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Life Sciences Commons

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Chemical Engineering

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SelectedWorks

2008

Articles 1 - 3 of 3

Full-Text Articles in Life Sciences

Synthesis And Characterization Of Poly(Allyl Methacrylate) Obtained By Free Radical Initiator., Selda Keskin Jan 2008

Synthesis And Characterization Of Poly(Allyl Methacrylate) Obtained By Free Radical Initiator., Selda Keskin


Allyl methacrylate was polymerized in CCl4 solution by a,a0-azoisobutyronitrile at 50, 60, and 708C. The kinetic curves were autoaccelarated types at 60 and 708C, but almost linear at 508C. Arrhenius activation energy was 77.5 kJ/mol. The polymer was insoluble in common organic solvents. It was characterized by FT-IR, NMR, DSC, TGA and XPS methods. About 98–99% of allyl side groups were remained as pendant even after completion of the polymerization. The spectroscopic and thermal results showed that polymerization is not a cyclopolymerization type, but may have end group cyclization. The high molecular weight is the main cause of a polymer …


The Evaluation Of Some Flexural Properties Of Denture Base Resin Reinforced With Various Aesthetic Fibers, Selda Keskin Jan 2008

The Evaluation Of Some Flexural Properties Of Denture Base Resin Reinforced With Various Aesthetic Fibers, Selda Keskin


No abstract provided.


Stoichiometric Network Analysis And Associated Dimensionless Kinetic Equations. Application To A Model Of The Bray-Liebhafsky Reaction, Zeljko D. Cupic Jan 2008

Stoichiometric Network Analysis And Associated Dimensionless Kinetic Equations. Application To A Model Of The Bray-Liebhafsky Reaction, Zeljko D. Cupic

Zeljko D Cupic

No abstract provided.