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- Stainless steel (4)
- Cyclic voltammetry (3)
- Photocurrent (3)
- Platinum electrode (3)
- Copper (2)
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- Corrosion (2)
- Cytochrome c (2)
- Electrocatalytic oxidation (2)
- Electrochemistry (2)
- Ion implantation (2)
- Lead electrode (2)
- Passive films on REBAR (2)
- Photoelectrochemistry (2)
- Underpotentialdeposition (2)
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- 2-ethylan-thraq uinone (1)
- 4 (1)
- 4'-Dithiodipyridine (1)
- 4-butynediol (1)
- A.V. modulation (1)
- AES (1)
- Absorption of oxygen (1)
- Activation (1)
- Activator (1)
- Additive (1)
- Adenine (1)
- Adsorbed antimony atom (1)
- Al-Mn alloy (1)
- Alkaline (1)
- Aluminum sacrificial anode (1)
Articles 31 - 60 of 72
Full-Text Articles in Physical Sciences and Mathematics
Properties Of Zr-Based Laves Phase Hydrogen Storage Electrode, Xueping Gao, Huabin Yang, Deying Song, Yunshi Zhang, Zuoxiang Zhou, Wei Zhang, Panwen Shen
Properties Of Zr-Based Laves Phase Hydrogen Storage Electrode, Xueping Gao, Huabin Yang, Deying Song, Yunshi Zhang, Zuoxiang Zhou, Wei Zhang, Panwen Shen
Journal of Electrochemistry
After treated by HF solution,the surface of Zr(V_(0.2)Mn_(0.2)Ni_(0.54)Mo_(0.06))_(2.4) alloywas transformed from Zr-rich and Mn-rich layer to Ni-rich layer.In this way,the nickel on thesurface could be believed to be the Raney-type nickel, which could obviously shorten the activationcycles,improve electrocatalytic activity and hydrogen adsorption ability.In this paper,the reactionmechanism on the alloy surface(i.e. the mechanism of nickel-catalysis,hydrogen-adsorption andhydrogen-transference)had been investigated.And the impedance spectra were fitted to an equivalentcircuit using a non-linear,least-squares(NLLS)fitting program.
Coadsorption Of Para-Toluene Sulfamide And 1.4-Butynediol At Mercury Electrode, Shukun Huang, Naixian Xie, De Gao, Qiang Liu
Coadsorption Of Para-Toluene Sulfamide And 1.4-Butynediol At Mercury Electrode, Shukun Huang, Naixian Xie, De Gao, Qiang Liu
Journal of Electrochemistry
The coadsorption characteristics of para-toluene sulfamide and 1,4-butynediol atmercury electrode have been studied by means of electrocapillary curve,differential capacity curve,Stuart model and the SCFMO method(CNDO/2).The coadsorption is a physical adsorption occuringnaturally. Lateral and flat orientations in the two adsorbates close to their maximum adsorptionpotential were considered respectively.Unlike attractive interactions of their own,there was arepulsive interaction at their coadsorption layer.A preferred adsorption of 1,4-butynediol occurredWhen they were at the same volume concentration.
A Relativistic Density-Functional Investigation Of Vibrational Frequencies Of Cn￣- On Cu And Ag Electrodes, Mengsheng Liao, Xin Lv, Qianer Zhang
A Relativistic Density-Functional Investigation Of Vibrational Frequencies Of Cn￣- On Cu And Ag Electrodes, Mengsheng Liao, Xin Lv, Qianer Zhang
Journal of Electrochemistry
Abstract Potential Dependence,Vibrational Frequency,copper-electrode,Silver-electrode,Relativistic density-functional calculationAcknowledgements This work was supported by the National Natural Science Foundationof China and ChinaPostdoctoral Science Foundation.
