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Full-Text Articles in Nanoscience and Nanotechnology

The Impact Of Controlled Solvent Exposure On The Morphology, Structure And Function Of Bulk Heterojunction Solar Cells, Raghavendra R. Hegde Dr Dec 2012

The Impact Of Controlled Solvent Exposure On The Morphology, Structure And Function Of Bulk Heterojunction Solar Cells, Raghavendra R. Hegde Dr

Raghavendra R Hegde Dr

Films of poly(3-hexyl thiophene) (P3HT):[6,6]-phenyl C61-butyric acid methyl ester (PCBM) were controllably exposed to CS2 vapor in a column with a linear solvent vapor pressure gradient. Changes in the morphology of the P3HT:PCBM thin film were monitored and correlated to the ability of this thin film to act as the active layer in an organic solar cell. The results show that the crystallinity and crystal size of the P3HT increase initially with solvent vapor pressure and annealing time, but longer exposure to solvent decreases P3HT crystallinity and photovoltaic efficiency. Neutron reflectivity indicates that the PCBM segregates to the Si substrate …


Temperature Dependence Anomalous Dielectric Relaxation In Co Doped Zno Nanoparticles, Sajid Ali Ansari Sep 2012

Temperature Dependence Anomalous Dielectric Relaxation In Co Doped Zno Nanoparticles, Sajid Ali Ansari

Sajid Ali Ansari

We have reported temperature and frequency dependence of dielectric behaviour of nanocrystalline Zn1-xCoxO (x = 0.0, 0.01, 0.05 and 0.1) samples prepared by gel-combustion method. The synthesized samples were examined by x-ray diffraction (XRD), scanning electron microscopy (SEM) and LCR-meter, respectively. The XRD analysis reveals that ZnO has a hexagonal (wurtzite) crystal structure. The morphology and size of the nanoparticles (∼10-25 nm) were observed by SEM for 5% Co doped ZnO sample. In dielectric properties, complex permittivity (ɛ* = ɛ’-jɛ”), loss tangent (tanδ) and ac conductivity (σac) in the frequency range 75 kHz - 5 MHz were analyzed with temperature …


Monitoring Exposure To Airborne Ultrafine Particles In Lisbon, Portugal, João F. Gomes Jan 2012

Monitoring Exposure To Airborne Ultrafine Particles In Lisbon, Portugal, João F. Gomes

João F Gomes

No abstract provided.


Comparison Of Deposited Surface Area Of Airborne Ultrafine Particles Generated From Two Welding Processes, João F. Gomes Jan 2012

Comparison Of Deposited Surface Area Of Airborne Ultrafine Particles Generated From Two Welding Processes, João F. Gomes

João F Gomes

No abstract provided.


Capturing Ultrasmall Emt Zeolite From Template-Free Systems, Eng-Poh Ng Dr. Jan 2012

Capturing Ultrasmall Emt Zeolite From Template-Free Systems, Eng-Poh Ng Dr.

Eng-Poh Ng

No abstract provided.


Phosphate Protected Fluoride Nano-Phosphors, Joanna Cybinska, Chantal Lorbeer, Anja V. Mudring Jan 2012

Phosphate Protected Fluoride Nano-Phosphors, Joanna Cybinska, Chantal Lorbeer, Anja V. Mudring

Anja V. Mudring

A fast and easy 2-in-1 step microwave reaction procedure to phosphate coated nanofluorides allows for the formation of phosphate protected fluoride nanoparticles from simple lanthanide precursors in ionic liquids. The phosphate shell efficiently prevents the fluoride particle from decomposition in an atmosphere (containing oxygen and water) at elevated temperatures.


