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Mechanical Engineering Undergraduate Honors Theses

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Full-Text Articles in Nanoscience and Nanotechnology

Nanoscratch Study Of Diamond-Like Carbon Coatings With A Polydopamine + Sio2 Adhesive Underlayer, Anna Fisher May 2021

Nanoscratch Study Of Diamond-Like Carbon Coatings With A Polydopamine + Sio2 Adhesive Underlayer, Anna Fisher

Mechanical Engineering Undergraduate Honors Theses

Diamond-like carbon (DLC) coatings have a wide array of desirable characteristics such as low friction, high hardness, and scratch resistance. Due to high residual stress and thermal mismatch, DLC films experience adhesion difficulties when bonded with metallic substrates, leading to cracking and delamination. In this study, the properties of a new coating with a polydopamine underlayer and silica nanoparticles bonded to a stainless-steel substrate (PDA+SiO2/DLC) were studied alongside three other samples, one with a polydopamine underlayer (PDA/DLC), one with a trimethylsilane (TMS) underlayer (TMS/DLC), and one with no underlayer (DLC only). Nanoscratch tests were performed with a 1 μm spheroconical …


Non-Covalent Functionalization Of Graphene Films For Uniform Nanoparticle Deposition Via Atoic Layer Deposition, Ty Seiwert May 2018

Non-Covalent Functionalization Of Graphene Films For Uniform Nanoparticle Deposition Via Atoic Layer Deposition, Ty Seiwert

Mechanical Engineering Undergraduate Honors Theses

Graphene functionalized with platinum (Pt) and palladium (Pd) has proven to be highly effective as a hydrogen sensor. Deposition methods such as Atomic layer deposition (ALD) can be further enhanced by pretreating the graphene with a non-covalent surfactant prior to nanoparticle deposition. In this study, graphene-based sensing devices will be fabricated by ALD deposition. The graphene will be non-covalently functionalized using sodium dodecyl sulfate (SDS) anionic surfactant prior to ALD deposition. The aim of this study is to test the deposition pattern achieved by varying the amount of time that graphene is treated with the SDS surfactant. Initially, ALD deposition …