Mechanical Engineering Commons^™

A Reversible And Stable Flake-Like Licoo2 Cathode For Lithium Ion Batteries, Tao Wei, Rui Zeng, Yongming Sun, Yunhui Huang, Kevin Huang

Faculty Publications

A dense and thick flake-like cathode structure was demonstrated to have a preferential crystallographic orientation for Li+ migration and a better tolerance to cracking, both of which enable a reversible and stable capacity at moderate rates from 0.1 to 2 C.

Flex-16: A Large-Displacement Monolithic Compliant Rotational Hinge, Robert Mcintyre Fowler, Alex Maselli, Peter Pluimers, Spencer P. Magleby, Larry L. Howell

Faculty Publications

This paper describes the design, analysis, and testing of a large-displacement monolithic compliant rotational hinge, called the Flex-16. The Flex-16 achieves 90 of rotation from monolithic construction and is aimed for application as a compliant satellite deployment hinge. Five prototypes were fabricated from three different materials (polypropylene, titanium, and a carbon nanotube framework) on two different size scales (macro and micro). A parametric finite element model was created to rapidly analyze a variety of design identified during a configuration study. Prototypes were tested for their ability to reach 90 of rotation without failure or self collision, and for their nonlinear …

Direct Synthesis Of Methane From Co2-H2O Co-Electrolysis In Tubular Solid Oxide Electrolysis Cells, Long Chen, Fanglin Chen, Changrong Xia

Faculty Publications

Directly converting CO₂ to hydrocarbons offers a potential route for carbon-neutral energy technologies. Here we report a novel design, integrating the high-temperature CO₂–H₂O co-electrolysis and low-temperature Fischer–Tropsch synthesis in a single tubular unit, for the direct synthesis of methane from CO₂ with a substantial yield of 11.84%.

Synthesis And Formation Mechanism Of Cuins2 Nanocrystals With A Tunable Phase, Chao Yu, Linlin Zhang, Long Tian, Dan Liu, Fanglin Chen, Cheng Wang

Faculty Publications

Chalcopyrite CuInS₂ (CIS) hierarchical structures composed of nanoflakes with a thickness of about 5 nm were synthesized by a facial solvothermal method. The thermodynamically metastable wurtzite phase CIS would be obtained by using InCl₃ instead of In(NO₃)₃ as In precursor. The effects of the In precursor and the volume of concentrated HCl aqueous solution on the phases and morphologies of CIS nanocrystals have been systematically investigated. Experimental results indicated that the obtained phases of CIS nanocrystals were predominantly determined by precursor-induced intermediate products. The photocatalytic properties of chalcopyrite and wurtzite CIS in visible-light-driven degradation of …

Biphilic Nanoporous Surfaces Enabled Exceptional Drag Reduction And Capillary Evaporation Enhancement, Xianming Dai, Fanghao Yang, Ronggui Yang, Xinyu Huang, William A. Rigdon, Xiaodong Li, Chen Li

Faculty Publications

Simultaneously achieving drag reduction and capillary evaporation enhancement is highly desired but challenging because of the trade-off between two distinct hydrophobic and hydrophilic wettabilities. Here, we report a strategy to synthesize nanoscale biphilic surfaces to endow exceptional drag reduction through creating a unique slip boundary condition and fast capillary wetting by inducing nanoscopic hydrophilic areas. The biphilic nanoporous surfaces are synthesized by decorating hydrophilic functional groups on hydrophobic pristine multiwalled carbon nanotubes. We demonstrate that the carbon nanotube-enabled biphilic nanoporous surfaces lead to a 63.1% reduction of the friction coefficient, a 61.7% wetting speed improvement, and up to 158.6% enhancement …

Host-Guest Interaction Dictated Selective Adsorption And Fluorescence Quenching Of A Luminescent Lightweight Metal-Organic Framework Toward Liquid Explosives, Dan Liu, Xiaojuan Liu, Yongxin Liu, Yang Yu, Fanglin Chen, Cheng Wang

Faculty Publications

In this article, we report the successful preparation of a Mg-based luminescent MIL-53 metal–organic framework (MOF), namely [Mg2(BDC)2(BPNO)]·2DMF (1) (BDC = 1,4-benzene dicarboxylate, BPNO = 4,4’- dipyridyl-N,N’-dioxide, DMF = N,N-dimethylformamide) in a mixed solvent containing a 2 : 3 volume ratio of DMF and ethanol (EtOH) under solvothermal conditions. Desolvated compound 1a can be used as an absorbent for selective adsorption and separation of liquid explosives, including nitroaromatic (nitrobenzene (NB)) and nitroaliphatic (nitromethane (NM) and nitroethane (NE)) compounds, through single crystal-to-single crystal (SC–SC) transformations. As one of the weakly luminescent MOFs, the luminescence of compound 1a could be quenched by …

