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Materials Science and Engineering

Doctoral Dissertations

Crystal growth

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Full-Text Articles in Nuclear Engineering

Development Of Novel Cesium Chloride-Based Ultrafast Inorganic Scintillators For Fast Timing Radiation Detection Applications, Daniel Rutstrom May 2024

Development Of Novel Cesium Chloride-Based Ultrafast Inorganic Scintillators For Fast Timing Radiation Detection Applications, Daniel Rutstrom

Doctoral Dissertations

Cs2ZnCl4 [dicesium zinc tetrachloride] and Cs3ZnCl5 [tricesium zinc pentachloride] are relatively new scintillator materials that appear to be promising for use in fast-timing radiation detection applications owing to their 1 to 2 nanosecond decay times. Moreover, they offer several advantages over the state-of-the-art ultrafast inorganic scintillator BaF2 [barium fluoride]. To fully realize the potential of these novel materials, growth of crystals having improved optical quality must be demonstrated. The mechanism responsible for the ultrafast decay times, core valence luminescence (CVL), in cesium zinc chloride crystals can also be observed in other compounds containing …


Discovery And Development Of Rare Earth Activated Binary Metal Halide Scintillators For Next Generation Radiation Detectors, Kan Yang Aug 2011

Discovery And Development Of Rare Earth Activated Binary Metal Halide Scintillators For Next Generation Radiation Detectors, Kan Yang

Doctoral Dissertations

This work focuses on discovery and development of novel binary halide scintillation materials for radiation detection applications. A complete laboratory for raw materials handling, ampoule preparation, material rapid synthesis screening, single crystal growth, sample cutting, polishing and packaging of hygroscopic halide scintillation materials has been established. Ce3+ and Eu2+ activated scintillators in three binary systems: Alkali Halide – Rare Earth Halide (AX–REX3), Alkali Halide – Alkaline Earth Halide (AX–AEX2) and Alkalin Earth Halide – Rare Earth Halide (AEX2–REX3) were systematically studied. Candidates for new scintillation materials in the three systems …