Nanoscience and Nanotechnology Commons^™

Electrochemical Surface-Enhanced Raman Spectroscopic Studies On Nickel Ultramicroelectrode, Li-Wen Wu, Wei Wang, Yi-Fan Huang

Journal of Electrochemistry

Nickel (Ni) electrodes are widely used in electrochemical researches. Understanding electrochemical processes on Ni electrodes through in-situ characterization of adsorbed species on their surfaces is helpful for rational optimization and application of Ni electrochemistry. Microelectrochemical surface-enhanced Raman spectroscopy (μEC-SERS) combines the mass transfer feature of ultramicroelectrode with high-sensitivity characterizations of molecular structures, which is a powerful method for studying Ni electrochemistry on polarization and non-equilibrium conditions. The key point of performing μEC-SERS is to make a SERS-active Ni ultramicroelectrode.
Here, we demonstrate a method of preparing a SERS-active Ni ultramicroelectrode through electrochemical deposition of several atomic layers of …

Study Of Nickel Silicide Formation By Physical Vapor Deposition Techniques, Shanti Pancharatnam

Legacy Theses & Dissertations (2009 - 2024)

Metal silicides are used as contacts to the highly n-doped emitter in photovoltaic devices. Thin films of nickel silicide (NiSi) are of particular interest for Si-based solar cells, as they form at lower temperature and consume less silicon. However, interfacial oxide limits the reduction in sheet resistance. Hence, different diffusion barriers were investigated with regard to optimizing the conductivity and thermal stability.

Patterning And Characterization Of Carbon Nanotubes Grown In A Microwave Plasma Enhanced Chemical Vapor Deposition Chamber, Mauricio Kossler

Theses and Dissertations

This research studies the growth of carbon nanotubes (CNT) from a nickel catalyst to be used on a field emission device. This thesis can be divided into three sections: the construction of a vacuum chamber for field emission testing, the design and fabrication of a triode structure to enable improved electron emission, and the pretreatment and growth of CNTs. To experimentally test the field emission of CNTs, a vacuum chamber must attain a vacuum of at least 10^-5 torr. Our vacuum chamber designed and built achieved a maximum, final pressure of 10^-8 torr. A triode structure was designed …

Electrodeposition Of Nickel Nanowires And Nanotubes Using Various Templates, Asli Ertan, Surendra N. Tewari, Orhan Talu

Chemical & Biomedical Engineering Faculty Publications

Nickel nanotubes and nanowires are grown by galvanostatic electrodeposition in the pores of 1000, 100, and 15 nm polycarbonate as well as in anodised alumina membranes at a current density of 10 mA cm-2. The effects of pore size, porosity, electrodeposition time, effective current density, and pore aspect ratio are investigated. Nickel nanotube structures are obtained with 1000 nm pore size polycarbonate membrane without any prior treatment method. At the early stages of electrodeposition hollow nickel nanotubes are produced and nanotubes turn into nanowires at longer depositon times. As effective current density accounting for the membrane porosity decreases, the axial …

Development Of Nanostructure Based Corrosion-Barrier Coatings On Steel For Transmutation Applications, Biswajit Das

Transmutation Sciences Materials (TRP)

Advanced transmutation systems require structural materials that are able to withstand high neutron fluxes, high thermal cycling, and high resistance to chemical corrosion. The current candidate materials for such structures are ferritic and ferritic-martensitic steels due to their strong resistance to swelling, good microstructural stability under irradiation, and the retention of adequate ductility at typical reactor operating temperatures.

In parallel, lead-bismuth eutectic (LBE) has emerged as a potential spallation target material for efficient production of neutrons, as well as a coolant in the accelerator system. While LBE has excellent properties as a nuclear coolant, it is also highly corrosive to …

Corrosion Barrier Development For Lbe Corrosion Resistance: Quarterly Report (April 2006), Biswajit Das

Transmutation Sciences Materials (TRP)

As reported in the last quarterly report, synthesis of Cr nanowires was found to be problematic in terms of uniform coverage. Hence Ni was identified as the alternative metal to form the nanowires. The purpose of the metal nanowires is to provide structural integrity to the nanoporous alumina, as well as a second defense mechanism against corrosion by oxidizing in case the top alumina layer is compromised. Nickel was selected due to its established electrochemical synthesis procedure. While Ni can provide very good structural integrity to the porous alumina, one potential problem is its higher dissolution rate in LBE. However, …

Study Of Electrochemical Properties Of Ni(Oh)_2 /Niooh With Spectroscopic Ellipsometry, Shengtao Zhang, Zongqing Huang

Journal of Electrochemistry

Electrochemical reactions of Ni(OH)_2 /NiOOH system were studied by using in-situ spectroscopic ellipsometry and the conventional electrochemical metheds.By fitting data fromellipsometric measurements,a transformation medel of the surface film was obtained for cathedic andanodic processes. The results indicated that the transformation medel after cobalt implantation almostremained the same as that before cobalt implantation,but the electrochemical properties wereaffectedobviously by implantation of cobalt.