Forest Sciences Commons^™

Production And Applications Of Formaldehyde-Free Phenolic Resins Using 5-Hydroxymethylfurfural Derived From Glucose In-Situ, Yongsheng Zhang

Electronic Thesis and Dissertation Repository

The phenol-formaldehyde (PF) resin manufacturing industry is facing a growing challenge with respect to concerns over human health, due to the use of carcinogenic formaldehyde and sustainability due to the use of petroleum-based phenol in PF resin manufacture. Glucose and its derivative, 5-hydroxymethylfurfural (5-HMF), have proven to be potential substitutes for formaldehyde in the synthesis of phenolic novolac resins.

This thesis investigated a number of glucose and 5-HMF resin systems including the curing of phenol-glucose novolac resin (PG) with a bis-phenol-A type epoxy. The curing process was modeled according to the Sestak-Berggren equation (S, B) using Málek methods. This was …

Ecohydrological Function Of Lower Coastal Plain Bioretention Cells In South Carolina, Jessica Palazzolo

All Theses

Flooding and stormwater control is a critical issue in coastal South Carolina because of shallow water table elevation, topography and rapid urbanization in the region. A best management practice (BMP) using low impact design (LID) principles known as a bioretention cell (BRC) is gaining popularity for stormwater management. Five BRCs in four landscape positions (well-drained uplands, tidal-proximal, poorly-drained-uplands, and floodplain) were instrumented for microclimate, soil moisture, and water table elevation for hydraulic efficiency and for water quality measurements. Three BRCs did not have an overflow outlets, one BRC (floodplain) employed an underdrain system, and one BRC (tidal proximal) had an …

Evaluation Of Methods For Control Of Vegetation In Utility Corridors, George V. Rancea

Master's Projects and Capstones

Vegetation management programs are now one of the largest budget items for most of the utility companies in the United States. Control methods used in line clearance activities include mechanical trimming, planting management, or use of tree growth regulators (chemicals that suppress the production of gibberellins, the plant hormones that control stem elongation). Choosing the appropriate control method is a decision that vegetation program managers should take based on many factors, like costs, environmental impacts, existing agreements with the landowners, terrain, public perception etc. To find a balance between competing interests – a reliable and economic electric system on one …

2013 Annual Report Of Uvm Extension And The Vermont Agricultural Experiment Station, Uvm Extension And Vermont Agricultural Experiment Station

Annual Reports

2013 Annual report of outreach and research from UVM Extension and Vermont Agricultural Experiment Station.

Forest Biomass Supply Chains In Ireland: A Life Cycle Assessment Of Ghg Emissions And Primary Energy Balances, Fionnuala Murphy

Fionnuala Murphy

The demand for wood for energy production in Ireland is predicted to double from 1.5 million m3 over bark (OB) in 2011 to 3 million m3 OB by 2020. There is a large potential for additional biomass recovery for energetic purposes from both thinning forest stands and by harvesting of tops and branches, and stumps. This study builds on research within the wood-for-energy concept in Ireland by analysing the energy requirements and greenhouse gas emissions associated with thinning, residue bundling and stump removal for energy purposes. To date there have been no studies on harvesting of residues and stumps in …

Heat Transfer Characteristics In Wildland Fuelbeds, Justin English

Theses and Dissertations--Mechanical Engineering

The fundamental physics governing wildland fire spread are still largely misunderstood. This thesis was motivated by the need to better understand the role of radiative and convective heat transfer in the ignition and spread of wildland fires. The focus of this work incorporated the use of infrared thermographic imaging techniques to investigate fuel particle response from three different heating sources: convective dominated heating from an air torch, radiative dominated heating from a crib fire, and an advancing flame front in a laboratory wind tunnel test. The series of experiments demonstrated the uniqueness and valuable characteristics of infrared thermography to reveal …

Comparison Study Of Different Ionic Liquid Pretreatments In Maximizing Total Reducing Sugars Recovery, Kiat Moon Lee, Gek Cheng Ngoh Dr, Adeline Seak May Chua Dr, Li Wan Yoon, Teck Nam Ang Dr., Min Gyu Lee Prof

Teck Nam Ang Dr.

A process scheme combining the most suitable ionic liquid pretreatment, followed by solid acid and enzymatic saccharification was used to maximize the reducing sugars recovery from sago waste. Three types of ionic liquids, i.e. 1-butyl-3-methylimidazolium chloride ([BMIM]Cl), 1- ethyl-3-methylimidazolium acetate ([EMIM][OAc]) and 1-ethyl-3-methylimidazolium diethyl phosphate ([EMIM][(EtO)2PO2]) were evaluated based on their performance in terms of the total reducing sugars recovery, chemical cost, and pretreatment energy requirement. The results showed that all the ionic liquids assisted the saccharification processes by dissolving and depolymerizing the carbohydrates of the sago waste into shorter chain soluble oligosaccharides, as well as disrupting the biomass structure …