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Catalysis and Reaction Engineering

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Zeolite

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Full-Text Articles in Nanoscience and Nanotechnology

Nanosized Molecular Sieves Utilized As An Environmentally Friendly Alternative To Antioxidants For Lubricant Oils, Eng-Poh Ng Dr. Jan 2011

Nanosized Molecular Sieves Utilized As An Environmentally Friendly Alternative To Antioxidants For Lubricant Oils, Eng-Poh Ng Dr.

Eng-Poh Ng

Lubricants play a significant part in current environmental considerations since they are an integral and indispensable component of modern technology. The production, application and disposal of the lubricants have to follow increasingly strict requirements for protecting the environment and living organisms. In this respect, molecular sieve (LTL type zeolite) is investigated as a potential environmentally friendly alternative to traditional antioxidant additives for lubricant oils. Accelerated oxidation experiments using pure base oil and additivated base oil in the presence of the LTL molecular sieve are carried out in parallel, and the oxidation processes are monitored by FT-IR spectroscopy, spectrophotometry, chromatography, total …


Alpo-18 Seed Layers And Films By Secondary Growth, Lubomira Tosheva, Eng-Poh Ng, Svetlana Mintova, Manfred Holzl, Till H. Metzger, Aidan M. Doyle Jan 2008

Alpo-18 Seed Layers And Films By Secondary Growth, Lubomira Tosheva, Eng-Poh Ng, Svetlana Mintova, Manfred Holzl, Till H. Metzger, Aidan M. Doyle

Eng-Poh Ng

AlPO-18 layers were prepared on Si wafers via spin-coating or the Langmuir−Blodgett (LB) method using nanosized crystals. Multilayers were deposited by spin-coating, whereas the seeds assembled by the LB technique were monolayers. The seeded layers were not stable upon secondary growth under microwave radiation, and no films were formed on the supports. Dense AlPO-18 films could be obtained by secondary growth after stabilization of the seed layers by adding prehydrolyzed tetraethylorthosilicate (TEOS) to the colloidal AlPO-18 suspension prior to support seeding. The stabilized seed layers and the grown AlPO-18 films were stable. The structure and the morphology of the films …