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Characterizing The Structure And Radiation Resistance Of Weberite-Type Complex Oxides, Igor M. Gussev

Doctoral Dissertations

Weberite-type A₃BO₇ oxides, where A is a trivalent rare earth and B is a pentavalent element like Ta, have been a focus of research due to the discovery of the weberite-type local atomic arrangement in ceramics with a defect-fluorite structure. Earlier studies primarily examined their long-range structures, leaving gaps in understanding their short-range atomic behavior. This thesis investigates various weberite-type tantalates across all structural scales. There has been debate over the long-range structure of Y₃TaO₇, a medium-sized rare earth tantalate oxide, particularly regarding its spacegroup symmetry. This work identifies Y₃TaO_{7 …}