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Articles 1 - 5 of 5
Full-Text Articles in Nanoscience and Nanotechnology
Preparation And Electrochemical Lithium Intercalation Performance Of Different Shaped Carbon Nanotube, Mao-Hui Chen, Zhen-Cai Huang, Guo-Tao Wu, Jin-Kua You, Zu-Geng Lin
Preparation And Electrochemical Lithium Intercalation Performance Of Different Shaped Carbon Nanotube, Mao-Hui Chen, Zhen-Cai Huang, Guo-Tao Wu, Jin-Kua You, Zu-Geng Lin
Journal of Electrochemistry
In the present work, different shaped carbon nanotubes were produced by the general CVD and the template method at different temperature (600 ℃,700 ℃) with the reaction gas of acetylene. The morphology, structure and the electrochemical lithium intercalation performance were comparatively studied and characterized by TEM, HRTEM, SEM, XRD, Raman techniques and Charge/Discharge Test. It was found that the different preparation methods and temperatures all had an obvious effect on these properties of carbon nanotubes. In our samples, with the increase of preparation temperature, the degree of crystallinity decreased, and the reversible specific capacity increased respectively.
Nano-Sized Cobalt-Based Oxides As Negative Electrode For Lithium-Ion Batteries, Feng Huang, Zheng-Yong Yuan, Yun-Hong Zhou, Ju-Tang Sun
Nano-Sized Cobalt-Based Oxides As Negative Electrode For Lithium-Ion Batteries, Feng Huang, Zheng-Yong Yuan, Yun-Hong Zhou, Ju-Tang Sun
Journal of Electrochemistry
Nanosized cobalt-based oxide (Co 3O 4, CoB 1.36 O 2.8 and CoB 0.5 Al 0.1 O 1.5 ) samples were prepared by rheological phase method and were tested as anodes in secondary lithium batteries. The cells were cycled between 0.01V and 3.00 V. The best electrochemical performance was obtained from the Li/Co 3O 4 cell, which retained 95% of its initial capacity (931 mAh/g) after 30 cycles. The doping of B, Al reduced the reversible capacity during the first discharge/charge cycle, and the quantity of reversible capacity reduced with B, A1 increasing. The modifying structures at difference charge and discharge …
Pure Hap Film Prepared By Direct Electrodepositing On Metallic Surface And Its Mechanism, Hao-Bing Hu, Chang-Jian Lin, Fei Chen, Ren Hu, Ming Guo
Pure Hap Film Prepared By Direct Electrodepositing On Metallic Surface And Its Mechanism, Hao-Bing Hu, Chang-Jian Lin, Fei Chen, Ren Hu, Ming Guo
Journal of Electrochemistry
In controlling concentration of Ca 2+ and PO 4 3- in electrodeposition solution, the HAP film on Ti alloy has been deposited directly. Using XRD and SEM we have learned that prepared HAP is intact in crystal and equal in dimension. Thermodynamic calculation indicated that the HAP is easer formation of than that TCP of. With the XRD, SEM analyses and thermodynamic calculation, the electrodeposition mechanism has been discussed. It was proved that electrodepositon is a two_stage process and formation of HAP is a direct process from solution ions to HAP crystal without precursor.
Syntheses And Photoluminescence Of Zinc Oxide Polyaniline Coaxial Nanowires And Their Array, Zhi-Xin Zheng, Yan-Yan Xi, Ping Dong, Huai-Guo Huang, Jian-Zhang Zhou, Lin-Lin Wu, Zhong-Hua Lin
Syntheses And Photoluminescence Of Zinc Oxide Polyaniline Coaxial Nanowires And Their Array, Zhi-Xin Zheng, Yan-Yan Xi, Ping Dong, Huai-Guo Huang, Jian-Zhang Zhou, Lin-Lin Wu, Zhong-Hua Lin
Journal of Electrochemistry
A novel nanomaterial,zinc oxide (ZnO) and polyaniline (PANI) coaxial nanowires and their array in the template,was synthesized using anodic aluminum oxide (AAO) membrane as template.The morphology of these coaxial nanowires was observed with transmission electron microscope (TEM).The experiments on photoluminescence (PL) of coaxial nanowires and their array in AAO membrane show that the visible emission band of ZnO shifts from 530 nm to 400 nm and the luminescence is enhanced for the coaxial nanowires array in AAO membrane,and the visible emission band shifts to a lower wavelergth(385 nm) for coatial nanowires in NaOH solution. Possible explanations for these two blue …
Photocurrent Enhancement By Ticl_4 Post_Treatment For Tio_2 Nanoporous Film Electrode, Yan-Jie Ren, Li Zhang, Sheng-Min Cai
Photocurrent Enhancement By Ticl_4 Post_Treatment For Tio_2 Nanoporous Film Electrode, Yan-Jie Ren, Li Zhang, Sheng-Min Cai
Journal of Electrochemistry
Enhanced photocurrent in dye_sensitized photoelectrochemical cell was obtained by post_treating the TiO 2 nanoporous film electrode with TiCl 4. By investigating the effect of the post_treatment on surface area, pore size distribution, laser pulse induced current transient of the film electrode, photocurrent increase by the post_treatment was assigned to the improved electron percolation resulting from broadening of interparticle neck.