Physical Sciences and Mathematics Commons^™

Spatial And Temporal Variations In The Air-Sea Carbon Dioxide Fluxes Of Florida Bay, Christopher Michael Dufore

USF Tampa Graduate Theses and Dissertations

The flux of CO2 between the ocean and the atmosphere is an important measure in determining local, global, and regional, as well as short term and long term carbon budgets. In this study, air-sea CO2 fluxes measured using a floating chamber were used to examine the spatial and temporal variability of CO2 fluxes in Florida Bay. Measurements of dissolved inorganic carbon and total alkalinity obtained concurrently with chamber measurements of CO2 flux allowed calculation of ΔpCO2 from flux measurements obtained at zero wind velocity. Floating chamber measurements of ΔpCO2 were subsequently coupled with wind speed data to provide a simple …

A Geochemical Analysis: Application Of A Chelating Agent On Potential Asr Reactive Aggregates, Jennifer N. Garcia

Geosciences Theses

Alkali Silica Reaction (ASR) is a deleterious, expansive reaction in concrete. Several ASTM methods test potential aggregates for ASR risk. One method uses NaOH digestion, followed by spectroscopic methods, to estimate the amount of reactive silica present in an aggregate. NaOH, however, can digest both crystalline (i.e. quartz) and non-crystalline (e.g. opal), or poorly crystalline silica, potentially yielding falsely high estimates of reactive silica. Studies in soil and plant sciences have used Tiron, an alkaline chelating agent (C₆H₄S₂O₈Na₂), as a method of digesting opaline silica for spectroscopic analysis. Here we …

Sequence Stratigraphy Of Basal Oquirrh Group Caronates (Bashkirian) Thorpe Hills, Lake Mountain, Wasatch Front, Utah, Andrew D. Derenthal

Theses and Dissertations

The Early Pennsylvanian (Bashkirian/Morrowan) Bridal Veil Limestone of north-central Utah was deposited in the eastern portion of the rapidly subsiding Oquirrh basin. The 420 meter-thick Bridal Veil Limestone displays distinct cyclicity formed by stacked, meter to decameter scale high-frequency sequences and their constituent parasequences. Though no one ideal cycle may be defined for the Bridal Veil Limestone, each high-frequency sequence and parasequence contains a general shallowing upward trend that ranges from anaerobic to dysaerobic mudstone at the base to skeletal wackestone to mud-dominated packstone, capped by heterozoan grain-rich carbonates or siliciclastic tidalites. Cycles bounded by exposure surfaces, indicated by micro-brecciation, …

Seismic Microzonation Of Great Toronto Area And Influence Of Building Resonances On Measured Soil Responses, Dimitar Genchev Mihaylov

Electronic Thesis and Dissertation Repository

A pilot seismic microzonation of the Greater Toronto Area (GTA) is used to establish the conditions and limitations of geophysical methods for site response investigations in city conditions. Maps of fundamental soil resonant frequencies, amplifications at these frequencies and interpolated average shear wave velocity of top 30 m of soil profile (VS- 30) used in soil classification were compared to the maps of drift thickness and surficial geology for the GTA. The non-applicability of the interpolated VS-30 map for site classification between measured test points is indicated. It is also shown that the soil response cannot be estimated properly using …

Quasi 3-Dimensional Electrical Resistivity Mapping Of Air-Filled Karst Conduits And Policy Implications, Charles W. Mccrackin

USF Tampa Graduate Theses and Dissertations

This study assesses the capability and practical applications of quasi 3-Dimensional (3D) electrical resistivity surveying (ER) for mapping air-filled karst conduits. Vadose zone caves within the Brooksville Ridge of West Central Florida are relatively similar in architecture, with N-S elongation, and do not consist of an interconnected network of conduits. A high resolution quasi-3D ER survey was performed over two mapped cave systems on the Brooksville Ridge. The resultant survey verified the general effectiveness of quasi-3D ER in locating the two known near-surface cave features. Several other locations in the survey show similar or stronger resistivity anomalies trending in a …

Post-Fire Near-Surface Runoff From Small-Scale Rainfall Simulations, Santa Cruz Mountains, Michael Founds

