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Full-Text Articles in Nanoscience and Nanotechnology
An Examination Of The Indentation Size Effect In Fcc Metals And Alloys From A Kinetics Based Perspective Using Nanoindentation, David Earl Stegall
An Examination Of The Indentation Size Effect In Fcc Metals And Alloys From A Kinetics Based Perspective Using Nanoindentation, David Earl Stegall
Mechanical & Aerospace Engineering Theses & Dissertations
The indentation size effect (ISE) in metals is described as the rise in hardness with decreasing depth of indentation and contradicts conventional plasticity behavior. The goal of this dissertation is to further examine the fundamental dislocation mechanisms that may be contributing to the so-called indentation size effect. In this work, we examined several metals and alloys including 99.999% Aluminum (SFE ~200 mJ/m2), 99.95% Nickel (SFE ~125 mJ/m2), 99.95% Silver (SFE ~22 mJ/m2), and three alloys, alpha brass 70/30 (SFE >10 mJ/m2), 70/30 nickel copper (SFE ~100 mJ/ …
Synthesis, Morphological Control, Dispersion Stabilization And In Situ Self-Assembly Of Noble Metal Nanostructures Using Multidentate Resorcinarene Surfactants, Sangbum Han
Chemistry & Biochemistry Theses & Dissertations
In this dissertation, a detailed investigation on the influence of various macrocyclic resorcinarene surfactants in determining the morphology, stabilization and self-assembly of mono- and bi- metallic nanoparticles was undertaken. Chapter 2 describes the influence of resorcinarene surfactants functionalized with amine- and thiol- headgroups in determining the morphology of monometallic Pt nanoparticles synthesized via the Brust-Schiffrin reaction. We found that while resorcinarene benzylthiol can lead to the formation of highly branched Pt nanostructures, resorcinarene amine can lead to the formation of anisotropic crystalline Pt nanoparticles. Further, we have evaluated the influence of resorcinarene ligands in determining the catalytic activity of these …