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Nanoscience and Nanotechnology Commons

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Theses/Dissertations

2017

William & Mary

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Vertically Oriented Graphene Electric Double Layer Capacitors, Dilshan V. Premathilake Jun 2017

Vertically Oriented Graphene Electric Double Layer Capacitors, Dilshan V. Premathilake

Dissertations, Theses, and Masters Projects

Vertically oriented graphene nanosheets (VOGN) synthesized by radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) have been fabricated as electrical double layer capacitors (EDLCs). The relatively open morphology of the films provided good frequency response, but had limited capacitance compared to present day activated carbon EDLCs. The objective of this research was to improve the capacitance of these films to a commercially viable level while maintaining sufficient frequency response for AC filtering. The growth of VOGN on Ni and Al substrates has been studied in this work. The native oxide on Ni was thinned at temperatures above ~600ºC with the …