Natural Resources Management and Environmental Sciences

The influence of environmental variables on the runoff response to a fire is poorly understood. Small-scale rainfall simulation was used to study the factors impacting near-surface runoff following the Lockheed Fire, which occurred on August 12, 2009. A variable speed rainfall simulator was used to rain on 15 different test plots at an average rate of 50mmh^-1. Variables of burn severity, time following the fire, soil parent material, vegetation type, and presence of a duff layer were all analyzed using the ratio of runoff to rainfall. The difference in-between burned sites and similar control sites were 19±6%. Only …

Quantification Of Nitrate Sources And Sinks Using A Water Quality Network In Morro Bay Estuary, California, Johanna Nadia Jean Weston

Master's Theses

Using an instrumented water quality network in Morro Bay Estuary, California from 2007 to 2010 (15 min sampling frequency), this study addressed the two objectives of constructing a nitrate budget and assessing the influence of sampling frequency on water quality parameters. These two objectives led to the submission of an original report of research (Appendix A) and a note (Appendix B) to peer-reviewed journals.

The first objective was to characterize the high spatial and temporal variation in physical parameters and nitrate concentrations and to construct a nitrate budget quantifying sources and sinks of nitrate from the ocean, streams, and groundwater, …

Paleomagnetism And Investigation Of 40 Ma Lavas, Liverpool Range, New South Whales, Australia, Nathan M. Padilla

Physics

The main focus of this project is the continued study of a reversal of the earth’s magnetic field recorded from lavas in the Liverpool Range of New South Whales, Australia. This reverse-to-normal transition, recently dated at ~40 Ma, was first reported in Nature in 1986. [2] In March 2011 some 200+ cores were drilled from several sections about the volcanic range—Jemmy’s Creek, Bald Hill, Rock Creek, Yarraman, and Coolah Tops Road. Here we focus on paleomagnetic findings from samples drilled from the most extensive section, that being along the trail near Jemmy’s Creek. Results from alternating field demagnetization show the …

Effect Of Reworking And Bioturbation On Sedimentary Reactive Iron Within A Microtidal Estuary, Amy Kathleen Pitts

OES Theses and Dissertations

Mixed redox conditions in sediments due to physical reworking may allow for enhanced remineralization of refractory organic matter due to Fe(III) redox cycling. In part this may occur because easily reducible iron oxides can be used by heterotrophic bacteria to remineralize the organic carbon. This phenomena has been observed in bioturbated sediments and in areas where physical factors (such as strong bottom currents) constantly rework the sediments. To specifically determine the effects of physical reworking and bioturbation on concentrations of easily reducible iron oxides, reactive iron concentrations were measured in surface sediments taken from two contrasting sites in the York …

Stromatolitic Knobs In Storrs Lake, San Salvador, Bahamas: Insights Into Organomineralization, Alexandre J. Fowler

Master's Theses

Storrs Lake, a hypersaline lake on the east coast of San Salvador Island, Bahamas, contains well-developed microbial mats, some of which have developed calcified structures called microbialites. Many of these microbialites are laminated, and therefore classified as stromatolites. This study focuses on small stromatolitic knobs located in the southern portion of Storrs lake, which are still actively forming, to gain insights into the early stages of stromatolite formation. These knobs appear to be forming as the result of in situ micritic precipitation mediated by both photosynthetic and heterotrophic microbial metabolisms. By comparing these small stromatolitic knobs to larger stromatolitic heads …

Ice-Movement History And Kimberlite Indicator Mineral Dispersal Study, Pelly Bay, Lower Boothia Peninsula, And Wager Plateau Areas, Nunavut, Canada, Carl Ozyer

Electronic Thesis and Dissertation Repository

This study reconstructs the ice flow history of the eastern portion of the Keewatin sector of the Laurentide Ice Sheet by integrating field work, remote imagery, and work by others. The study reveals at least seven ice flow phases during the Wisconsinan, including ice streams. A model was developed using inverse distance weighed (IDW) interpolation with GIS to identify and isolate potential kimberlite bedrock sources in kimberlite indicator mineral-rich areas in the Pelly Bay area, Nunavut. Kimberlite indicator mineral (KIM) data were normalized by “peer size” to better understand how KIM grains from three kimberlite sources are distributed within three …

Extreme Variation In The Sagittal Crest Of Tapirus Polkensis (Mammalia Perissodactyla) At The Gray Fossil Site Northeastern Tn., Aaron Randall Abernethy

