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Full-Text Articles in Life Sciences
Oxygen Exchange During The Reaction Of Pocl3 And Water, Robert Clark, Robert Morrison, Andrew Thomas, Rebeca Alvarez, Paul Milham
Oxygen Exchange During The Reaction Of Pocl3 And Water, Robert Clark, Robert Morrison, Andrew Thomas, Rebeca Alvarez, Paul Milham
Robert Clark
To investigate O exchange during the reaction of POCl3 and water, natural abundance POCl3 was reacted with water highly enriched in 18O, and the resulting H3PO4 was isolated as KH2PO4. This reaction was conducted with and without tetrahydrofuran (THF) as a solvent, and was controlled in THF and violent in its absence. Approximately 5 x 10-4M aqueous solutions of the KH2PO4 were analyzed using electrospray ionization mass spectrometry, to estimate the proportions of the mass-clumped 16,17,18O isotope analogues of [H2PO4] -. During analysis, ~29% of [H2PO4] - dehydrated to [PO3]-, for which the proportions of the O isotope analogues were …
Soil Chemistry: Understanding Phosphorus In The Environment, Paul Milham, Warwick Dougherty, Robert Morrison, Robert Clark, Ronald Smernik, Ashlea Doolette, Lucy Burkitt, Damian Collins, Rebeca Alvarez, Andrew Thomas
Soil Chemistry: Understanding Phosphorus In The Environment, Paul Milham, Warwick Dougherty, Robert Morrison, Robert Clark, Ronald Smernik, Ashlea Doolette, Lucy Burkitt, Damian Collins, Rebeca Alvarez, Andrew Thomas
Robert Clark
It is an essential ingredient in food production, but poor management means bad news downstream. Understanding the way phosphorus behaves in the environment calls for soil and plant biology, and some new soil chemistry.