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Avian Chemical Repellency: A Structure-Activity Approach And Implications, Pankaj Shah, Russell Mason, Larry Clark
Avian Chemical Repellency: A Structure-Activity Approach And Implications, Pankaj Shah, Russell Mason, Larry Clark
Larry Clark
Until recently, the discovery of avian sensory repellents has been empirical (MaRnn, AnAmR 'Inn l;qr\r FlR'l), Hm> !ilv!ilr, recent liltudilillil in our laboratory have shown that many avian repellents have similar perceptual and structural properties (Mason et al. 1989; Mason Clark and Shah 1991; Clark and Shah 1991; Clark, Shah and Mason 1991; Shah, Clark and Mason 1991). For example, methyl anthranilate, which has a grapy odor, is repel lent to birds (Kare and Pick, 1960). Ortho-aminoacetophenone has an odor and structure similar to that of methyl anthranilate, differing only in the substitution of a ketone for an ester group …
Taxon-Specific Differences In Responsiveness To Capsaicin And Several Analogues: Correlates Between Chemical Structure And Behavioral Aversiveness, Russell Mason, Jay Bean, Pankaj Shah, Larry Clark
Taxon-Specific Differences In Responsiveness To Capsaicin And Several Analogues: Correlates Between Chemical Structure And Behavioral Aversiveness, Russell Mason, Jay Bean, Pankaj Shah, Larry Clark
Larry Clark
The present set of experiments was designed to explore avian insensitivity to capsaicin. Based upon a molecular model of avian chemosen sory repellency, we hypothesized that structural modifications of the basic capsaicin molecule, which is itself not aversive to birds, might produce aver sive analogues. To this end, European starlings (Sturnus vulgaris) and Nor way rats (Rattus norvegicus) were given varied concentrations of synthetic capsaicin and four analogues (methyl capsaicin, veratryl amine, veratryl acet amide, vanillyl acetamide) in feeding and drinking tests. The results agreed with a model that we are developing to describe the chemical nature of avian repellents. …