Physical Sciences and Mathematics Commons^™

Microstructures And Quartz Lattice-Preferred Orientations In The Eclogite-Bearing Migmatitic Gneisses Of The D’Entrecasteaux Islands, Papua New Guinea, T. A. Little, B. R. Hacker, S. J. Brownlee, G. Seward

Environmental Science and Geology Faculty Research Publications

Lattice preferred orientations (LPO) of quartz in gneiss domes of the D’Entrecasteaux Islands, Woodlark Rift shed insight into exhumation of the world’s youngest (~5–7Ma) eclogite-bearing terrane at cm/yr rates. We focus on deformation that affected the terrane as it transited between lower crustal depths and the surface, including: (1) grain-scale deformation mechanisms; and (2) style of flow and mode of emplacement of the domes. Electron-backscatter diffraction was used to analyze microstructure and LPOs of 37 quartzofeldspathic gneiss samples that enclose meter-scale mafic blocks preserving original eclogite-facies assemblages. During exhumation of the ultrahigh-pressure (UHP) terrane, gneisses were retrogressed in the amphibolite …

A Combined Radio- And Stable-Isotopic Study Of A California Coastal Aquifer System, Peter W. Swarzenski, Mark Baskaran, Robert J. Rosenbauer, Brian D. Edwards, Michael Land

Environmental Science and Geology Faculty Research Publications

Stable and radioactive tracers were utilized in concert to characterize geochemical processes in a complex coastal groundwater system and to provide constraints on the kinetics of rock/water interactions. Groundwater samples from wells within the Dominguez Gap region of Los Angeles County, California were analyzed for a suite of major cations (Na⁺, K⁺, Mg²⁺, Ca²⁺) and anions (Cl⁻, SO₄²⁻), silica, alkalinity, select trace elements (Ba, B, Sr), dissolved oxygen, stable isotopes of hydrogen (δD), oxygen (δ¹⁸O), dissolved inorganic carbon (δ¹³C_DIC), and radioactive …

Effects Of Flow Rates And Composition Of The Filter, And Decay/Ingrowth Correction Factors Involved With The Determination Of In Situ Particulate 210Po And 210Pb In Seawater, Mark Baskaran, Thomas Church, Gi Hong, Anupam Kumar, Ma Qiang, Hui Choi, Sylvain Rigaud, Kanchan Maiti

Environmental Science and Geology Faculty Research Publications

Accurate measurements of particulate ²¹⁰Po (²¹⁰Po_p) and ²¹⁰Pb (²¹⁰Pb_p) are required in the investigation of (i) partitioning of Po and Pb between particulate and dissolved phases and (ii) export estimates of carbon and other key trace metals from the euphotic zone via sinking particulate matter. Based on the intercomparison of different composition of the filter material (QMA, Supor, Millipore, and Pall GN6) and flow rates (2 to 8 L min), we show how these factors affect the measured concentrations of ²¹⁰Po_p and ²¹⁰Pb_p and their activity …

Intercalibration Studies Of 210Po And 210Pb In Dissolved And Particulate Seawater Samples, Thomas Church, Sylvain Rigaud, Mark Baskaran, Anupam Kumar, Jana Friedrich, Pere Masque, Viena Puigcorbé, Guebuem Kim, Olivier Radakovitch, Gi Hong, Hui Choi, Gillian Stewart

Environmental Science and Geology Faculty Research Publications

Documented is an intercalibration (IC) exercise for both ²¹⁰Po and ²¹⁰Pb in seawater aliquots distributed between up to eight international laboratories that followed individual protocols. Dissolved and particulate samples were provided by GEOTRACES during two IC cruises at baseline stations in the North Atlantic and North Pacific oceans. Included were surface and/or deep dissolved and particulate samples at each site, plus complete profiles analyzed by the laboratory of the lead author. An unspecified solid phase standard was also distributed with ²¹⁰Po and ²¹⁰Pb in secular equilibrium to confirm spike calibrations. The ²¹⁰Po activities reported n …

