Open Access. Powered by Scholars. Published by Universities.®
Nanoscience and Nanotechnology Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Nanoscience and Nanotechnology
Synthesis Of Vo2/Poly(Mma-Co-Dmemuabr) Antimicrobial/Thermochromic Dual-Functional Coating And Reactivity Ratios Study, Yixian Liu
Electronic Thesis and Dissertation Repository
Antimicrobial/thermochromic dual-functional coatings were successfully synthesized via UV-curing. The quaternary ammonium compound (QAC) N,N-dimethyl-N-{2-[(2-methylprop-2-enoyl)oxy]ethyl}undecane-1-aminium bromide (dMEMUABr) was synthesized and copolymerized with methyl methacrylate (MMA) for antimicrobial properties. Vanadium oxide (VO2) nanoparticles were evenly dispersed within the coating, providing thermochromic properties. The dual-functional coating showed high luminous transmittance (Tlum(25°C) =36.1 %) and solar energy modulation ( Tsol=5.8 %). 90.3 % of bacteria reduction was observed against Escherichia coli within 24 h contact. To further understand the sequence distribution of the copolymer poly(MMA-co-dMEMUABr), the reactivity ratios of MMA and dMEMUABr monomer were studied and compared under thermal …
Novel Avenues Toward Controlling The Photophysical Properties Of Ultra-Small Silicon Quantum Dots, Mohammed Abdelhameed
Novel Avenues Toward Controlling The Photophysical Properties Of Ultra-Small Silicon Quantum Dots, Mohammed Abdelhameed
Electronic Thesis and Dissertation Repository
Quantum dots (QDs) have attracted an increasing attention in the last decade over many conventional organic dyes. This is due to their unique optical properties including broad absorption spectra, high photostability, and size-tunable photoluminescence (PL). However, some toxicity concerns associated with traditional quantum dots have hindered their wide applicability. Interestingly, silicon quantum dots (SQDs) have been shown to be more advantageous than most of QDs thanks to their excellent biocompatibility and biodegradability, low cytotoxicity, and versatile surface functionalization capability. Thus, SQDs are promising candidates for various biological and biomedical applications such as bioimaging, biosensing, and photodynamic therapy. Unfortunately, only a …