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Full-Text Articles in Mechanical Engineering
Establishing Physical And Chemical Mechanisms Of Polymerization And Pyrolysis Of Phenolic Resins For Carbon-Carbon Composites, Ivan Gallegos, Josh Kemppainen, Jacob R. Gissinger, Malgorzata Kowalik, Adri Van Duin, Kristopher E. Wise, S. Gowtham, Gregory Odegard
Establishing Physical And Chemical Mechanisms Of Polymerization And Pyrolysis Of Phenolic Resins For Carbon-Carbon Composites, Ivan Gallegos, Josh Kemppainen, Jacob R. Gissinger, Malgorzata Kowalik, Adri Van Duin, Kristopher E. Wise, S. Gowtham, Gregory Odegard
Michigan Tech Publications, Part 2
The complex structural and chemical changes that occur during polymerization and pyrolysis critically affect material properties but are difficult to characterize in situ. This work presents a novel, experimentally validated methodology for modeling the complete polymerization and pyrolysis processes for phenolic resin using reactive molecular dynamics. The polymerization simulations produced polymerized structures with mass densities of 1.24 ± 0.01 g/cm3 and Young's moduli of 3.50 ± 0.64 GPa, which are in good agreement with experimental values. The structural properties of the subsequently pyrolyzed structures were also found to be in good agreement with experimental X-ray data for the phenolic-derived carbon …
Development Of Strength Theories For Random Fiber Composites, Victor Giurgiutiu
Development Of Strength Theories For Random Fiber Composites, Victor Giurgiutiu
Faculty Publications
A ressessment of existing theories for calculating the strength of random and quasi-random fiber composites is presented. Fundamental aspects regarding the physical model, macromechanics analysis, fiber distribution functions, generalized failure criterion, and progressive versus sudden failure models are covered first. Progressive ductile failure, progressive brittle failure, and sudden brittle failure are treated in detail. In each case, the original theory is briefly reviewed, and then its extensions accompanied by numerical examples are presented. Several limitations originally imposed by Hahn, such as the monotonically nonincreasing requirement on the failure strain curve, are lifted and the mathematical formulations are generalized. Some common …