Depositional Fluxes And Concentrations Of 7Be And 210Pb In Bulk Precipitation And Aerosols At The Interface Of Atlantic And Mediterranean Coasts In Spain, R. L. Lozano, E. G. San Miguel, J. P. Bolívar, M. Baskaran

Environmental Science and Geology Faculty Research Publications

Bulk depositional fluxes of ⁷Be and ²¹⁰Pb in precipitation measured over a period of 16 months (April 2009–July 2010) in Huelva, Spain varied between 5.6 and 186 Bq m⁻² month⁻¹ (annual mean: 834 Bq m⁻² year⁻¹) and 0.8 and 8.1 Bq m⁻² month⁻¹ (annual mean: 59 Bq m⁻² year⁻¹), respectively, with the lowest depositional fluxes occurring during dry summer months. Quantitative evaluation of the precipitation-normalized seasonal depositional fluxes of ⁷Be and ²¹⁰Pb indicates that the enrichment factor in winter is < 1.0 while in 2010 spring, it is significantly higher than 1, possibly indicating input of air from the stratosphere-troposphere exchange (for ⁷Be). The specific activities of …

Magnetic Properties Of Ilmenite‐Hematite Single Crystals From The Ecstall Pluton Near Prince Rupert, British Columbia, Sarah J. Brownlee, Joshua M. Feinberg, Takeshi Kasama, Richard J. Harrison, Gary R. Scott, Paul R. Renne

Environmental Science and Geology Faculty Research Publications

Paleomagnetic studies of the 91 Ma Ecstall pluton and other Cretaceous plutons of British Columbia imply large northward tectonic movements (>2000 km) may have occurred during the tectonic evolution of western North America. However, more recent studies have shown that the eastern edge of the Ecstall pluton experienced considerable mineralogical changes as younger Eocene plutons, such as the ∼58 Ma Quottoon Pluton, were emplaced along its margins. We investigated changes in the rock magnetic properties associated with this reheating event by examining isolated grains of intergrown ilmenite and hematite, the primary paleomagnetic recorder in the Ecstall pluton. Measurements of …

Predicted Velocity And Density Structure Of The Exhuming Papua New Guinea Ultrahigh‐Pressure Terrane, Sarah J. Brownlee, Bradley R. Hacker, Matthew Salisbury, Gareth Seward, Timothy A. Little, Suzanne A. Baldwin, Geoffrey A. Abers

Environmental Science and Geology Faculty Research Publications

New electron backscatter diffraction measurements show that the Papua New Guinea (PNG) ultrahigh‐pressure (UHP) terrane is dominated by rocks with weakly oriented quartz and feldspar and less abundant strongly oriented hornblende, clinopyroxene, and mica. Velocities measured at high pressures (600 MPa) show that V_P is 5.8–6.3 km/s for gneiss samples, 6.5–7.7 km/s for amphibolite, and 7.7–8.2 km/s for eclogite and V_S is 3.4–3.9 km/s for gneiss, 4.0–4.4 km/s for amphibolite, and 4.5–4.6 km/s for eclogite. Velocities and anisotropies calculated from mineral crystal preferred orientations (CPOs) are equivalent to within 5% of the measured values. The highest seismic anisotropy …

Reproduction And Genetic Detection Of Veligers In Changing Dreissena Populations In The Great Lakes, Jeffrey L. Ram, Aos S. Karim, Payel Acharya, Pranav Jagtap, Sonal Purohit, Donna R. Kashian

Environmental Science and Geology Faculty Research Publications

Dreissenid bivalves, Dreissena polymorpha (zebra mussel) and Dreissena bugensis (quagga mussel) are biofouling species that invaded the Great Lakes region of North America from source populations in Europe in the 1980s. Initially, D. polymorpha spread faster and farther; however, D. bugensis have recently displaced D. polymorpha in many areas of the Great Lakes and was the first to be found west of the Continental Divide. Early detection of dreissenids is important in anticipating and preventing potentially high economic impacts. To study population dynamics and to enhance detection methods, we assessed “spawnability” using a serotonin bioassay and developed a new, sensitive, …

