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Mathematical Expression And Quantitative Analysis Of Impedance Spectrum On The Interface Of Glassy Carbon Electrode, Lei Cheng, Pu-Xuan Yan, You-Jun Fan, Hua-Hong Zou, Hong Liang

Journal of Electrochemistry

Glassy carbon electrode (GCE) is a common basic electrode for various electrochemical sensors, and the detection properties are determined by its interfacial characteristics. In this paper, we established an equivalent circuit including electrolyte resistance (R_el), charge transport resistance (R_ct), diffusion impedance (R_di, C_di), electrochemical (oxidation/reduction) reaction impedance (R_R, C_R), surface adsorption impedance (R_ads , C_ads), double-layer capacitance (C_DL), and derived the mathematical expression for the equivalent circuit. The R_el and C_DL are contributed by inactive …