Development Of High Active Aluminum Alloy Sacrificail Anode, Zhaobo Wei, Jianhua Wu, Guangzhang Chen, Songrao Jiang
Development Of High Active Aluminum Alloy Sacrificail Anode, Zhaobo Wei, Jianhua Wu, Guangzhang Chen, Songrao Jiang
Journal of Electrochemistry
A high active aluminum alloy sacrificial anode with the operating potential-1.40 v (SCE),and the the current capacity more than 2 175 A·h/kg and dissolution fair issuccessfully developed by adding zinc,indium,gallium,bismuth and heat treatment.The aluminumalloy sacrificial anode with super electrochemical properties can throughly replace the magnesium alloyanode when applied to seawater and freshening seawater,which is obviously advantageous to thetechnology and economy.
The Oxidation Of Hydrogen Absotbing Alloys And Its Inhibition, Suqin Wang, Baojia Xia, Geping Yin, Pengfei Shi
The Oxidation Of Hydrogen Absotbing Alloys And Its Inhibition, Suqin Wang, Baojia Xia, Geping Yin, Pengfei Shi
Journal of Electrochemistry
This paper introduces the method to judge:1)the possibility of oxidation of themetal hydride electrode in an anode process by cyclic voltammetric curves,2)the oxidation pattern ofmetal hydride electrode in oxygen atmosphere in various charged states,and 3)the inhibition ofoxidation of hydrogen absorbing alloys by certain surface treatment.
Photoelectric Property For Zinc Phthalocyanine Of Doping C_(60) On Inp Electrode, Mengxiong Zhan, Rongqing Yu, Biaolian Zhen, Dadian Cheng, Lansun Zheng
Photoelectric Property For Zinc Phthalocyanine Of Doping C_(60) On Inp Electrode, Mengxiong Zhan, Rongqing Yu, Biaolian Zhen, Dadian Cheng, Lansun Zheng
Journal of Electrochemistry
The curves of spectral and photovoltaic responses to zinc phthalocyanine of dopingC_(60) were determinted.The photovoltaic property for zinc phthalocyanine of doping C_(60) wereinvestigated on the InP single crystal in the photoelectrochemical cell.The results have shown that:1)The photovoltaic effect and the in tensit ies of the spectral response and of the photovoltaic responsefor ZnPc of doping C_(60) were greater than those of ZnPc;2)had better redox couple in the cells.
Studies On The Bright Zinc-Nickel Alloy Palting In Alkaline Baths, Jiale Cai, Shaomin Zhou
Studies On The Bright Zinc-Nickel Alloy Palting In Alkaline Baths, Jiale Cai, Shaomin Zhou
Journal of Electrochemistry
The electrochemical properties of the Zn-Ni plating baths and the structure andperformance of the obtained deposits were investigated.The results show that the nickel content of theobtained deposits is incereased with decreasing of Zn￣(2+)/Ni￣(2+) ratio in the baths and with increasing ofcathodic current density;The cathode current efficiency is increased with increasing of Zn [Ⅱ]content in the bath and with decreasing of cathodic current density.The ZN-11 additive used is thereaction product of heterocyclic compound and polyamines with epichlorohydrin,it has a higheradsorptivity on Hg-electrede at potential between -0.16～-1.68 V (vs. Hg/HgO,1 mol·L￣(-1)KOH). It is found that zinc and nickel are codeposited anomalously due …
Study On The Surface States Of Zinc Sulfide Thin Film Doped With Erbium And Their Effect On The Relaxation Luminance, Yujiang Wang, Zhaohong Liu, Zhenxiang Chen
Study On The Surface States Of Zinc Sulfide Thin Film Doped With Erbium And Their Effect On The Relaxation Luminance, Yujiang Wang, Zhaohong Liu, Zhenxiang Chen
Journal of Electrochemistry
X-ray photoelectron spectrum and characteristics of the capacity,versus thevoltage of the thin film devices are measured to study the surface states of the zinc sulfide thin film.The transient electroluminescence excited by pulses shows the relaxation luminance peaks during anon-exponential decay process of the characteristic transitions activated by Er￣(3+) in the ZnS directcurrent thin film electroluminescence (DCTFEL) devices.The surface structures of ZnS:Cu,Cl,Erfilm with the absorption of oxygen,and the effect of the surface states on the relaxation luminance ofthe devices are discussed.
