Nanoscience and Nanotechnology Commons^™

Solvent Dependent Morphologies In Thiol-Ene Photopolymerization: A Facile Route To Synthesis Of Resorcinarene Nanocapsules, Zaharoula Marie Kalaitzis

Chemistry & Biochemistry Theses & Dissertations

Synthesis of morphologically distinct polymeric nanostructures is vital for their wide ranging applications from nanomedicine to material science. Among various polymeric nanostructures, nanocapsules in particular have attracted a lot of attention as nanoreactors and drug delivery vehicles in nanomedicine. Often, synthesis of nanocapsules is achieved by template-based approaches. A direct, template-free method for the fabrication of nanocapsules and a variety of other morphologically distinct polymeric architectures was developed. The photopolymerization of a resorcinarene thiol-ene surfactant in various solvents lead to the formation of nanocapsules, nanoparticles, fibers, distorted honeycomb-like lattices, and sheets. The progress of the polymerization reaction and the morphology …

Substituent Effect On The Electronic And Assembling Properties Of Asymmetric Phenazine Derivatives, Bin Cao

UNLV Theses, Dissertations, Professional Papers, and Capstones

Currently, one-dimensional (1-D) nanostructures have drawn much interest because of their potential applications for nanoscale optoelectronic devices. Self-assembly (SA) based on π-conjugated systems through various intermolecular interactions has been widely used to produce 1-D nanostructure. Morphology of the assembled structures can be modified by incorporating substituents, which provide additional secondary interactions. Meanwhile, those substituents also influence the electronic properties of the molecules. Previous studies have made little effort to systematically study subsistent effects on both electronic and SA properties.

The primary objective of this research is to generate controllable 1-D structures through SA, and to provide a fundamental understanding of …

Electron Microscopy And Optical Characterization Of Cadmium Sulphide Nanocrystals Deposited On The Patterned Surface Of Diatom Biosilica, Timothy Gutu, Debra K. Gale, Clayton Jeffryes, Wei Wang, Chih-Hung Chang, Gregory L. Rorrer, Jun Jiao

Physics Faculty Publications and Presentations

Intricately patterned biosilica obtained from the shell of unicellular algae called diatoms serve as novel templates for fabrication of optoelectronic nanostructures. In this study, the surface of diatom frustules that possessed hierarchical architecture ordered at the micro and nanoscale was coated with a nanostructured polycrystalline cadmium sulphide (CdS) thin film using a chemical bath deposition technique. The CdS thin film was composed of spherical nanoparticles with a diameter of about 75 nm. The CdS nanoparticle thin film imparted new photoluminescent properties to the intricately patterned diatom nanostructure. The imparted photoluminescent properties were dependent on the CdS coverage onto the frustules …