Electronic Theses and Dissertations

The preservation and quantity of fossil tapirs (Tapirus polkensis) from the Gray Fossil Site in northeastern Tennessee provides a unique opportunity for comparison and analysis of skeletal characters. Intraspecifically, modern tapirs show little to no variation in the morphology of the sagittal crest. However, several different morphologies exist within the sample at Gray. No osteological evidence of sexual dimorphism exists for tapirs, and no correlation between crest shape and sex was observed. Several juveniles display well defined crests, while some adults have only minor thickening of the temporal ridges; therefore, no distinct correlation between age and crest state …

Development Of An Approach To Evaluate Fractured Crystalline Bedrock Water Resource Supply And Sustainability, Helen E. Spera

Master's Theses

Groundwater derived from fractured crystalline bedrock is an important resource in Connecticut. Despite its importance we know very little about this resource. This study was conducted at the Plant Science and Landscape Architecture Research and Education Facility, University of Connecticut, Storrs, CT. The objectives of this study were: to improve the characterization of the hydrogeology of the facility; to develop a method to determine the amount of recharge to the bedrock from the overburden during pumping and non-pumping periods; and to develop an approach that can be used in evaluating the sustainability and zone of contribution of bedrock pumping wells. …

Ergodicity And Seismicity Clustering With Applications In Statistical Seismology, Nelson Cho

Electronic Thesis and Dissertation Repository

The implications of understanding fault networks as ergodic systems are addressed here by using the Thirumalai-Mountain metric that identifies effective ergodic periods, when long but finite time intervals are considered. This framework was proven to be useful in statistical seismology studies. Initially, it was established that that the metric can be used to quantify seismicity clustering. Periods of effective ergodicity were characterized by the occurrence of declustered seismicity. This interpretation was implemented for synthetic and seismic data from southern California and Canadian mines.

Next, methods used in the estimation of regional seismic hazard were applied to mining induced seismicity. The …

Assessment Of Watershed Model Simplification And Potential Application In Small Ungaged Watersheds: A Case Study Of Big Creek, Atlanta, Ga, Zoia A. Comarova Ms

Geosciences Theses

Technological and methodological advances of the past few decades have provided hydrologists with advanced and increasingly complex hydrological models. These models improve our ability to simulate hydrological systems, but they also require a lot of detailed input data and, therefore, have a limited applicability in locations with poor data availability. From a case study of Big Creek watershed, a 186.4 km² urbanizing watershed in Atlanta, GA, for which continuous flow data are available since 1960, this project investigates the relationship between model complexity, data availability and predictive performance in order to provide reliability factors for the use of reduced …

Implications Of Dune Pattern Analysis For Titan's Surface History, Christopher Jon Savage

Theses and Dissertations

Analyzing dune parameters such as dune width and spacing can be useful in determining the reaction of dunes to changes in atmospheric and sedimentary conditions currently and in the recent geologic past. Dune parameters, dune width and spacing, were measured for linear dunes in regions across Saturn's moon Titan from images T21, 23, 28, 44 and 48 collected by Synthetic Aperture RADAR aboard the Cassini spacecraft in order to reconstruct the surface history of Titan. Dunes in the five study swaths are all linear in form, but lack superimposed or flanking dunes. They have a mean width of 1.3 km …

Stakeholders' Perceptions Of Risk For Gentrification In Atlanta's Pittsburgh Neighborhood, David C. Holmes

Geosciences Theses

The 2008-2010 foreclosure crisis and the Beltline project present two significant forces shaping neighborhoods throughout Atlanta. Both the high foreclosure rates and the promise of public and private investment create conditions for the displacement of existing residents and for the gentrification of the southwest Atlanta neighborhood of Pittsburgh in particular. Through qualitative analysis, including interviews with residents, community leaders, and government officials, the development of overlay analysis maps of Pittsburgh, as well as studying the various stakeholders' perception of risk for gentrification in Pittsburgh, this research examines how and why these stakeholders' perception of the risk of gentrification in Pittsburgh …

Subsurface Controls On Mainland Marsh Shoreline Response During Barrier Island Transgressive Submergence, Mary Ellison

University of New Orleans Theses and Dissertations

Many recent studies have sought to understand the response of barrier islands and their attendant marshes to sea level rise. The Mississippi River delta plain, specifically the Chandeleur Islands and associated interior wetlands in eastern Louisiana, serves as an excellent natural laboratory for studying these responses. This region is presently undergoing the highest rates of shoreline erosion (> 15 m yr -1) in North America as wetlands are converted to open water in a regime of subsidence-driven rapid relative sea-level rise (~1 cm yr-1). Three conceptual models were developed based on the geomorphic relationships observed in the marsh that describe …