Electrochcmical Reaction Of Redoxproteins Speeded Up By The Dye Modified Electrodes, Ting Chen, Shaojun Dong, Yuanwu Xie
Electrochcmical Reaction Of Redoxproteins Speeded Up By The Dye Modified Electrodes, Ting Chen, Shaojun Dong, Yuanwu Xie
Journal of Electrochemistry
The electron transfer reaction of redox proteins faciliated by dye medifiedelectrede was reviewed in this paper.The medification metheds and the properties of dye modifiedelectrede were discussed. Several different studying metheds,such as voltammetry,flow analysis andspectroelectrochemical methed,were reviewed.Areversible electrocatalytic reaction mechanism wasproposed and verified by comparing the digital calculation results with the experimental results.47references were cited.
The Effects Of Magnetic Field Onthe Electropolymerization Of Aniline, Lintao Cai, Shibing Yao, Shaomin Zhou
The Effects Of Magnetic Field Onthe Electropolymerization Of Aniline, Lintao Cai, Shibing Yao, Shaomin Zhou
Journal of Electrochemistry
The aniline electropolyinerization under the magnetic field was studied by cyclicvoltammetry and potentiostatic step techniques. Theinaximum peak current was obtained at 0. 58 Twhen the magnetic flux was perpendicular to the surface of the working electrede in H_2SO_4 solution.These were speculated in terins of magnetic dircctional effect. But when the magneic flux directed inparallcl with the surface of elcctrode, the peak current obviously increased as the magnetic flux densityrised. The results uere explained as the enhancement of mass transfer by magnetohydredynamic(MHD) mechanism. The PAN film growth via a two-dimentional (2-D) instantaneous nucleationunder the electron transfer kinetic controlled. The enhanced effects …
Laser Scanning In-Situ Photoelectrochemical Microscopictechnique And Its Applications, Zugeng Lin, Jinkua You, Xiangdong Zhuo, Chun Zhang, Yong Yang
Laser Scanning In-Situ Photoelectrochemical Microscopictechnique And Its Applications, Zugeng Lin, Jinkua You, Xiangdong Zhuo, Chun Zhang, Yong Yang
Journal of Electrochemistry
Abstract The main factors of the laser scanning in-situ photoelectrochemical microscopicmeasurement system which is set up in our lab have been discusaed in this paper. Some applications ofthis technique for insttn study of medificiition and processing of semiconductor electrodes , monitoringof electredeposition process of semiconducting material and redox reaction occurring at metal oxideelectrodes have aiso been presented. The results have shown that the technique is very powerfui thatfor studing local photoelectrochemical properties of semiconductors and metal oxide electredes. Theseprovide important information on the micro structural and electronic properties in the solidlelectrolyteinterface.AbstractLaser scanning, Local photocurrent spectroscopy, Photoelectrochemical,Semiconductor electode
The Electrochemical Reduction Of 2-Ethylanthraquinone(2eaq), Yaobin Zhu
The Electrochemical Reduction Of 2-Ethylanthraquinone(2eaq), Yaobin Zhu
Journal of Electrochemistry
The process of electrochemical reduction of 2EAQ in DMSO is studied using CVand ESR methods in this work, Pt, Pd and some implanted materials are used as electrodes. Thequasi-rever+sible property of two electron transfer steps and their following homogeneous chemicalreactions are illustrated,The mechanism of the electrochemical red uction of 2 EAQ and the kineticparameters of the related steps are obtained. Having measured the influence of water content in thesystem, the effect of the proton donor is discussed. After comparising the experimental results witheach other these experiments gives us the idea that the replacement of metal Pd or some Pd-catalystswith pd-implanted …
An Indirect Electrochemical Oxidation Of Toluene──Anodic Oxidation Of Mn(Ⅱ) On The Lead Electrode, Zhonghua Wang, Qingmin Hua, Guaeai Chen
An Indirect Electrochemical Oxidation Of Toluene──Anodic Oxidation Of Mn(Ⅱ) On The Lead Electrode, Zhonghua Wang, Qingmin Hua, Guaeai Chen
Journal of Electrochemistry
The electrochemical oxidation of Mn (Ⅱ) to Mn(Ⅱ) in concentrated H_2SO_4(2￣8 mol . L-1) at lead electrede has been studied. It is found that the electrede surface is oxidized toPbO_2 in a direct electrochemical reaction, then PbO_2formed reacts with Mn (Ⅱ) in a chemicalreaction. Some effects involves current density , concentration of H_2SO_4 , temperature and conversionwere evaluated. The rule of electrogenerated Mn (Ⅲ) in flow electrolysis cell were determined atseveral conditions. The current efficiency at greater than 90% is obtained in general.
