang, Zi-Dong Wei
Journal of Electrochemistry
Transition metal oxides (TMOs) based catalysts have become the most promising catalysts to be employed in anion exchange membrane fuel cell for the sluggish oxygen reduction reaction (ORR). However, their ORR activity is still far from that of the Pt-based catalysts. Therefore, it is important to develop high performance TMO based catalysts. Electrical conductivity and intrinsic activity have been regarded as the two keys to affect the ORR activity of the TMOs based catalysts. In this review, we focused on the recent progresses in the fundamental viewpoints on the electrical conductivity and intrinsic activity of the TMOs based ORR catalysts. …
Effects Of Sulfur-Containing Additive On Low Temperature Performance Of Graphite Anode, Ze-Li Wu, Ye-Zhen Zheng, Zhong-Ru Zhang, Yong Yang
Effects Of Sulfur-Containing Additive On Low Temperature Performance Of Graphite Anode, Ze-Li Wu, Ye-Zhen Zheng, Zhong-Ru Zhang, Yong Yang
Journal of Electrochemistry
The low temperature performance of lithium ion battery mainly depends on the graphite anode, and one of the research focuses is to improve the low temperature performance of the anode by additives. In this paper, the effects of different sulfur-containing functional groups such as DTD (ethylene sulfate), 1,3-PS (1,3-propane sultone) and ES (ethylene sulfite) on low temperature performances of artificial graphite materials were systematically studied. The results in density functional theory (DFT) calculations, cyclic voltammetry (CV), scanning electron microscopy (SEM) and charge-discharge measurement clearly demonstrated that all three sulfur-containing additives could participate in formation of films on the surface of …
Recent Advances In Non-Noble Metal Nanomaterials For Oxygen Evolution Electrocatalysis, Dan-Dan Zhao, Nan Zhang, Ling-Zheng Bu, Qi Shao, Xiao-Qing Huang
Recent Advances In Non-Noble Metal Nanomaterials For Oxygen Evolution Electrocatalysis, Dan-Dan Zhao, Nan Zhang, Ling-Zheng Bu, Qi Shao, Xiao-Qing Huang
Journal of Electrochemistry
Hydrogen is a kind of renewable energies with the merits of environmentally friendly, abundance and high weight energy density, which can replace the fossil energy. The electrolysis of water is regarded as the most effective way to generate hydrogen. Owing to the sluggish kinetics and large overpotential of the anode oxygen evolution reaction (OER), the efficiency of the cathode hydrogen evolution reaction is greatly limited. Therefore, it is highly desirable to explore efficient, stable and low cost electrocatalysts to reduce the overpotential of OER and improve the efficiency of hydrogen evolution. Based on the natural characteristics of non-noble metal catalysts …
Research Progresses In Improvement For Low Temperature Performance Of Lithium-Ion Batteries, Yue-Ru Gu, Wei-Min Zhao, Chang-Hu Su, Chuan-Jun Luo, Zhong-Ru Zhang, Xu-Jin Xue, Yong Yang
Research Progresses In Improvement For Low Temperature Performance Of Lithium-Ion Batteries, Yue-Ru Gu, Wei-Min Zhao, Chang-Hu Su, Chuan-Jun Luo, Zhong-Ru Zhang, Xu-Jin Xue, Yong Yang
Journal of Electrochemistry
Lithium-ion batteries (LIBs) have become a new research hotspot due to their high energy density and long service life. However, the temperature characteristics, especially the poor performance at low temperatures, have seriously limited their wider applications. In this report, the research progresses in the low temperature performance of LIBs are reviewed. The main existing limitations of LIBs at low temperatures were systematically analyzed, and followed by discussion on the recent improvements in low temperature performances by developing novel cathode, electrolyte, and anode materials. The developments for improving the low temperature performance of LIBs are prospected. The three most important factors …