Physical Sciences and Mathematics Commons^™

Adsorption Of Arsenic Onto River Sediments, Leticia Augusta Dos Santos Ferreira

Masters Theses

“Previous studies have noted the relationship between shallow groundwater rich in sodium (Na) and bicarbonate (HCO₃) and elevated levels of dissolved arsenic. However, most experimental work on arsenic adsorption in the presence of HCO₃ and differing Na/Ca ratios has proven difficult to extrapolate to natural systems because of differences in tested mineral compositions and component concentrations. In this study, I performed a series of adsorption experiments using river sediments to evaluate the influence of HCO₃ and monovalent/divalent cations on the extent of arsenic adsorption onto natural sediment in groundwater.

Batch adsorption (kinetics, equilibrium, and metal loading) …

Using Lake Sediment Chemistry In The Exploration For Nickel Laterite Deposits In Tropical Regions, Gabriela Yvonne Ramirez

Masters Theses

"Developing reliable geochemical indicators to guide the search for ore deposits is a long-standing goal. This particularly applies to tropical regions that are often heavily vegetated which hampers boots-on-the ground exploration efforts. Here we present the preliminary results of a study that investigates the usefulness of lake sediment chemistry in the exploration for nickel laterite ore deposits in tropical regions using Lake Izabal, Guatemala, as a case study. Lake Izabal’s catchment area contains Ni laterite deposits along its northern shore, whereas no Ni-laterite discoveries have been made in the south except for a Ni mine in the southern region that …

Lithofacies Characterization Of Marine Shelf Shale And Implicaitons On Depositional Conditions And Processes On The Continental Shelf — A Case Study Of The Upper-Cretaceous Tuscaloosa Marine Shale In Louisiana And Mississippi, U.S.A., Efren Mendez Jr

Masters Theses

"The Upper Cretaceous Tuscaloosa Marine Shale (TMS) is an unconventional shale reservoir deposited on the continental shelf of the northern Gulf of Mexico Basin. Previous studies have focused on sequence stratigraphy, thermal modeling, and well-log correlations. However, a limited understanding of the stratigraphic heterogeneity of the TMS is yet to be studied. This study aims to characterize the stratigraphic heterogeneity of the TMS using core, petrographic, and well-log analyses to better understand the depositional conditions and processes that occur on the continental shelf. The TMS has been classified into four lithofacies of very fine sands – coarse silts (LF1), medium-fine …

Preclassic Cultural Eutrophication Of Lake Petén Itzá, Lowland Guatemala, By The Early Maya Of Nixtun-Ch'ich', Brooke A. Birkett

Masters Theses

"Paleolimnological evidence indicates the ancient Maya transformed lowland terrestrial ecosystems by felling forest vegetation to construct large civic-ceremonial centers and expand agriculture. The effects of prehistoric Maya land alterations on lake trophic status, however, remain poorly understood. We analyzed a 515-cm-long sediment core from Lake Petén Itzá, lowland Guatemala, to infer paleoenvironmental changes resulting from Maya occupation of the riparian archaeological site of Nixtun-Ch'ich'. Substantial increases in charcoal and fecal stanol concentrations indicate Maya occupation of the Candelaria Peninsula by the late Early Preclassic period beginning ca. 1400 cal yr Before the Common Era (hereafter BCE), despite scant archaeological evidence …

Multiple Generations Of Phlogopite In An Alnöite Diatreme: Insights Into The Petrogenesis Of The Avon Alkaline Igneous Province, Missouri, Nathan Gregory Limbaugh

Masters Theses

“Alkaline Ultramafic Carbonatite (AUC) complexes, although rare, are valued for diamonds and REEs, and as windows into subcontinental and mantle processes as recorded by rock fabrics, mineral spatial relationships, and mineral compositions. We report specifically on olivine and phlogopite petrographic relationships and compositions from the Devonian alnoite diatreme-facies of the Avon Alkaline Igneous Province, Missouri. The diatreme alnoite is a mixture of domains of olivine magmaclasts (OM) set in a crystal-rich melilite matrix. OM are highly fractured, serpentinized olivine pseudomorphs with variable amounts of pristine olivine fragments. Larger olivine domains typically exhibit clear crystal faces and irregular “channels” indicative of …

Relationships Among Mineralogy, Geochemistry, And Oil And Gas Production In The Tuscaloosa Marine Shale, Hayley Roxana Beitel

