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Development Of Nanostructured Limpo4 (M=Fe, Mn) As Cathodes For High Performance Lithium-Ion Batteries, Jinli Yang

Electronic Thesis and Dissertation Repository

Olivine LiFePO₄ has garnered the most interest because of its environmental benignity, high safety and theoretical capacity. However, the major limitation for LiFePO₄ is the intrinsically poor electronic conductivity and ionic conductivity. The sluggish kinetics for LiFePO₄ could be overcome by reducing the size, coating with conductive carbon, or doping with isovalent ions. The decrease of the size to nanoscale could shorten the diffusion time of Li ions in LiFePO₄ during intercalation/deintercalation process, but the nano-size active material usually accompanies with low tap density. Carbon coating and carbon addition could alleviate the poor electronic conductivity. However, …