A Simple Solution Method For The Blade Element Momentum Equations With Guaranteed Convergence, Andrew Ning

Faculty Publications

The blade element momentum equations, though conceptually simple, can be challenging to solve reliably and efficiently with high precision. These requirements are particularly important for efficient rotor blade optimization that utilizes gradient-based algorithms. Many solution approaches exist for numerically converging the axial and tangential induction factors. These methods all generally suffer from a lack of robustness in some regions of the rotor blade design space, or require significantly increased complexity to promote convergence. The approach described here allows for the blade element momentum equations to be parameterized by one variable: the local inflow angle. This reduction is mathematically equivalent, but …

Extended Formation Flight At Transonic Speeds, Andrew Ning, Ilan Kroo, Michael Aftosmis, Marian Nemec, James Kless

Faculty Publications

Aircraft flown in formation can realize significant reductions in induced drag by flying in regions of wake upwash. However, most transports fly at transonic speeds where the impact of compressibility on formation flight is not well understood. This study utilizes an Euler solver to analyze the inviscid aerodynamic forces and moments of transonic wing/body configurations flying in a two-aircraft formation. Formations with large streamwise separation distances (10-50 wingspans) are considered.

This work indicates that compressibility-related drag penalties in formation flight may be eliminated by slowing 2-3% below the nominal out-of-formation cruise Mach number (either at fixed lift coefficient or fixed …

Implementing Dubins Airplane Paths On Fixed-Wing Uavs, Timothy Mclain, Randall W. Beard, Mark Owen

Faculty Publications

A well-known path-planning technique for mobile robots or planar aerial vehicles is to use Dubins paths, which are minimum-distance paths between two configurations subject to the constraints of the Dubins car model. An extension of this method to a three-dimensional Dubins airplane model has recently been proposed. This chapter builds on that work showing a complete architecture for implementing Dubins airplane paths on small fixed-wing UAVs. The existing Dubins airplane model is modified to be more consistent with the kinematics of a fixed-wing aircraft. The chapter then shows how a recently proposed vector-field method can be used to design a …

A Position Analysis Of Coupled Spherical Mechanisms In Action Origami, Landen A. Bowen, L. A. Baxter, Spencer P. Magleby, Larry L. Howell

Faculty Publications

Origami has been previously utilized in design to create deployable systems. Action origami, origami designed to move, has the ability to deploy to a larger state and have motion in the deployed state. The majority of action origami achieves motion through coupled systems of spherical mechanisms. An origami vertex, the point at which folds converge, is shown to be equivalent to a spherical change-point mechanism. A position analysis of an origami vertex is presented, resulting in a relationship between input and output angles as well as the path of the coupler link. A method for analyzing coupled systems of repeated …

Are Undergraduate Gpa And General Gre Percentiles Valid Predictors Of Student Performance In An Engineering Graduate Program?, Larry L. Howell, Carl D. Sorenson, Matthew R. Jones

Faculty Publications

While both subjective measures and quantitative metrics play an important role in admissions decisions, quantitative metrics are amenable to critical analysis using the tools of academic analytics. The hypotheses that motivated this study are: 1. Can an applicant’s undergraduate grade point average (UGPA) and scores on the Graduate Records Examinations (GRE) be used to accurately predict the performance of the applicant in a graduate mechanical engineering program? 2. Is a single construct based on these quantitative predictive metrics a valuable tool in efficiently making admissions decisions? This study analyzed the relationship between quantitative predictive metrics, available at the time of …

Uncertainty Quantification Driven Predictive Multi-Scale Model For Synthesis Of Mycotoxins, Sourav Banerjee, Gabriel A. Terejanu, Anindya Chanda

Faculty Publications

Many toxic molds synthesize and release an array of poisons, termed mycotoxins that have an enormous impact on human health, agriculture and economy [1]. These molds contaminate our buildings, indoor air and crops, cause life threatening human and animal diseases and reduce agricultural output [2]. In order to design appropriate approaches to minimize the detrimental effects of these fungi, it is essential to develop diagnostic methodologies that can rapidly and accurately determine based on fungal strains and their growth patterns, the extent of mycotoxin mediated damage caused to the environment.Here we developed a novel multi-scale predictive mathematical model that could …