Masters Theses

"The Tuscaloosa Marine Shale (TMS) is an unconventional shale reservoir located in southeast Louisiana and southwest Mississippi. Limited mineralogical and geochemical data for the TMS have been published. The data that do exist indicate that the formation is heterogeneous. Consequently, previous investigators and oil and gas companies have not managed to effectively link mineralogical and chemical changes to oil and gas production in the TMS. These linkages are critical to establish for future exploration efforts. In this study, we attempt to establish these relationships by gathering all existing mineralogical and chemical data in the TMS, including newly acquired data from …

Strain Partitioning Across The Polochic-Motagua Fault System In Guatemala: Insight From Kinematic Modeling, Qiaoqi Sun

Masters Theses

”The Polochic-Motagua Fault System in Guatemala is the on-land segment of the sinistral transform plate boundary between the North American Plate and the Caribbean Plate. Three major seismically active strike-slip faults in this fault system pose significant earthquake threats to surrounding populated cities. The assessment of seismic hazard requires a better understanding of the kinematics of the fault system. GPS monitoring indicates that seventy-five percent of the ~20 mm/yr. plate motion is accommodated by the Motagua Fault and less than twenty-five percent is accommodated by the Polochic Fault. However, the Polochic Fault documents a lateral offset of ~132 ± 5 …

The Role Of Tectonic Inheritance, Plate-Reorganization, And Magma Flare-Ups In The Evolution Of The Sevier Orogeny, J. Daniel Quick

Masters Theses

"The temporal and spatial distribution of strain associated with the Sevier Orogeny in western North America is significantly different in the southern end of the belt, at the latitude of Las Vegas, than further to the north at the latitude of Salt Lake City. Until this study, reasons for these differences were speculative as a lack of thrust kinematic data in the intervening region hindered along strike correlation across the belt. A crystallization age of 100.18 ± 14 0.04 Ma was determined for zircons extracted from a recently recognized ash fall tuff near the base of the synorogenic Iron Springs …

Mineral Compositions Of Meteorite Samples Alha 77005, Nwa 7397, Nwa 5480, And Ausson: Implications For Geodynamic Processes On Their Parent Bodies And Meteorite Reclassification, Kaylin Agnata Tunnell

Masters Theses

“This study investigates the major, minor, and trace element compositions of minerals from a series of meteorites which represent different stages of planetary evolution including two sample from Mars (ALHA 77005 and NWA 7397), one sample from Vesta (NWA 5480), and one ordinary chondrite (Ausson). The goal of this study is to investigate if petrogenetic tracers commonly employed to understand terrestrial samples can also be applied to extraterrestrial samples. The data presented here show that mineral trace element data allow for novel insight into the magmatic history of meteorite samples. For example, V/Sc and Fe/Mn ratios in olivine provide insight …

Exploration For Alteration Halos Around The Ag-W Deposits In Southeastern Missouri, Usa, Daniel Joseph Warbritton

Masters Theses

"The St. Francois Mountains in SE Missouri are an extensive terrane of granitic ring complexes and associated rhyolites. They were an important source of Ag, W, and Sn and mined intermittently from the 1800s until the 1950s. The Ag-W ores occur in the Silvermine Granite and rhyolite roof rocks. The deposits are classified as a xenothermal ore system with mineralization occurring in quartz veins and surrounding greisen (up to 2.5 m). Exploration for hydrothermal ore deposits often focuses on the identification of alteration halos in the surrounding host rocks. In the vast majority of xenothermal ore deposits, such as in …

Archaeological Investigation Using Geophysical Methods To Locate Historic Byram's Ford Road, Marshall Seth Foster

Masters Theses

"Ground penetrating radar, a time domain electromagnetic metal detector and a frequency domain electromagnetic metal detector were used with the goal of locating a section of the Byram's Ford Road believed to be intersecting the historic Big Blue Battlefield in the Westport area of Kansas City, Missouri.

Ground penetrating data were acquired at three sites, Site A, Site B, and Site C. The time domain EM metal detector was used to acquire data at Site A, where subsequent ground truthing was conducted using the frequency domain EM metal detector and an excavation tool. Significant anomalies were visible on both the …

Reprocessing And Comparison Of The 2 Hz And 10 Hz Vertical Component Seismic Data Of The Blackfoot 3c-2d Survey, Mete Sarikaya

Masters Theses

"The Blackfoot seismic 3C-2D data were obtained from the Consortium for Research in Elastic Wave Exploration Seismology (CREWES) Project in 1995. The seismic data acquisition was performed in the Blackfoot Field, which is around 15 km southeast of Strathmore, Alberta. The 4 Hz and 10 Hz vertical component data are reprocessed to increase the quality and resolution of the seismic images. The Glauconitic sand reservoir at approximately 1.1 s, and a strong reflection about at 1.5 s are the focuses of the study.