Thermal History Of The Ecstall Pluton From 40Ar/39Ar Geochronology And Thermal Modeling, Sarah J. Brownlee, Paul R. Renne

Environmental Science and Geology Faculty Research Publications

New ⁴⁰Ar/³⁹Ar thermochronology results and thermal modeling support the hypothesis of Hollister et al. (2004), that reheating of the mid-Cretaceous Ecstall pluton by intrusion of the Coast Mountains Batholith (CMB) was responsible for spatially variable remagnetization of the Ecstall pluton. ⁴⁰Ar/³⁹Ar ages from hornblende and biotite from 12 locations along the Skeena River across the northern part of the Ecstall pluton decrease with proximity to the Quottoon plutonic complex, the nearest member of the CMB to the Ecstall pluton. The oldest ⁴⁰Ar/³⁹Ar ages are found farthest from the Quottoon plutonic …

What Are The Causes, Consequences And Correctives Of Fish Contamination In The Detroit River Aoc That Cause Health Consumption Advisories? (Final Report, Michigan Sea Grant Michu-T-10-001), Donna R. Kashian, Ken G. Drouillard, D. Haffner, Ann E. Krause, Z Liu, Larissa Sano

Environmental Science and Geology Faculty Research Publications

Using an Integrated Assessment (IA) framework, we consolidated and utilized existing data from the Detroit River to develop models that both identify possible drivers of elevated fish contaminant body burdens, and to facilitate a more risk-based approach of tissue trigger-levels for consumption advisories. This integrated assessment approach was particularly useful for consumption advisories as it provided the ability to integrate and organize complex data in a manner that can help inform management decisions. In addition, the IA framework explicitly fosters collaboration and participation of multiple interested groups. We have capitalized on this component of IAs, by seeking the active participation …

Constraints On The Utility Of Mno2 Cartridge Method For The Extraction Of Radionuclides: A Case Study Using 234Th, M. Baskaran, P. W. Swarzenski, B. A. Biddanda

Environmental Science and Geology Faculty Research Publications

Large volume (10²–10³ L) seawater samples are routinely processed to investigate the partitioning of particle reactive radionuclides and Ra between solution and size-fractionated suspended particulate matter. One of the most frequently used methods to preconcentrate these nuclides from such large volumes involves extraction onto three filter cartridges (a prefilter for particulate species and two MnO₂-coated filters for dissolved species) connected in series. This method assumes that the extraction efficiency is uniform for both MnO₂-coated cartridges, that no dissolved species are removed by the prefilter, and that any adsorbed radionuclides are not desorbed from …

A New Global Model For P Wave Speed Variations In Earth's Mantle, Chang Li, Robert D. Van Der Hilst, E. Robert Engdahl, Scott Burdick

Environmental Science and Geology Faculty Research Publications

We document our tomographic method and present a new global model of three-dimensional (3-D) variations in mantle P wave velocity. The model is parameterized by means of rectangular cells in latitude, longitude, and radius, the size of which adapts to sampling density by short-period (1 Hz) data. The largest single data source is ISC/NEIC data reprocessed by Engdahl and coworkers, from which we use routinely picked, short-period P, Pg, Pn, pP, and pwP data (for earthquakes during the period 1964∼2007). To improve the resolution in the lowermost and uppermost mantle, we use differential times of core phases (PKPAB − PKPDF, …

The Influence Of Metal Exposure History And Ultraviolet-B Radiation On Benthic Communities In Colorado Rocky Mountain Streams, Robert E. Zuellig, Donna R. Kashian, Marjorie L. Brooks, Peter M. Kiffney, William H. Clements

Environmental Science and Geology Faculty Research Publications

Interest in understanding the influence of ultraviolet-B (UVB; 280–320 nm) radiation in aquatic ecosystems has increased since the early 1990s. Pollution from historic mining operations coupled with physicochemical characteristics of Rocky Mountain streams that increase exposure of benthic communities to UVB provided an opportunity to examine how UVB interacted with heavy metal contamination to structure stream communities. We integrated a series of UVB addition experiments done in stream microcosms with a large-scale UVB shading experiment to test the hypothesis that effects of UVB were greater on benthic communities from metal-polluted streams than from reference streams. Microcosm experiments involved short-term exposure …