Photoelectrochemical And Spectroelectrochemical Studies Oniron Oxide Ultrafine Particles, Maizhi Yang, Yongjun Ji, Wen Zhang, Shengmin Cai
Photoelectrochemical And Spectroelectrochemical Studies Oniron Oxide Ultrafine Particles, Maizhi Yang, Yongjun Ji, Wen Zhang, Shengmin Cai
Journal of Electrochemistry
in this paper, Raman spectra, photocurrent and the UV-VIS reflectance aremeasured for studying the α-Fe_2O_3ultrafine particles adsorbed on Pt electrode. The blue shifts ofRaman peaks demonstrate the size quantization effect for the particles of 50 nm in diameter ascompared with the bulk material. With the changing of the potential , the photocurrent decrcases as theUV-VIS reflectance increases, and vice-versa. Therefore, the potential not only affects the hargetransfer direcdtion in the interface of electrede/redox couple, but also influences the light absortion onthe surface of particles.According to the results of photoelectrochemistry, we suggest that the cathedicphotocurrent in the potential range of more …
A Sutface-Enhanced Raman Spectroscopic Study On The Inhibition Mechanism Of Bmat On Stainless Steel In Hydrochloric Acid Solutions, Yinghua Zha, Baoming Wei
A Sutface-Enhanced Raman Spectroscopic Study On The Inhibition Mechanism Of Bmat On Stainless Steel In Hydrochloric Acid Solutions, Yinghua Zha, Baoming Wei
Journal of Electrochemistry
The absorbtion of some nitrogen and sulfur compounds such as BMAT on 18-8stainless steel(SS)in 0.5% HCl were investigated by surface enhanced Raman scattering(SERS)spectroscopy.The SERS spectra of BMAT adsorbed on SS were measured using a SS electredepositedwith discontin uous silvet micro-islands.The results show that the inhibitor,BMAT,is chemisorbed onthe SS surface through the N atom. Under the influence of π-electron interaction ,BMAT can beadsorbed on SS surface at an angle. The allyls in BMAT molecules play the role of steric hindrance inthe inbibition effect.
Study On The Electron Transfer Process Of Cytochrome C With Different Charge Transfer Promoters, Guoxin Tang
Study On The Electron Transfer Process Of Cytochrome C With Different Charge Transfer Promoters, Guoxin Tang
Journal of Electrochemistry
The diffusion coefficient D. standard rate constant and transfer coefficient afor electron transfer process of cytochrome C at OTTLE in the presence of 4,4'-Dithiedipyridine(PySSPy),Adenine and L-Cysteine were determined by the chronoadsorptometric technique with Au-OTTLE. A computer fitting method was used to calculated these kinetic parameters.The mechanismsof PysSPy,Adenine and L-Cysteine were used as the promoters,and were also discussed.