The processing procedure includes different parameters and methods to obtain the best seismic sections of 2 Hz …

U-Pb Detrital Zircon Geochronology Of Paleozoic Clastics Of The Ozark Plateau: Implication For Sea-Level Fluctuations And Far-Field Tectonics, Chen Zhao

Masters Theses

"The Ozark Plateau of south-central Missouri is underlain by Ordovician to Pennsylvanian carbonate and clastic strata. Enigmatic, presumably Pennsylvanian 'filled sink' structures are common on the Ozark Plateau and remain a source of controversy. We present results for U-Pb ages of detrital zircons for 13 samples from the OP. We use U-Pb ages from other Paleozoic clastics and 'filled sinks' on the OP, to suggest: 1) FSS record a period of Middle Ordovician erosion and sedimentation and 2) document significant shifts in sediment provenance that reflect regional tectonic events affecting the North American Craton.

The KDE plots of normalized detrital …

Reprocessing Of The 2 Hz P-P Data From The Blackfoot 3c-2d Survey With Special Reference To Multicomponent Seismic Processing, Onur Akturk

Masters Theses

"The 3C-2D multicomponent seismic survey was acquired in the Blackfoot Field, which is located 15 km southeast of Strathmore, Alberta. The 2 Hz vertical component data were reprocessed to better image the target reservoir, the Glauconitic sand formation at approximately 1150 ms. The zone of the major reflector at about 1550 ms was also taken into consideration to determine the better seismic section for further processing. The main characteristics of the converted wave processing, such as common conversion point (CCP), asymptotic binning, gamma ratios, receiver statics, rotation of the data, positive/negative offsets, and anisotropy, were also summarized in this study. …

3d Seismic Imaging Of Submarine Stratovolcanic And Salt Structures Beneath The Taranaki Basin, New Zealand And The Gulf Of Mexico, Ersin Erdem Unkaracalar

Masters Theses

"The relationship of submarine stratovolcanic and salt structures with overlying sediments creates a significant role in the petroleum system due to the emplacement and burial of volcano and salt. This study characterizes the spatial and temporal distribution of structural and stratigraphic features associated with submarine stratovolcano and salt body to provide insights for elements and processes of petroleum geology related to regional tectonics.

The stratovolcanic and salt structures are clearly identified on seismic sections. However, distortion of ray paths passing through the salt and turning seismic waves prevents accurate identification of steep flanks of salt. The seismic response to a …

Conical Folds -- An Artifact Of Using Simple Geometric Shapes To Describe A Complex Geologic Structure, Avery Joseph Welker

Masters Theses

"Accurate representation of the 3D shapes of natural folds is essential to characterization of the dynamic models for fold formation. Geometrical analysis of folds commonly relies upon analyzing patterns defined by the variation in the orientation of poles to planar surfaces deformed by a shortening event when plotted using graphical calculators (e.g., stereogram, polar tangent diagrams) to interpret the shape of folds. Stereograms for which orientation data define small circles are classified as non-cylindrical regular folds and are interpreted as "conical folds," where the shape of the fold is represented by a cone that terminates at a point. Utilizing similar …

Application Of Seismic Attributes For 3-D Seismic Visualization Contributed In Structural And Stratigraphic Interpretation Of The Tangahoe And Farewell Formations In The Kupe Field, Taranaki Basin, New Zealand, Housam Hussein Grabeel

Masters Theses

"Taranaki Basin is a mainly offshore basin covering an area of approximately 100,000 km², elongated across the western margin of New Zealand's north island. However, the modern limit of the basin is extended toward the deep water to cover about 330,000 km². The basin is divided by tectonic activities into northern and southern grabens. The southern region has become the most extensively researched district in recent years as its prime lithology and structural trap distributions provide numerous hydrocarbon fields. One such field is the Kupe Field (256 km²), which lies on a northerly-plunging, reverse-faulted, …

Development Of A Variogram Approach To Spatial Outlier Detection Using A Supplemental Digital Elevation Model Dataset, Zane Daniel Helwig

Masters Theses

"When developing a ground water model, the quality of the dataset should first be evaluated. Spatial outliers can lead to predictions which are not representative of actual conditions. In order to isolate misrepresentative points, a method is presented which examines the experimental variogram of a ground water elevation dataset. To define a threshold variance between pairs of ground water elevation measures, ground elevation values from a digital elevation model (DEM) are used to determine a maximum reasonable variance expected to occur on the experimental variogram. To determine appropriate DEM parameters, a separate study was also done which observed characteristic behavior …