Phonon Confinement Using Spirally Designed Elastic Resonators In Discrete Continuum, Sourav Banerjee, Raiz U. Ahmed

Faculty Publications

Periodic and chiral orientation of microstructures, here we call phononic crystals, have extraordinary capabilities to facilitate the innovative design of new generation metamaterials. Periodic arrangements of phononic crystals are capable of opening portals of non-passing, non-dispersive mechanical waves. Defying conventional design of regular periodicity, in this paper spirally periodic but chiral orientation of resonators are envisioned. Dynamics of the spirally connected resonators and the acoustic wave propagation through the spirally connected multiple local resonators are studied using fundamental physics. In present study the spiral systems with local resonators are assumed to be discrete media immersed in fluid. In this paper …

Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen

Faculty Publications

Solid oxide fuel cells (SOFCs) can convert chemical energy from the fuel directly to electrical energy with high efficiency and fuel flexibility. Ni-based cermets have been the most widely adopted anode for SOFCs. However, the conventional Ni-based anode has low tolerance to sulfur-contamination, is vulnerable to deactivation by carbon build-up (coking) from direct oxidation of hydrocarbon fuels, and suffers volume instability upon redox cycling. Among these limitations, the redox instability of the anode is particularly important and has been intensively studied since the SOFC anode may experience redox cycling during fuel cell operations even with the ideal pure hydrogen as …

Understanding The Benefits And Limitations Of Increasing Maximum Rotor Tip Speed For Utility-Scale Wind Turbines, Andrew Ning

Faculty Publications

For utility-scale wind turbines, the maximum rotor rotation speed is generally constrained by noise considerations. Innovations in acoustics and/or siting in remote locations may enable future wind turbine designs to operate with higher tip speeds. Wind turbines designed to take advantage of higher tip speeds are expected to be able to capture more energy and utilize lighter drivetrains because of their decreased maximum torque loads. However, the magnitude of the potential cost savings is unclear, and the potential trade-offs with rotor and tower sizing are not well understood. A multidisciplinary, system-level framework was developed to facilitate wind turbine and wind …

Automatic Evaluation Of Multidisciplinary Derivatives Using A Graph-Based Problem Formulation In Openmdao, Justin Gray, Tristan Hearn, Kenneth Moore, John Hwang, Joaquim Martins, Andrew Ning

Faculty Publications

The optimization of multidisciplinary systems with respect to large numbers of design variables is best pursued using a gradient-based optimization together with a method that efficiently evaluates coupled derivatives, such as the coupled adjoint method. However, implementing such a method in a problem with more than a few disciplines is time consuming and error prone. To address this issue, we develop an automated procedure for assembling and solving the coupled derivative equations that takes into account the disciplinary couplings using the interdisciplinary dependency graph of the problem. The coupled derivatives can be computed completely analytically, if analytic derivatives are available …

Quaternion Based Attitude Error For A Tailsitter In Hover Flight, Timothy Mclain, Matthew E. Argyle, Jason M. Beach, Randall W. Beard, Stephen Morris

Faculty Publications

The tailsitter is a promising airframe that can take off and land on its tail and transition to level flight. While this ability provides vertical takeoff and landing capabilities with no additional moving parts, it introduces interesting control challenges. In this paper, we look at the attitude control system of a tailsitter in hover flight and show that the behaviour of the aircraft relies on the method used to compute the attitude error. We investigate three different methods of computing the attitude error, quaternion feedback, resolved tilt twist, and the resolved Euler angles, and compare them through simulated hover flight.

Tailsitter Heading Estimation Using A Magnetometer, Timothy Mclain, Jason M. Beach, Matthew E. Argyle, Randall W. Beard, Stephen Morris

Faculty Publications

The tailsitter aircraft merges the endurance and speed of fixed-wing aircraft with the flexibility and VTOL abilities of rotorcraft. Typical control and estimation schemes make assumptions about the maximum attitude an aircraft will experience that are not valid for tailsitters. This paper discusses the limitations of a typical EKF magnetometer measurement update that uses Euler angles. It is shown how to use a second set of Euler angles to avoid gimbal lock. A method is given that bypasses the use of Euler angles altogether and directly uses the quaternion to determine heading error and update the attitude estimate. This method …

Probing The Roles Of Polymeric Separators In Lithium-Ion Battery Capacity Fade At Elevated Temperatures, Jianchao Chen, Yongda Yan, Tao Sun, Yue Qi, Xiaodong Li