Horseradish Peroxidase/Poly-O- Phen Ylenediamine Mem Brane Electrode:Preparation And Properties, Dong Wei, Huihuang Wu
Horseradish Peroxidase/Poly-O- Phen Ylenediamine Mem Brane Electrode:Preparation And Properties, Dong Wei, Huihuang Wu
Journal of Electrochemistry
A horseradish peroxidase(HRP)/poly-o-phenylenediamine(PPD)membraneelectrede was prepared by electropolymerization of o-phenylenediamine on glassy carbon in pH 7.0phosphate buffer,the process of the enzyme immobilization was studied,The enzyme electredeobtained exhibits the activity to catalyze the electrored uction of hydrogen peroxide in the absence ofany electron transfer mediator.The red uction reaction occurs in the potential range of PPD redoxprocess,it was believed that the polymer participates in electron transfer of the enzyme.The enzymereaction kinetics at rotating H RP/PPD electrede was analysed,and the factors influencing kineticparameters were discussed.
Studies Of The Black Molybdate Conversion Film On Stainless Steel, Jingli Fang, Liuqin Liuqin, Keping Han, Yaohui Chen
Studies Of The Black Molybdate Conversion Film On Stainless Steel, Jingli Fang, Liuqin Liuqin, Keping Han, Yaohui Chen
Journal of Electrochemistry
A black conversion film was formed on stainless steel with cathodicelectrodeposition method from a molybdate-phosphate solution. This film displayed goodthemcotability. The results of XPS and AES analysis showed that the thickness of the film was 820 nmand that Mo existed as Mo(Ⅵ)in the surface of the film,while existed as Mo(Ⅵ)and Mo(Ⅳ)in theinternal layer of the film. The relative atomic percent content(A,C.% of the film obtained from theelemental composition constant region of the depth profile curves by AES was O 50.9%,Mo 29.4%,P12.6%and Fe 7.1%respectively.The cyclevoltammetric oxluation peak also showed that Mo(Ⅳ)existed in the internal layer of the film.
Study Of The Electrochemistry Of Systems Of Practical Importance, Chuansin Cha, Juntao Lu
Study Of The Electrochemistry Of Systems Of Practical Importance, Chuansin Cha, Juntao Lu
Journal of Electrochemistry
Research projects mainly of the following two categories have been carrying on inthis laboratory:1.Development of experimental electrochemical methedes,including traditional electrochemicaland spectro-electrochemical techniques suitable for the study of practical electrochemical systems,suchas porous electrodes,powdery materials,hazardous(toxic,explosive)systems,etc.2.Study of electrochemical systems possessing practical importance,including mechanistic andelectrocatalytic studies.The studied electrochemical systems are mostly related to electrochemicalpower sources,electrochemical sensors and electrochemical synthesis.
Studies On Low Temperature Performance Of Rechargeable Mh-Ni Batteries, Wenkuan Zhang, Jingxian Shi, Yu Wan Lou, Qiusheng Duan
Studies On Low Temperature Performance Of Rechargeable Mh-Ni Batteries, Wenkuan Zhang, Jingxian Shi, Yu Wan Lou, Qiusheng Duan
Journal of Electrochemistry
The Dependence of low temperature performance on the alloy composition andelectrolyte component for rechargeable MH-Ni batteries is studied, the suitable composition of alloyand electrofyte are founds.
Electrochemically Modified Glassy Carbon Electrode And Determination Of Copper By Anodic Stripping Voltammetry, Jinrui Xu, Yie Liu, Xiurun Zhuang
Electrochemically Modified Glassy Carbon Electrode And Determination Of Copper By Anodic Stripping Voltammetry, Jinrui Xu, Yie Liu, Xiurun Zhuang
Journal of Electrochemistry
This paper reported the glassy carbon electrode modified by cyclic voltammetrybetween-0. 1and + 1. 5 V(vs. SCE)in an aqueous solution containing catechol,formaldehyde andtalium hydroxide. The modified electrode can be applied to the determination of copper(Ⅱ) in water,and its sensitivity is about 35 times higher than that of unmedified glassy carbon electrede, Thequantitative limit with this modified electrede is 0. 1 ng/ml.