Provenance And Depositional Environments Of Fluvial-Lacustrine Deposits In A Non-Marine Rift Basin, Lower-Triassic Jiucaiyuan And Shaofanggou Low-Order Cycles Bogda Shan, Nw China, Jaimeson Grigaitis Fredericks

Masters Theses

"The uppermost Carboniferous to Lower Triassic eolian-fluvial-lacustrine deposits of Turpan-Junggar Basin, NW China, record the non-marine sediment-filling processes in a continental rift basin in mid-latitude NE Pangea. This study focuses on the fluvial-lacustrine strata of the Lower Triassic Jiucaiyuan (JCY) and Shaofanggou (SFG) low-order cycles (LCs) in multiple half grabens at the southern and northern foothills of Bogda Shan. Outcrop, paleocurrent, and petrographic analyses indicate a southern provenance. Intermediate to felsic volcanic lithics and metamorphic lithics are interpreted as being derived from Tian Shan to the south while the sedimentary lithics originate from the local rift shoulders. The basaltic lithics …

Mining Asteroids For Volatile Resources: An Experimental Demonstration Of Extraction And Recovery, Egboche Christopher Unobe

Masters Theses

"Gaseous compounds trapped within carbonaceous asteroids may prove to be important targets for prospective space miners in the near-term. Volatile release is from hydrated, hydroxylated and carbonated phases present, making such bodies attractive as feedstock for the production of H₂O, CO₂ and simple organic compounds. A source of these species in orbit provides an opportunity to locally produce space-craft propellant and other life-support gases through the application of In-situ Resource Utilization (ISRU).

For this study, an experimental vacuum system was modified and used to test the technical validity of radiatively heating asteroid simulants to extract contained gaseous …

Structural And U-Pb Detrital Zircon Geochronologic Constraints On The Origin Of The Condrey Mountain Schist, California - Oregon, Joseph Reid Coons

Masters Theses

"The Condrey Mountain Schist (CMS) of the Klamath Mountains (northern California and southern Oregon) represent low grade oceanic and terrigenous sediments thrust beneath higher grade ophiolitic rocks of the Rattlesnake Creek Terrane (RCT). This study presents new U-Pb detrital zircon dates from the CMS, and from the possibly correlative basin rocks of the Galice Formation and accretionary rocks of the South Fork Mountain Schist. The Galice Formation yields a maximum depositional age of ca. 152 Ma with prominent date distributions of ca. 150-200 Ma (39% of analyzed grains), 200-600 Ma (1%), 600 - 1000 Ma (2%), and 1000-3200 Ma (58%). …

Hydrogeochemical Controls On Reactive And Nonreactive Solute Transport In Heterogenous Porous Media, Mahta Gholizadeh Ansari

Masters Theses

"This work examines how physical and chemical heterogeneity can affect reactive and non-reactive transport in porous media. The effect of heterogeneity of the porous media is investigated both on dissolution rate of magnesite and attenuation time of nonreactive contaminants in non-reactive media. Various spatial distribution were created using statistical parameters in PETREL.A total of 6793 transport modeling simulations were run using CrunchFlow. Lasso regression was used to select most significant features and those features are then used in linear regression and deep learning models.

The magnesite dissolution simulations were performed under different permeability ratios (magnesite /sand permeability) and inlet pH. …

Crustal Thickness And Vp/Vs Ratio Of Yellowstone, Eastern Snake River Plain, Wyoming Province, And The Northern Basin And Range Province Through Receiver Function Analysis, Avikant Dayma

Masters Theses

"For decades, numerous studies have been conducted and contradictory results were achieved about the origin and evolution of the Yellowstone supervolcano and the Eastern Snake River Plain. Whether the 640 km long time-progressive chain of rhyolitic calderas was formed due to mantle-plume or a result of lithospheric extension allowing the emergence of melt on the surface is still a debate. Using receiver function analyses, this study determines the crustal thickness and the Vp/Vs ratio below the Yellowstone Plateau, Wyoming Province (WP), Idaho Batholith (IB), Eastern Snake River Plain (ESRP), and the northern Basin and Range Province (BRP). The thickness is …

Evaluation Of Swelling And Re-Swelling Of Preformed Particle Gels (Ppg) When Exposed To Co₂, Sujay Suresh