Residence Times And Temporal Variations Of 210Po In Aerosols And Precipitation From Southeastern Michigan, United States, Daphne Mcneary, Mark Baskaran

Environmental Science and Geology Faculty Research Publications

Daughter products of ²²²Rn (such as ²¹⁰Pb, half-life = 22.1 years, and ²¹⁰Po, half-life = 138 days) have been widely used as tracers to determine the removal rates of aerosols as well to obtain analog information on the behavior of other chemical species in the lower atmosphere. To establish the first data set on the depositional fluxes of ²¹⁰Po in bulk precipitation and concentrations in air samples from the midwestern United States, we measured the depositional fluxes of ²¹⁰Pb and ²¹⁰Po in the bulk (wet plus dry) and dry fallout by deploying a rain …

The Quartzite Problem Revisited, Jeffrey L. Howard

Environmental Science and Geology Faculty Research Publications

A review of past terminology and previous petrological studies suggests that quartzite should be classified descriptively as both a sedimentary and a metamorphic rock. Quartzite is identified in the field as a quartz‐rich rock (exclusive of chert and vein quartz) that is exceptionally hard and, when broken by a rock hammer, fractures irregularly through both grains and cement (where present) to form an irregular or conchoidal fracture surface. Quartzite is differentiated from quartzose sandstone (arenite), which is softer and fractures around individual grains, and from chert and vein quartz by a bright vitreous luster. Quartzite is classified further on the …

Interaction Of Sea Ice Sediments And Surface Sea Water In The Arctic Ocean: Evidence From Excess 210Pb, M. Baskaran

Environmental Science and Geology Faculty Research Publications

We measured the activities of ²¹⁰Pb, ²²⁶Ra, ²³⁸U and ¹³⁷Cs in a suite of ice-rafted sediments (IRS) from the Arctic Ocean in an attempt to assess the interaction of sea ice sediments and surface water. The concentrations of these nuclides were compared to those of the benthic sediments in the coastal and shelf regions of the Arctic Ocean, which are believed to be the major source region for the IRS. The concentration factors (CF = activity of a nuclide in IRS/average activity in benthic sediments) are ∼1 and 4-92 for ¹³⁷Cs and ²¹⁰Pb, respectively. …

Comparison Of Two-Dimensional And Three-Dimensional Simulations Of Dense Nonaqueous Phase Liquids (Dnapls): Migration And Entrapment Of A Nonuniform Permeability Field, John A. Christ, Lawrence D. Lemke, Linda M. Abriola

Environmental Science and Geology Faculty Research Publications

The influence of reduced dimensionality (two-dimensional (2-D) versus 3-D) on predictions of dense nonaqueous phase liquid (DNAPL) infiltration and entrapment in statistically homogeneous, nonuniform permeability fields was investigated using the University of Texas Chemical Compositional Simulator (UTCHEM), a 3-D numerical multiphase simulator. Hysteretic capillary pressure–saturation and relative permeability relationships implemented in UTCHEM were benchmarked against those of another lab-tested simulator, the Michigan-Vertical and Lateral Organic Redistribution (M-VALOR). Simulation of a tetrachloroethene spill in 16 field-scale aquifer realizations generated DNAPL saturation distributions with approximately equivalent distribution metrics in two and three dimensions, with 2-D simulations generally resulting in slightly higher maximum …

Influence Of Hydraulic Property Correlation On Predicted Dense Nonaqueous Phase Liquid Source Zone Architecture, Mass Recovery And Contaminant Flux, Lawrence D. Lemke, Linda M. Abriola, John R. Lang