Faculty Publications

The high temperature mechanical property of separators is very important for safety of lithium-ion batteries. However, the mechanical integrity of polymeric separators in lithium-ion batteries at elevated temperatures is still not well characterized. In this paper, the temperature dependent micro-scale morphology change of PP (polypropylene)-PE (polyethylene)-PP sandwiched separators (Celgard 2325) was studied by in-situ high temperature surface imaging using an atomic force microscope (AFM) coupled with power spectral density (PSD) analysis and digital image correlation (DIC) technique. Both PSD and DIC analysis results show that the PP phase significantly closes its pores by means of dilation of the nanofibrils surrounding …

A Novel Intermediate-Temperature All Ceramic Iron–Air Redox Battery: The Effect Of Current Density And Cycle Duration, Xuan Zhao, Xue Li, Yunhui Gong, Nansheng Xu, Kevin Huang

Faculty Publications

We here report the energy storage characteristics of a new all ceramic iron–air redox battery comprising of a reversible solid oxide fuel cell as the charger/discharger and a Fe–FeO_x redox couple as the chemical storage bed. The effects of current density and cycle duration on specific energy and round trip efficiency of the new battery have been systematically studied at 650°C and 550°C. The results explicitly show that current density is the most influential variable on the performance, signifying the importance of improving electrochemical performance of the reversible solid oxide fuel cell.

Characterization Of 3d Interconnected Microstructural Network In Mixed Ionic And Electronic Conducting Ceramic Composites, William M. Harris, Kyle S. Brinkman, Ye Lin, Dong Su, Alex P. Cocco, Arata Nakajo, Matthew B. Degostin, Yu-Chen Karen Chen-Wiegart, Jun Wang, Fanglin Chen, Yong S. Chu, Wilson K. S. Chiu

Faculty Publications

The microstructure and connectivity of the ionic and electronic conductive phases in composite ceramic membranes are directly related to device performance. Transmission electron microscopy (TEM) including chemical mapping combined with X-ray nanotomography (XNT) have been used to characterize the composition and 3-D microstructure of a MIEC composite model system consisting of a Ce_0.8Gd_0.2O₂ (GDC) oxygen ion conductive phase and a CoFe₂O₄ (CFO) electronic conductive phase. The microstructural data is discussed, including the composition and distribution of an emergent phase which takes the form of isolated and distinct regions. Performance implications are considered …

Piezoresistive Sensing Of Bistable Micro Mechanism State, Jeffrey K. Anderson, Larry L. Howell, Jonathan W. Wittwer, Timothy W. Mclain

Faculty Publications

The objective of this work is to demonstrate the feasibility of on-chip sensing of bistable mechanism state using the piezoresistive properties of polysilicon, thus eliminating the need for electrical contacts. Changes in position are detected by observing changes in resistance across the mechanism. Sensing the state of bistable mechanisms is critical for various applications, including high-acceleration sensing arrays and alternative forms of nonvolatile memory. A fully compliant bistable micro mechanism was designed, fabricated, and tested to demonstrate the feasibility of this sensing technique. Testing results from two fabrication processes, SUMMiT IV and MUMPs, are presented. The SUMMiT mechanism was then …

Tailsitter Attitude Control Using Resolved Tilt-Twist, Timothy Mclain, Jason M. Beach, Matthew E. Argyle, Randall W. Beard, Stephen Morris

Faculty Publications

The tailsitter aircraft merges the endurance and speed of fixed-wing aircraft with the flexibility and VTOL abilities of rotorcraft. Because of the requirement to be functional at a full range of attitudes, quaternions are typically employed to calculate attitude error. Attitude control is then accomplished by using the vector component of the error quaternion to drive flight control surfaces. This paper demonstrates that this method of driving the flight control surfaces can be suboptimal for tailsitter type aircraft and can lead to undesired vehicle movement. An alternate method of calculating attitude error called resolved tilt-twist is improved and validated. The …

A Sinteractive Ni-Bazr0.8Y0.2O3-Δ Composite Membrane For Hydrogen Separation, Shumin Fang, Siwei Wang, Kyle S. Brinkman, Fanglin Chen

Faculty Publications

BaZr_0.8Y_0.2O_3−δ (BZY) is an excellent candidate material for hydrogen permeation membranes due to its high bulk proton conductivity, mechanical robustness, and chemical stability in H₂O- and CO₂-containing environments. Unfortunately, the use of BZY as a separation membrane has been greatly restrained by its highly refractory nature, poor grain boundary proton conductivity, high number of grain boundaries resulting from limited grain growth during sintering, as well as low electronic conductivity. These problems can be resolved by the fabrication of a Ni–BZY composite membrane with large BZY grains, which requires the development …

