Mechanical Engineering Commons^™

Anisotropic Compositional Expansion And Chemical Potential For Amorphous Lithiated Silicon Under Stress Tensor, Valery I. Levitas, Hamed Attariani

Mechanical and Materials Engineering Faculty Publications

Si is a promising anode material for Li-ion batteries, since it absorbs large amounts of Li. However, insertion of Li leads to 334% of volumetric expansion, huge stresses, and fracture; it can be suppressed by utilizing nanoscale anode structures. Continuum approaches to stress relaxation in Li_xSi, based on plasticity theory, are unrealistic, because the yield strength of Li_xSi is much higher than the generated stresses. Here, we suggest that stress relaxation is due to anisotropic (tensorial) compositional straining that occurs during insertion-extraction at any deviatoric stresses. Developed theory describes known experimental and atomistic simulation …