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Full-Text Articles in Physical Sciences and Mathematics
Determination Of Amino Acids And Chloramino Acids In Municipal Wastewater, Jeffrey Taylor Jewell
Determination Of Amino Acids And Chloramino Acids In Municipal Wastewater, Jeffrey Taylor Jewell
Chemistry & Biochemistry Theses & Dissertations
It is well known that unchlorinated municipal wastewater contains high levels of organic and inorganic amino nitrogen compounds, the single most abundant amino-N species being ammonia. Upon chlorination, these compounds are transformed almost instantaneously and quantitatively into N-chloramino derivatives. The organic chloramines have been shown to
interfere with disinfection and have lower disinfection capacities than their inorganic counterpart monochloramine. The environmental effects imposed by the discharge of these compounds into natural receiving waters is unknown. This study has shown that amino acid precursors for N-chloramino acids range in concentration from 1.4 X 10-7 M to 9.0 X 10-7 …
Reactions Of Organic N-Chloramines In The Gastric Fluid Of The Rat, Kathryn E. Mazina
Reactions Of Organic N-Chloramines In The Gastric Fluid Of The Rat, Kathryn E. Mazina
Chemistry & Biochemistry Theses & Dissertations
Using chlorine as a drinking water disinfectant may have potential health effects due to its reactivity with organic amino nitrogen compounds found in the stomach. Organic N-chloramines have been shown to form in the stomachs of laboratory rats. The possible reactions of N-chloramines in the stomach fluid were examined in this study using a model radiolabeled N-chloramine. 36Cl-N-Chloropiperidine, was synthesized and purified to remove 36Cl-chloride. Stomach fluid was obtained from Sprague-Dawley rats which had been first fasted for 24 or 48 hours and then administered 3 mL of deionized water. Different concentrations of radiolabeled chloramine were reacted with …