The Paleoecology And Biogeography Of Ordovician Edrioasteroids, Rene Anne Lewis

Doctoral Dissertations

All organisms are subjected to the living and non-living influences of their surroundings. They derive their energy and essential materials, such as sunlight and nutrients, from their environment, sharing their world not only with members of their own species but also with members of other species. These interactions are central to the survival of the organism, forming reciprocating and integrated systems with other members of their environment. Paleoecology uses the fossil record to interpret and reconstruct life habits of past organisms and environments. By examining well-preserved fossil populations we can assess the relationship between the organisms and their surrounding environment, …

Petrology And Geochemistry Of Olivine-Bearing Diogenites And A Group Of Paired Howardites, Andrew William Beck

Doctoral Dissertations

Asteroid 4 Vesta, the largest differentiated body in the asteroid belt, is a protoplanet, much like those that accreted to form the Earth. Understanding the geology of Vesta furthers understanding of early differentiation processes that occurred on Earth and helps define igneous processes occurring on other differentiated bodies in the early solar system. Howardite, eucrite and diogenite (HED) meteorites, which are thought to have originated from Vesta, can be analyzed to better understand the geology of that asteroid. Here my colleagues and I investigate the petrology and geochemistry of two groups of HEDs. This work is timely, in that the …

Oceanic-Atmospheric And Hydrologic Variability In Long Lead-Time Forecasting, Abdoul Aziz Oubeidillah

Doctoral Dissertations

Water managers throughout the world are challenged with managing scarce resources and therefore rely heavily on forecasts to allocate and meet various water demands. The need for improved streamflow and snowpack forecast models is of the utmost importance. In this research, the use of oceanic and atmospheric variables as predictors was investigated to improve the long lead-time (three to nine months) forecast of streamflow and snowpack. Singular Value Decomposition (SVD) analysis was used to identify a region of Pacific and Atlantic Ocean SSTs and a region of 500 mbar geopotential height (Z500mb) that were teleconnected with streamflow and snowpack. The …

Geochronologic And Isotopic Investigation Of The Koipato Formation, Northwestern Great Basin, Nevada: Implications For Late Permian-Early Triassic Tectonics Along The Western U.S. Cordillera, Nicholas Quentin Vetz

Boise State University Theses and Dissertations

The volcanics of the Early Triassic Koipato Formation of central Nevada unconformably overlie the Golconda Allochthon and, classically, this relationship has been used to define the timing of the Sonoma Orogeny as post-Middle Permian to earliest Triassic. However, the Koipato Formation represents a rather isolated magmatic succession, with other western U.S. Early Mesozoic igneous provinces determined to be younger or lacking rocks of Koipato age. This isolation, coupled with the fact that the Koipato Formation does not overlap the Golconda Allochthon, has left open two possible scenarios for its tectonic history: 1) the Koipato Formation represents the earliest, post-Sonoma Orogeny …

Critical Thresholds For Sediment Mobility In An Urban Stream, Ross H. Martin

Geosciences Theses

Bed load transport measurements were made in a small urban stream in Decatur, GA, from which thresholds for motion were calculated using methodologies from the published literature. These methodologies are discussed in terms of their limitations and assumptions. Mobility frequencies were calculated for single grains of each grain size fraction to illustrate the transition from size selective transport to equal mobility. In general, urban streams behave differently than many gravel rivers in non-urban settings because of differences in the availability and character of sediment sources and altered flow hydrographs. This comparison allows for discussion about the way sediment is transported …

Effects Of High-Density, Short-Duration Planned Livestock Grazing On Soil Carbon Sequestration Potentials In A Coastal California Mixed Grassland, Kristina Michelle Wolf, Marc Horney, Brent Hallock, Robert T. Rutherford, Anthony T. O'Geen, Royce Larsen, William Plummer

Master's Theses

Planned grazing management in rangelands may improve carbon sequestration potential of soils by increasing plant biomass and the rate of nutrient cycling, which might mitigate global warming. The effects of high-intensity, short-duration planned grazing of sheep on several soil and ecosystem properties were investigated on a mixed grassland in San Luis Obispo, CA. The objectives of this study were to (a) identify soil properties related to soil C sequestration in rangelands; (b) determine if planned grazing improved soil carbon sequestration; (c) quantify changes in identified variables in grazed and rested plots; and (d) analyze any changes in plant species composition …

Environmental Magnetism Survey Of A Holocene Sedimentary Record From Barilari Bay, Western Antarctic Peninsula, Carl Joseph Natter Jr.

