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Full-Text Articles in Nanoscience and Nanotechnology

Possible Room-Temperature Ferromagnetism In Hydrogenated Carbon Nanotubes, Adam L. Friedman, Hyunkyung Chun, Yung Joon Jung, Don Heiman, Evan R. Glaser, Latika Menon Oct 2012

Possible Room-Temperature Ferromagnetism In Hydrogenated Carbon Nanotubes, Adam L. Friedman, Hyunkyung Chun, Yung Joon Jung, Don Heiman, Evan R. Glaser, Latika Menon

Donald Heiman

We find that ferromagnetism can be induced in carbon nanotubes (CNTs) by introducing hydrogen. Multiwalled CNTs grown inside porous alumina templates contain a large density of defects resulting in significant hydrogen uptake when annealed at high temperatures. This hydrogen incorporation produces H-complex and adatom magnetism which generates a sizable ferromagnetic moment and a Curie temperature near TC=1000  K. We studied the conditions for the incorporation of hydrogen, the temperature-dependent magnetic behavior, and the dependence of the ferromagnetism on the size of the nanotubes.


Negative Index Metamaterials Based On Metal-Dielectric Nanocomposites For Imaging Applications, L. Menon, W. T. Lu, A. L. Friedman, S. P. Bennett, D. Heiman, S. Sridhar Oct 2012

Negative Index Metamaterials Based On Metal-Dielectric Nanocomposites For Imaging Applications, L. Menon, W. T. Lu, A. L. Friedman, S. P. Bennett, D. Heiman, S. Sridhar

Donald Heiman

Negative index metamaterials are demonstrated based on metal-dielectric nanocomposites prepared using a versatile bottom-up nanofabrication approach. The method involves the incorporation of vertically aligned metal nanowires such as Au and Ag inside dielectric aluminum oxide nanotemplates. Optical absorbance measurements show resonance peaks corresponding to the transverse and longitudinal surface plasmon modes. A quantitative model based on effective medium theory is in excellent agreement with experimental data, and points to specific composite configurations and wavelength regimes where such structures can have applications as negative refraction media for imaging.


Large Coercivity In Nanostructured Rare-Earth-Free Mnₓga Films, Don Heiman, Tom Nummy, Steve Bennett, Tom Cardinal Oct 2012

Large Coercivity In Nanostructured Rare-Earth-Free Mnₓga Films, Don Heiman, Tom Nummy, Steve Bennett, Tom Cardinal

Donald Heiman

The magnetic hysteresis of MnₓGa films exhibit remarkably large coercive fields as high as μₒHC=2.5 T when fabricated with nanoscale particles of a suitable size and orientation. This coercivity is an order of magnitude larger than in well-ordered epitaxial film counterparts and bulk materials. The enhanced coercivity is attributed to the combination of large magnetocrystalline anisotropy and ~50-100 nm size nanoparticles. The large coercivity is also replicated in the electrical properties through the anomalous Hall effect. The magnitude of the coercivity approaches that found in rare-earth magnets, making them attractive for rare-earth-free magnet applications.


Magnetic Properties Of Gamnas Nanodot Arrays Fabricated Using Porous Alumina Templates, S. Bennett, L. Menon, D. Heiman Oct 2012

Magnetic Properties Of Gamnas Nanodot Arrays Fabricated Using Porous Alumina Templates, S. Bennett, L. Menon, D. Heiman

Donald Heiman

Ordered arrays of GaMnAs magnetic semiconductor nanodots have been fabricated using anodic porous alumina templates as etch masks. The magnetic behavior is studied for prepared arrays with 40 nm dot diameter, 15 nm dot thickness, and 80 nm periodicity. The disklike nanodots exhibit an easy axis for fields applied in the radial direction and a hard axis in the smaller direction. In the radial direction superparamagnetism is observed with a blocking temperature of 30 K. The fabrication technique is convenient for preparing nanodot arrays of compound semiconductors that cannot be formed by self-assembly techniques.