Open Access. Powered by Scholars. Published by Universities.®
Nanoscience and Nanotechnology Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Nanoscience and Nanotechnology
A Study Of Anodization Process During Pore Formation In Nanoporous Alumina Templates, Z. Wu, C. Richter, L. Menon
A Study Of Anodization Process During Pore Formation In Nanoporous Alumina Templates, Z. Wu, C. Richter, L. Menon
Latika Menon
We have carried out a systematic investigation of the anodization procedure in order to determine the exact chemical mechanism of the dissolution process responsible for pore formation in nanoporous alumina templates. We measured the anodization current as a function of time and compared it with the thickness of porous aluminum oxide layer obtained from cross-section scanning electron microscopy images. From this, we calculated the number of moles of electrons generated per mole of porous alumina grown. This analysis is consistent with a reaction mechanism in which aluminum is converted to aluminum oxide in addition with the direct transfer of aluminum …
A Study Of Titania Nanotube Synthesis In Chloride-Ion-Containing Media, E. Panaitescu, C. Richter, L. Menon
A Study Of Titania Nanotube Synthesis In Chloride-Ion-Containing Media, E. Panaitescu, C. Richter, L. Menon
Latika Menon
We have completed a detailed experimental investigation into the recently discovered synthesis of titania nanotubes in chloride-ion-containing media. We show that the role of the chloride ions is catalytic and it has a strong effect in increasing the reactivity of the solution, while the nature of cations has no visible role. We have identified the critical parameters for optimal growth and fast production of nanotubes, and a basic growth mechanism for the tubes is proposed. This opens routes for significant improvements of the method toward uniformity and/or better overall yield, making it a viable alternative to the present established methods.