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Experimental And Numerical Investigation Of An Electrospray Rf Ion Funnel, Eric Miguel Tridas Jan 2012

Experimental And Numerical Investigation Of An Electrospray Rf Ion Funnel, Eric Miguel Tridas

USF Tampa Graduate Theses and Dissertations

Using experimental techniques along with computational fluid dynamics and electrodynamic simulations the performance of the first of three focusing elements in an electrospray macromolecular patterning system was assessed. The performance of this element, the ion funnel, was analyzed by varying the parameters and electric field applied to the system including electrospray emitter to atmosphere-vacuum interface capillary distance, temperature of the desolvating heater, injection rate of solution and the voltage applied to the jet disruption element. Results indicated that processes involved in injecting larger droplets into the chamber resulted in a less effective transmission of the ions through the funnel. Droplet …