Relative Navigation Approach For Vision-Based Aerial Gps-Denied Navigation, Timothy Mclain, Randal W. Beard, Robert C. Leishman

Faculty Publications

GPS-denied aerial flight is a challenging research problem and requires knowledge of complex elements from several distinct disciplines. Additionally, aerial vehicles can present challenging constraints such as stringent payload limits and fast vehicle dynamics. In this paper we propose a new architecture to simplify some of the challenges that constrain GPS-denied aerial flight. At the core, the approach combines visual graph-SLAM with a multiplicative extended Kalman filter. More importantly, for the front end we depart from the common practice of estimating global states and instead keep the position and yaw states of the MEKF relative to the current node in …

Investigation Of The High-Temperature Redox Chemistry Of Sr2Fe1.5Mo0.5O6-Δ Via In Situ Neutron Diffraction, Daniel E. Bugaris, Jason P. Hodges, Ashfia Hug, W. Michael Chance, Andreas Heyden, Fanglin Chen, Hans-Conrad Zur Loye

Faculty Publications

Crystallographic structural changes were investigated for Sr₂Fe_1.5Mo_0.5O_6−δ, an electrode material for symmetric solid oxide fuel cells. The samples of this material were heated and cooled in wet hydrogen and wet oxygen atmospheres, to simulate the reducing and oxidizing conditions experienced under actual fuel cell operating conditions, and their structures and oxygen contents were determined using in situ powder neutron diffraction. The existence of a reversible tetragonal to cubic phase transition was established to occur between room temperature and 400 °C, both on heating and cooling in either oxygen or hydrogen. The …

Aerial Rendezvous Of Small Unmanned Aircraft Using A Passive Towed Cable System, Timothy Mclain, Randall W. Beard, Joseph W. Nichols, Liang Sun

Faculty Publications

A method for aerial rendezvous of small unmanned aircraft systems is proposed. The system includes placing a passively towed drogue into an orbit that is suitable for a small unmanned aircraft systems to follow, and a seeker guidance method for use with a monocular camera mounted on the centerline of the unmanned aircraft systems. The principle contributions of the work include a method for controlling the drogue path in moderate winds by manipulating the mothership orbit and airspeed, and a vision-based nonlinear pursuit tracking method that uses pitch rate and roll commands to guide the unmanned aircraft systems to an …

Automated Tracking And Estimation For Control Of Non-Rigid Cloth, Marc D. Killpack

Faculty Publications

This report is a summary of research conducted on cloth tracking for automated textile manufacturing during a two semester long research course at Georgia Tech. This work was completed in 2009. Advances in current sensing technology such as the Microsoft Kinect would now allow me to relax certain assumptions and generally improve the tracking performance. This is because a major part of my approach described in this paper was to track features in a 2D image and use these to estimate the cloth deformation. Innovations such as the Kinect would improve estimation due to the automatic depth information obtained when …

Aircraft Route Optimization For Formation Flight, Jia Xu, Andrew Ning, Geoffrey Bower, Ilan Kroo

Faculty Publications

We quantify the fuel and cost benefits of applying extended formation flight to com- mercial airline operations. Central to this study is the development of a bi-level, mixed integer-real formation flight optimization framework. The framework has two main components: 1) a continuous domain aircraft mission performance optimization and 2) an integer optimization component that selects the best combination of optimized missions to form a formation flight schedule. The mission performance reflects the effects of rolled-up wakes, formation heterogeneity, and formation-induced compressibility. The results show that an airline can use formation flight to reduce fuel burn by 5.8% or direct operating …

High-Efficiency Thermodynamic Power Cycles For Concentrated Solar Power Systems, Marc T. Dunham, Brian Iverson

Faculty Publications

This paper provides a review of high-efficiency thermodynamic cycles and their applicability to concentrating solar power systems, primarily focusing on high-efficiency single and combined cycles. Novel approaches to power generation proposed in the literature are also highlighted. The review is followed by analyses of promising candidates, including regenerated He-Brayton, regenerated CO2-Brayton, CO2 recompression Brayton, steam Rankine, and CO2-ORC combined cycle. Steam Rankine is shown to offer higher thermal efficiencies at temperatures up to about 600 ˚C but requires a change in materials for components above this temperature. Above this temperature, CO2 recompression Brayton cycles are shown to have very high …