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Full-Text Articles in Nanoscience and Nanotechnology
A Study Of Titania Nanotube Synthesis In Chloride-Ion-Containing Media, E. Panaitescu, C. Richter, L. Menon
A Study Of Titania Nanotube Synthesis In Chloride-Ion-Containing Media, E. Panaitescu, C. Richter, L. Menon
Eugen Panaitescu
We have completed a detailed experimental investigation into the recently discovered synthesis of titania nanotubes in chloride-ion-containing media. We show that the role of the chloride ions is catalytic and it has a strong effect in increasing the reactivity of the solution, while the nature of cations has no visible role. We have identified the critical parameters for optimal growth and fast production of nanotubes, and a basic growth mechanism for the tubes is proposed. This opens routes for significant improvements of the method toward uniformity and/or better overall yield, making it a viable alternative to the present established methods.
Cause And Prevention Of Moisture-Induced Degradation Of Resistance Random Access Memory Nanodevices, Albert Chen
Cause And Prevention Of Moisture-Induced Degradation Of Resistance Random Access Memory Nanodevices, Albert Chen
Albert B Chen
Dielectric thin films in nanodevices may absorb moisture, leading to physical changes and property/performance degradation, such as altered data storage and readout in resistance random access memory. Here we demonstrate using a nanometallic memory that such degradation proceeds via nanoporosity, which facilitates water wetting in otherwise nonwetting dielectrics. Electric degradation only occurs when the device is in the charge-storage state, which provides a nanoscale dielectrophoretic force directing H2O to internal field centers (sites of trapped charge) to enable bond rupture and charged hydroxyl formation. While these processes are dramatically enhanced by an external DC or AC field and electron-donating electrodes, …