Environmental Science and Geology Faculty Research Publications

Organic liquid saturation distributions resulting from a simulated tetrachloroethene (PCE) spill were generated with alternative models of spatially varying aquifer properties for a statistically homogeneous, nonuniform sand aquifer. The distributions were analyzed to quantify DNAPL source zone characteristics and then incorporated as initial conditions for simulated PCE recovery using surfactant-enhanced aquifer remediation (SEAR). The predicted evolution of the spatial distribution of DNAPL saturations or source zone ‘‘architectures’’ and associated remediation efficiencies are strongly influenced by the spatial correlation of aquifer parameters and multiphase flow constitutive relationships. Model predictions suggest that removal of 60 to 99% of entrapped PCE can reduce …

Dense Nonaqueous Phase Liquid (Dnapl) Source Zone Characterization: Influence Of Hydraulic Property Correlation On Predictions Of Dnapl Infiltration And Entrapment, Lawrence D. Lemke, Linda M. Abriola, Pierre Goovaerts

Environmental Science and Geology Faculty Research Publications

The influence of aquifer property correlation on multiphase fluid migration and entrapment was explored through the use of correlated and uncorrelated porosity, permeability, and capillary pressure-saturation (P_c-Sat) parameter fields in a crosssectional numerical multiphase flow model. Data collected from core samples in a nonuniform sandy aquifer were used to generate three-dimensional aquifer parameter fields. Porosity was assumed to be uniform or simulated using sequential Gaussian simulation (SGS). Permeability (k) was modeled independently of porosity using SGS as well as simulated geostatistical indicator classes derived from measured grain size distribution curves. Retention characteristics were assigned employing Leverett …

Depositional Characteristics Of 7Be And 210Pb In Southeastern Michigan, D. Mcneary, M. Baskaran

Environmental Science and Geology Faculty Research Publications

The depositional fluxes in the bulk and dry fallout as well as the concentrations of ⁷Be and ²¹⁰Pb in aerosols were measured for a period of 17 months at Detroit, Michigan. The bulk depositional fluxes of ⁷Be and ²¹⁰Pb varied between 3.11 and 63.0 dpm cm⁻² yr⁻¹ (mean of 11.4 dpm cm⁻² yr⁻¹) and 0.35 and 10.3 dpm cm⁻² yr⁻¹ (mean of 1.41 dpm cm⁻² yr⁻¹), respectively, and this variability in the depositional fluxes is attributed to the frequency and amount of precipitation and seasonal variations …

Narrow Hybrid Zone Between Two Subspecies Of Big Sagebrush (Artemisia Tridentata: Aeteraceae). V. Soil Properties, Han Wang, David W. Byrd, Jeffrey L. Howard, E. Durant Mcarthur, John H. Graham, D. Carl Freeman

Environmental Science and Geology Faculty Research Publications

We studied soils of the big sagebrush (Artemisia tridentata) hybrid zone at two locations in Utah. The elemental composition, depth, and pH of soil in the basin and mountain big sagebrush habitats differed significantly from each other and from the hybrid zone soil. The hybrid zone soil is not just a simple blend of the two parental habitat soils. Rather, it possesses novel characteristics found in neither parental habitat and is more variable than the parental habitat soils. Correspondence analyses show that the sites occupied by each parental taxon are chemically distinct. Moreover, the principal axes from the two study …

Comments On “Measurements Of 7Be And 210Pb In Rain, Snow, And Hall”, M. Baskaran

Environmental Science and Geology Faculty Research Publications

No abstract available

A Search For The Seasonal Variability On The Depositional Fluxes Of 7Be And 210Pb, M. Baskaran

Environmental Science and Geology Faculty Research Publications

Investigations of the atmospheric fallout of ⁷Be and ²¹⁰Pb in many places around the globe indicate that there are seasonal variations on the depositional fluxes of these nuclides: high in winter in a few places, while in most places the high occurs in spring. However, these earlier studies did not address quantitatively the corresponding seasonal variations of the amount of precipitation during these periods. Data on the depositional fluxes of ⁷Be and ²¹⁰Pb in Galveston, Texas, during the years 1989–1991 indicate that the seasonal variation is not uniform from year to year, and the amount of …

Conglomerates Of The Upper Middle Eocene To Lower Miocene Sespe Formation Along The Santa Ynez Fault: Implications For The Geologic History Of The Eastern Santa Maria Basin Area, Jeffrey L. Howard