The Reduction Of Oxygen To Hydrogen Peroxide At The Poly(O-Phenylenediamine)-Filmed Electrode, Zhaoe Lu, Tiangeng Zhong, Guanyong Zhang
The Reduction Of Oxygen To Hydrogen Peroxide At The Poly(O-Phenylenediamine)-Filmed Electrode, Zhaoe Lu, Tiangeng Zhong, Guanyong Zhang
Journal of Electrochemistry
The poly(o-phenylenediamine)(PPD)filmed graphite electrode was formed byelectro-polymerization of o-phenylenediamine in acidified(pH=1)0.2 mol·L-1 Na_2SO_4 solutionusing the cyclic voltammetric methed. The catalytic effect of the electrcareduction of oxygen in acidsolution was demonstrated by the voltammogram of the electrede in the oxygen saturated acid solutionof Na_2SO_4. The current efficiency of the reduction of oxygen to hydrogen peroxide was determined byIhe electrolysis in a divided cell under the condition of constant current. The various effectsinfluencing the accm ulation of H_2O_2 in the catholyte were discussed.
Studies On Coordination Behavior Of Dimethyl Sulfoxide In Complex Of Rare Earth With Cryptand, Shichang Liu
Studies On Coordination Behavior Of Dimethyl Sulfoxide In Complex Of Rare Earth With Cryptand, Shichang Liu
Journal of Electrochemistry
lectrochemical reduction reaction in the course of the titration of Eu ( 2.2.2)and Eu( 2.2)using strong bonding solvent,DMSO,in C_2H_4Cl_2 has been investigated by cyclicvoltammetry. The greater the concen tration of strong bonding solvent,the more negative the half-wave potentials for the reduction reaction are. The coordination number of Eu(2.2.2 ) and Eu(2.2)which are 2 and 3 respectively,with DMSO can be calculated,according to the relations betweenhalf -wave potentials and the variety of concentration of DMSO.
The Formation And Voltammetric Behavior Of Manganese Chlorophyll, Qingdong Qiao
The Formation And Voltammetric Behavior Of Manganese Chlorophyll, Qingdong Qiao
Journal of Electrochemistry
The formation and voltam metric behavior of manganese chlorophyll werestudied.The electrochemical red uction mechanism of Mn chlorophyll a (MnChla)in aqueous solutionwas investigated and discussed.During the electrored uction of MnChla ,the porphyrin ring was singlyreduced with 2 electrons and the Mn￣(2+) ion remained its original state,The reduction rate constant k_m=0.36/s was gained.
Application Of Voltammetry In Analysis Of Electroplating Baths, Jiayuan Xu, Shaomin Zhou
Application Of Voltammetry In Analysis Of Electroplating Baths, Jiayuan Xu, Shaomin Zhou
Journal of Electrochemistry
Based upon the electrochemical characteristics of the components or impurities tobe determined in the electroplating baths,and the inhibition or activation effect of the additives usedon the electrodepcosition processes of metals and alloys,direct voltammetry,indirect voltammetry andvoltammetry with anodic stripping of metallic deposits,were suggested to determine the concentrationof some components,several impurities and the additives usually used in the electroplating baths.Theprocedure of those methtods are simple and rapid,and are suitable to be used for in situ control inelectroplating workshops.