Masters Theses

"Long term water/gas flooding induces high permeability channels in reservoirs. Reservoir heterogeneity becomes the most prominent challenge faced in mature oil fields. Gel treatment has been a proven solution to counter the problem of reservoir heterogeneity, to provide in-depth treatment and improve the sweep efficiency for reservoirs. Preformed particle gels (PPGs) were developed as an alternative to in-situ gels as they preferentially penetrate and shutoff high permeability zones, leaving the low permeability zones undamaged. These gels have been predominantly used in water flooding projects, but have not been employed in carbon dioxide (CO₂) flooding projects. CO₂ Resistant …

Assessment Of Rockfall Rollout Risk Along Varying Slope Geometries Using The Rocfall And Crsp Software, Mariam S. Al E'Bayat

Masters Theses

"Most routes in mountainous areas suffer from rock falling, rolling and bouncing risk. There are many computer programs concerned with simulating the rockfall problem, and whereas they have the same purpose, they however differ in the input data that's needed to simulate the problem, and they also differ in the way of processing and kind of output.

This study used Rocfall® and the Colorado Rockfall Simulation Program (CRSP®) to simulate sixty-three models of varying slope geometry, where only the slope geometry is changed with the same material properties for both the slope and the rocks.

Both programs were fast and …

Deformation Processes At The Leading Edge Of The Sevier Fold And Thrust Belt, Southwest Utah, William Joseph Michael Chandonia

Masters Theses

"Deformation processes leading to formation and abandonment of 'triangle zones' along the leading edge of the Sevier fold and thrust belt are investigated near Kanarraville, Utah through construction of a detailed geologic map and cross-section along Spring Creek. Here the eastern limb of the Kanarra fold, a Sevier structure, is well exposed along the Hurricane Cliffs due to uplift and erosion of the footwall of the Hurricane Fault. The east-verging Kanarra fold changes from upright to overturned within Spring Creek. Within the fold limb, parasitic folds, minor thrust faults, and duplex structures result in local tectonic overthickening of units and …

Characterization Of Fracture Initiation In Non-Cylindrical Buckle Folds Using 3d Finite Element Analysis, Eli Jacob Steinbeck

Masters Theses

"The spatial distribution of fracture sets associated with buckle folds has been well documented in field studies. There are difficulties, however, in placing accurate constraints on the timing of the initiation of individual fracture sets during the deformation history of the fold under in-situ conditions. This study investigates specific conditions that give rise to the initiation of various fracture sets in the hinge and limb of a pericline, based on an analysis of the effective stress evolution during the processes of buckling and erosional unloading. A 3D finite element modeling approach is used to simulate the effective stress evolution in …

Fluid Flow Through Deformation Band, Huining Zhang

Masters Theses

"Cataclastic deformation bands, which are common in porous sandstone, have the potential to restrict fluid flow. Geological studies have shown that permeability of deformation band shear zones can be one to five orders of magnitude less than for the sandstone host rock. However, recent studies based on simplified analytical estimates have shown that fluid flow in jointed deformation bands may not be retarded since joints play an important role in conducting fluids. In this study, 2 dimensional finite element analysis (FEA) is used to simulate the total discharge flow rate through jointed deformations. Variations of single planar and conjugate jointed …

Periclinal Folding In Ozark Plateau: A Record Of Local Karst Collapse Or Regional Tectonic Forces?, Chao Liu

Masters Theses

"The Ordovician Rubidoux Formation of the Ozark Plateau, Missouri is typically identified as mechanically competent sub-horizontal beds of medium grained sandstone. North of Licking, MO, the Rubidoux Formation was deformed into a series of dome-and-basin shaped buckle folds, exposed in road cuts over a distance of ~10 km. Such folds are highly unusual within the Ozark Plateau and their origin remains controversial. Three major hypotheses have been proposed based on field observations and stereographic analysis. Given the pervasive distribution of karst collapse throughout Missouri, one hypothesis to explain these folds is that the Roubidoux Formation sagged into collapsed caverns. A …

Phytoforensics Tools: The Degradation And Detection Of Chlorinated Solvents In Integrated Systems, Tommy J. Goodwin Jr.

Masters Theses

"Due to decades of mismanaged pollutants entering groundwater, subsurface pollution of various compounds has become a widespread challenge. Chlorinated solvents are the most common groundwater contaminants that persist in aquifers, and remediation of these wide-spread plumes is difficult. Bioremediation, permeable reactive barriers, and phytoremediation are remedial technologies that have been developed and applied to chlorinated solvents in groundwater systems. This study integrates these technologies in different combinations to demonstrate the remediation potential of this approach. Zerovalent iron (ZVI) and bioaugmentation with a Dehalococcoides sp. (DHC) culture were applied separately and in combination for degradation of perchloroethene (PCE). Salix pentandra were …