Controlling Nanoparticles Formation In Molten Metallic Bilayers By Pulsed-Laser Interference Heating, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman Jan 2012

Controlling Nanoparticles Formation In Molten Metallic Bilayers By Pulsed-Laser Interference Heating, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman

Mikhail Khenner

The impacts of the two-beam interference heating on the number of core-shell and embedded nanoparticles and on nanostructure coarsening are studied numerically based on the non-linear dynamical model for dewetting of the pulsed-laser irradiated, thin (< 20 nm) metallic bilayers. The model incorporates thermocapillary forces and disjoining pressures, and assumes dewetting from the optically transparent substrate atop of the reflective support layer, which results in the complicated dependence of light reflectivity and absorption on the thicknesses of the layers. Stabilizing thermocapillary effect is due to the local thickness-dependent, steady- state temperature profile in the liquid, which is derived based on the mean substrate temperature estimated from the elaborate thermal model of transient heating and melting/freezing. Linear stability analysis of the model equations set for Ag/Co bilayer predicts the dewetting length scales in the qualitative agreement with experiment.


Ultrasound-Assisted Synthesis Of Mesoporous Β-Ni(Oh)2 And Nio Nano-Sheets Using Ionic Liquids, Tarek Alammar, Osama Shekhah, Jonas Wohlgemuth, Anja V. Mudring Jan 2012

Ultrasound-Assisted Synthesis Of Mesoporous Β-Ni(Oh)2 And Nio Nano-Sheets Using Ionic Liquids, Tarek Alammar, Osama Shekhah, Jonas Wohlgemuth, Anja V. Mudring

Anja V. Mudring

Via a facile ultrasound synthesis from nickel acetate and sodium hydroxide with ionic liquids as the solvent and template it is possible to obtain nano-β-Ni(OH)2 of various dimensionalities depending on the reaction conditions with the ionic liquid (IL) being the most important factor. Scanning electron microscopy (SEM) imaging showed β-Ni(OH)2 to form as nanosheets, nanorods and nanospheres depending on the IL. ILs with strong to moderate hydrogen bonding capability like [C3mimOH][Tf2N] (1-(3-hydroxypropyl)-3-methylimidazolium bis(trifluoromethanesulfonylamide)), [C4mim][Tf2N] (1-butyl-3-methylimidazolium bis(trifluoromethanesulfonylamide)) and [Edimim][Tf2N] (1-ethyl-2,3-diemethylimidazolium bis(trifluoromethanesulfonylamide)) lead to the formation of nanosheets whilst [Py4][Tf2N] (butyl-pyridinium bis(trifluoromethanesulfonylamide)) leads to nanoparticles and [N1888][Tf2N] (methyltrioctylammonium bis(trifluoromethanesulfonylamide)) to nanorods. Subsequent …


Determination Of Airborne Nanoparticles From Welding Operations, João F. Gomes Dec 2011

Determination Of Airborne Nanoparticles From Welding Operations, João F. Gomes

João F Gomes

The aim of this study is to assess the levels of airborne ultrafine particles emitted in welding processes (tungsten inert gas (TIG), metal active gas (MAG) of carbon steel and friction stir welding (FSW) of aluminium) in terms of deposited area in pulmonary alveolar tract using a Nanoparticle Surface Area Monitor (NSAM) analyzer. The obtained results showed the dependence from process parameters on emitted ultrafine particles and demonstrated the presence of ultrafine particles compared to background levels. Data indicated that the process that resulted in the lowest levels of alveolar deposited surface area (ADSA) was FSW, followed by TIG and …


Exposure To Airborne Ultrafine Particles From Cooking In Portuguese Homes, João F. Gomes Dec 2011

Exposure To Airborne Ultrafine Particles From Cooking In Portuguese Homes, João F. Gomes

João F Gomes

No abstract provided.


Assessment Of Exposure To Airborne Ultrafine Particles In The Urban Environment Of Lisbon, Portugal, João F. Gomes Dec 2011

Assessment Of Exposure To Airborne Ultrafine Particles In The Urban Environment Of Lisbon, Portugal, João F. Gomes

João F Gomes

The aim of this study was the assessment of exposure to ultrafine in the urban environment of Lisbon, Portugal, due to automobile traffic, and consisted of the determination of deposited alveolar surface area in an avenue leading to the town center during late spring. This study revealed differentiated patterns for weekdays and weekends, which could be related with the fluxes of automobile traffic. During a typical week, ultrafine particles alveolar deposited surface area varied between 35.0 and 89.2 mm2/cm3, which is comparable with levels reported for other towns such in Germany and the United States. These measurements were also complemented …