Environmental Science and Geology Faculty Research Publications

The depositional history of the Sespe Formation was studied using sedimentary facies analysis, clast counts, paleocurrent and clast morphological measurements, and petrographic methods. Sedimentation is interpreted to have occurred mainly as part of two depositional sequences in a coastal-braid-plain forearc-basin setting. Both sequences are present in the Santa Ynez Mountains, whereas only the upper sequence is recognized in the eastern Santa Maria basin. The lower sequence is part of a late middle to late Eocene sedimentary offlap attributed to a high input of terrigenous sediment derived mostly from the Mojave Desert region. This sequence is capped by an intraformational erosional …

Speleothems As Proxy For The Carbon Isotope Composition Of Atmospheric Co2, M. Baskaran, R. V. Krishnamurthy

Environmental Science and Geology Faculty Research Publications

We have measured the stable isotope ratios of carbon in a suite of recent cave deposits (<200 >years) from the San Saba County, Texas, USA. The methodology for dating these deposits using excess ²¹⁰Pb was recently established [Baskaran and Iliffe, 1993]. The carbon isotope ratios of these samples, spanning the time period ∼1800–1990 AD, reflect the carbon isotope ratio of atmospheric CO₂ for the same period. The pathways by which the δ¹³C of atmospheric CO₂ is imprinted on these speleothems can be explained using a model developed by Cerling (1984). The results suggest that the …

Atmospheric Depositional Fluxes Of 7Be And 210Pb At Galveston And College Station, Texas, M. Baskaran, Charles H. Coleman, Peter H. Santschi

Environmental Science and Geology Faculty Research Publications

The bulk depositional fluxes of ²¹⁰Pb and ⁷Be were measured at a coastal (Galveston) and an inland (College Station) station for about 3 years, between 1989 and 1991. The annual depositional fluxes of ⁷Be and ²¹⁰Pb at Galveston during this period varied by a factor of about 2.5, between 8.9 and 23.2 disintegrations per minute (dpm) cm⁻² yr⁻¹, with a mean of 14.7 dpm cm⁻² yr⁻¹ for ⁷Be, and 0.67 and 1.71 dpm cm⁻² yr⁻¹, with a mean of 1.03 dpm cm⁻² yr⁻¹ for ^{210 …}

Age Determination Of Recent Cave Deposits Using Excess 210Pb - A New Technique, M. Baskaran, Thomas M. Iliffe

Environmental Science and Geology Faculty Research Publications

Cave deposits have been widely used as proxy recorders in deciphering palaeoclimate during the last glacial/interglacial maxima (∼ 120 ka) [Harmon et al., 1975; Atkinson et al., 1978; Goede and Harmon, 1983; Ayliffe and Veeh, 1989]. Palaeoclimatic studies of cave deposits for the past 1–1000 yr time scale require a precise dating technique, that until now has been lacking. Due to the multiple sources of carbon in speleothems, ¹⁴C dates obtained for recently deposited calcite are highly variable and thus, ¹⁴C dating techniques are not suitable to obtain speleothem ages for the past 1–1000 years.

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Environmental Radiocesium In Subarctic And Arctic Alaska Following Chernobyl, M. Baskaran, J. J. Kelley, A. S. Naidu, D. F. Holleman

Environmental Science and Geology Faculty Research Publications

Radiocesium (¹³⁴ Cs and ¹³⁷ Cs) concentrations were measured in soil, plant and wildlife samples from subarctic to arctic Alaska. Concentrations of ¹³⁷ Cs ranged from below detectable or low levels in whale and fish samples to as high as 242 Bq/kg in lichen. For all potential human food items, the radiocesium concentrations measured in this study were below accepted permissible levels for human consumption. Chernobyl-derived radiocesium concentrations ranged from below detectable or low levels in all arctic samples (soil, sediment, lichen, whale, fish and caribou) to 32 Bq/kg in subarctic moss. Therefore the distribution and subsequent deposition of Chernobyl-derived …