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Full-Text Articles in Nanoscience and Nanotechnology

Cementitious Sensors Exhibiting Stopbands In Acoustic Transmission Spectra, Shreya Vemuganti Nov 2018

Cementitious Sensors Exhibiting Stopbands In Acoustic Transmission Spectra, Shreya Vemuganti

Shared Knowledge Conference

Ultrasonic monitoring in cementitious materials is challenging due to the high degree of attenuation. In wellbore environments, monitoring becomes more challenging due to inaccessibility. Meta materials, also known as acoustic bandgap materials, exhibit an interesting feature of forbidding the propagation of elastic/sound waves and isolate vibration in a certain frequency band. Traditionally, acoustic bandgap materials are developed with inclusions such as tin, aluminum, gold, steel in a polymer matrix. In this study, we present the development of three-dimensional cementitious sensors capable of exhibiting stopbands in the acoustic transmission spectra using carbon nanotubes. Relatively wide stopbands were engineered using Floquet-Bloch periodic …


Two-Dimensional Layered Materials (Graphene-Mos2) Nanocatalysts For Hydrogen Production, Jacob Dobler, Taylor Robinson, Sanju Gupta 7455940 Nov 2018

Two-Dimensional Layered Materials (Graphene-Mos2) Nanocatalysts For Hydrogen Production, Jacob Dobler, Taylor Robinson, Sanju Gupta 7455940

Posters-at-the-Capitol

Recent development of two-dimensional layered materials including graphene-family and related nanomaterials have arisen as potential game changer for energy, water and sensing applications. While graphene is a form of carbon arranged hexagonally within atomic thin sheet, MoS2 is becoming a popular, efficient, and cost-effective catalyst for electrochemical energy devices, in contrast to expensive platinum and palladium catalysts. In this work, we electrochemically desulfurize few-layer molybdenum disulfide (MoS2) and aerogels with reduced graphene oxide (rGO) prepared under hydrothermal conditions ((P< 20 bar, T< 200 oC), for improving hydrogen evolution reaction (HER) activity via point defects (S-vacancy). Moreover, the interactions between rGO …


Physical Properties Of Engineered Nanocomposites For Defense Applications, Alex Henson, Sanju Gupta Nov 2018

Physical Properties Of Engineered Nanocomposites For Defense Applications, Alex Henson, Sanju Gupta

Posters-at-the-Capitol

Polymer nanocomposites are significant for modern and future technologies (aerospace, defense, water purification etc.) due to their tailored properties, lightweight and low cost. However, ‘forward’ engineered polymer (host matrix) composites with smaller size nanoparticles (guest) providing desired properties targeting specific applications remains a challenging task as they depend largely on nanoparticles size, shape and loading (volume fraction). This study develops polymer nanocomposites impregnated with ‘organic-inorganic’ silsesquioxane nanoparticles and graphene nanoribbons, and investigates microscopic structure and dynamics of interfacial layer to predict macroscale properties. The nanocomposites consist of poly(2-vinylpyridine) (P2VP) polymer (segment ~5nm) with spherical silsesquioxane nanoparticles (diameter ~2-5nm) and planar …