Nuclear Engineering Commons^™

Microstructure-Informed Modeling Of Hydrogen Diffusion In Zirconium Polycrystals, Alireza Tondro

Electronic Thesis and Dissertation Repository

Zirconium alloys are widely used in the core of various types of nuclear reactors. During service, the hot water coolant reacts with zirconium and releases hydrogen atoms that ingress into the lattice of the metal alloy. With time, hydrogen concentration exceeds its terminal solid solubility limit in zirconium, and a brittle phase known as zirconium hydride forms. This phase severely deteriorates the mechanical properties of zirconium alloys, leading to safety concerns regarding the integrity of nuclear pressure tubes. This thesis uses a crystal plasticity finite element model coupled with diffusion equations to study the effects of localized deformation at the …