A Investigation Of Hydrogen-Storage Alloy As Catalytic Electrode For Hydrogenation Of Nitrobenzene, Shigang Lu, Hanxi Yang, Changfa Wan
A Investigation Of Hydrogen-Storage Alloy As Catalytic Electrode For Hydrogenation Of Nitrobenzene, Shigang Lu, Hanxi Yang, Changfa Wan
Journal of Electrochemistry
Since hydrogen.storage alloy ean not only absorb hydrogen atoms to form highlyreactive metal hydride as hydrogen source by electrolysis but also possesses a certain catalytic activityfor hydrogenation,it is thus feasible to utilize the allov as a novel electrOde for electrolvtichydrogenation in organic electrored uction. This work employed misch metal AB_5 type alloy as acatalytic electrode and studied the electrochemical hydrogenation of nitrobenzene. The hydrogen-storage electrede(MH)was a plastic bonded electrede sheet made from a paste ofMm(NiCoMnAl)_5 alloy powder and teflon emulsion. The electrolysis was performed at constantcurrent and controlled potential in a three electrede cell of H-type configuration. The electrolyte was0.5 …
Electroreduction Of The Nittobenzene On Titanium Electrode Implanted With Palladium, Zhongda Wu, Xianjun Zhu, Hongsen Wang
Electroreduction Of The Nittobenzene On Titanium Electrode Implanted With Palladium, Zhongda Wu, Xianjun Zhu, Hongsen Wang
Journal of Electrochemistry
The titanium substrates were bombarded with 1×10￣(17)～5×10￣(17)ions·cm￣(-2) ofpalladium at the room temperature. The surface composition of implanted electrede and concentration-depth profiles of various elements were measured by AES. The electrored uction processes ofnitrobenzene(NB)in 0.1 mol/L NaOH solution at Pd/Ti electrodes have been investigated by cyclicvoltaivimetry.The results show that the palladium implanted titanium electrodes exhibit a high catalyticactivity in the electroreduction of NB. The NB radical anion,which is the product of one-electronelectroreduction of NB,was detected by ESR in-situ in conjunction with electrochemical methods. Aniline was also detected as a product of electroreduction of NB by using UV-spectra in-situ. According to the …
Atomic And Molecular-Perspectives In Electrochemical Interfaces, Zhaowu Tian
Atomic And Molecular-Perspectives In Electrochemical Interfaces, Zhaowu Tian
Journal of Electrochemistry
The following recent studies on the atomic and molecular-perspectives atelectrochemical interfaces using Raman,IR,STM and quantum chemical methed by electrOchemistrygroup in Xiamen University are briefly reviewed. 1.Orientation,charge transfer and bonding of adsorbed molecules. 2.Adsorption effect,electrode potential effect and adatom effect on the electron populations and strength of intramolec ular bonds of the adsorbed molecules. 3.Detailed classification into various types(e. g.,competitive,chemically inductive, physical inductive etc.)of coadsorption on electrodes according to the above-mentioned effects. 4. Single crystal face structure effect and adatom effect on the kinetics and the mechanisms of electrocatalytic oxidation processes of small organic molecules. 5.Electrochemical scanning tunneling microscopy(ECSTM)specially designed for …
Studies Of Elecctrochcmical Oscillation Of Au/Hcl In Presence Of ″Positive Feedback ″Of Substrate Electrodes, Bin Ren, Bingwei Mao, Xiongwei Cai, Tao Jiang, Jiqian Mu
Studies Of Elecctrochcmical Oscillation Of Au/Hcl In Presence Of ″Positive Feedback ″Of Substrate Electrodes, Bin Ren, Bingwei Mao, Xiongwei Cai, Tao Jiang, Jiqian Mu
Journal of Electrochemistry
No abstract provided.
Electrocatalytic Oxidation Of Formaidehyde And Formic Acid On A Pt/Sb_(Ad) Electrode, Hong Li, Lincai Jiang, Xiong Jiang
Electrocatalytic Oxidation Of Formaidehyde And Formic Acid On A Pt/Sb_(Ad) Electrode, Hong Li, Lincai Jiang, Xiong Jiang
Journal of Electrochemistry
The electrocatalytic activity for the oxidation of formaldehyde and formic acid ona Sb-modified platinum (Pt/Sb_(ad))was investigated.Results showed that the Pt/Sb_(ad) electrode waselectrocatalytically more active than a Pt electrode in the anodic oxidation of formaldehyde and formicacid.In the case of formaldehyde,an oxidation peak appeared at a potential of ca.0.7V.During theoxidation of formic acid,a 4-fold increase in the 1st peak current was observed.The Sb-modifiedplatinum electrode was found to be most electrocatalytically active at a coverage of 0.75±0.05.Theelectrocatalytic activity of the Pt/Sb_(ad) electrode can be best explained in terms of the geometrical effect,which may lead to the inhibition of the formation of the …