Theses, Dissertations and Culminating Projects

Barilari Bay is located on the western side of the Antarctic Peninsula (AP), opposite the former Larsen B Ice Shelf on the eastern Antarctic Peninsula. Barilari Bay was swath mapped during United States Antarctic Program cruise NBP10-01 as part of the Larsen Ice Shelf System, Antarctic (LARISSA) program. The bay consists of a series of five basins with water depths greater than 600 meters, from which a suite of kasten cores and jumbo piston cores was collected. Three cores, JPC-127, its trigger core TC- 127, and JKC 55 were collected from the outer portion of the Bay and recovered an …

Mapping The River Kilometers Of Potential Daylighting Projects In Northeast New Jersey, Omoniyi Ayodeji Asaolu

Theses, Dissertations and Culminating Projects

A river offers many benefits to people who live near it, including transportation, a source of food, waste disposal, and water resources for consumption. Because of these advantages many great cities were built around rivers impacting rivers in many ways. While the effects of urban development on water quality have long been studied, this study measures how development has caused streams to disappear from the landscape. It was observed that some streams were buried due to negative impacts of urbanization. Public safety and flood control were some of the reasons these streams were buried, but with the advent of green …

Geochemical Analysis Of Long Island Sound Sediments, Jaroslaw W. Slusarczyk

Theses, Dissertations and Culminating Projects

As one of the largest estuarine systems in the northeastern United States, Long Island Sound (LIS) has been exposed to human activities for many centuries. Human settlement and population growth in the last 200 years has caused heavy pollution in LIS through inland and shore industrial and municipal releases. The geochemistry of one sediment core and numerous surface sediment samples were analyzed using environmental forensic techniques. This study employed use of pyrolysis gas chromatography/ mass spectrometry (Py-GC/MS) in conjunction with previously analyzed geochemical and radiometric data to study contamination sources and patterns though LIS. Geochemical analysis of samples was focused …

Groundwater Contamination Potential In Northern Nevada From Mining, Associated Communities, And Agriculture As Forecasted By Two Vulnerability Methods, John L. Swatzell

UNLV Theses, Dissertations, Professional Papers, and Capstones

Two methodologies, DRASTIC and the NDEP method, were used to compare the groundwater vulnerability of mining, associated towns, and agricultural areas in northern Nevada. The DRASTIC and NDEP methods were compared to determine which method produces a more accurate depiction of vulnerability. Vulnerability maps were created using the United States Environmental Protection Agency's (USEPA) DRASTIC and Nevada Department of Environmental Protection (NDEP) methodologies. The DRASTIC map uses seven aspect layers of geologic and hydrologic information with assigned values and weights that are applied to a mathematical equation. The NDEP method uses field data collection for potential contaminant sources and well …

Raman Spectroscopic Study Of Solid Solution Spinel Oxides, Brian D. Hosterman

UNLV Theses, Dissertations, Professional Papers, and Capstones

Solid solution spinel oxides of composition MgxNi1−xCr2O4, NiFexCr2−xO4, and FexCr3−xO4 were synthesized and characterized using x-ray diffraction and Raman spectroscopy. Frequencies of the Raman-active modes are tracked as the metal cations within the spinel lattice are exchanged. This gives information about the dependence of the lattice vibrations on the tetrahedral and octahedral cations. The highest-frequency Raman-active mode, A1g, is unaffected by substitution of the divalent tetrahedral cation, whereas the lower frequency vibrations are more strongly affected by substitution of the tetrahedral cation. The change in wavenumber of many phonons is nonlinear upon cation exchange. All detected modes of MgxNi1−xCr2O4 and …

Evaluating Substrate Metrics For Monitoring Sediment Impairment Of East Tennessee Streams., James Hunter Terrell

Masters Theses

Section 303(d) of the Clean Water Act (CWA) requires states to assess and list all streams that do not meet water quality criteria for their designated use classes. In Tennessee, the Tennessee Department of Environment and Conservation (TDEC) uses macroinvertebrate surveys to assess the condition of streams designated for “fish and aquatic life” and the progress of targeted waterbodies toward meeting established standards for sediment. As of yet, no substrate metric has been established to monitor water quality or to document progress toward water quality improvement with respect to fish and aquatic life in Tennessee. A substrate metric that could …