Mechanical Engineering Commons^™

Environmental And Energy Saving Technologies Of Vinyl Chloride Production, Mykola Kurta

USF Tampa Graduate Theses and Dissertations

Recently, because of the increase of environmental concerns in process design, the need to enhance conversion to product and prevent generation of wasteful byproducts in the reactor network has become urgent. This prevents high cost treatment and separation costs downstream in the process. Therefore, in this thesis I focus on making production of vinyl chloride monomer (VCM) more efficient and on possible ways of industrial organochlorine waste (OCW) recycling. In particular, in the first experiment, we investigate how catalyst and its structure can affect product output.

Infrared spectroscopy and X-ray diffraction analysis were utilized to investigate the structure of the …

Reliability Assessment Of Ion Contamination Residues On Printed Circuit Board, Minh Tam Tran Nguyen

USF Tampa Graduate Theses and Dissertations

Ion contaminants from Printed Circuit Board (PCB) assembly processes pose a high reliability risk because they result in damaged circuits. Therefore, it is essential to understand the level of ionic species on the electronic circuitry as well as the reliability risks caused by these contaminants. There are a number of approaches available in the industry to assess the reliability risks ; for example, the water drop test (WDT) is one of the techniques used to determine the propensity of an ionic contaminant to cause electrical short failures by dendrite formation. The objective of this research is to determine the time …

Towards Rans Parameterization Of Vertical Mixing By Langmuir Turbulence In Shallow Coastal Shelves, Nityanand Sinha

USF Tampa Graduate Theses and Dissertations

Langmuir turbulence in the upper ocean is generated by the interaction between the wind-driven shear current and the Stokes drift velocity induced by surface gravity waves. In homogenous (neutrally stratified) shallow water, the largest scales of Langmuir turbulence are characterized by full-depth Langmuir circulation (LC). LC consists of parallel counter-rotating vortices aligned roughly in the direction of the wind. In shallow coastal shelves, LC has been observed engulfing the entire water column, interacting with the boundary layer and serving as an important mechanism for sediment re-suspension.

In this research, large-eddy simulations (LES) of Langmuir turbulence with full-depth LC in a …

Analytical Modeling, Perturbation Analysis And Experimental Characterization Of Guided Surface Acoustic Wave Sensors, Onursal Onen

USF Tampa Graduate Theses and Dissertations

In this dissertation, guided surface acoustic wave sensors were investigated theoretically and experimentally in detail for immunosensing applications. Shear horizontal polarized guided surface acoustic wave propagation for mass loading sensing applications was modeled using analytical modeling and characterized by perturbation analysis. The model verification was performed experimentally and a surface acoustic wave immunosensor case study was presented. The results of the immunosensing were also investigated using the perturbation analysis.

Guided surface acoustic wave propagation problem was investigated in detail for gravimetric (or mass loading) guided wave sensors, more specifically for immunosensors. The analytical model was developed for multilayer systems taking …

Development Of Nanostructured Graphene/Conducting Polymer Composite Materials For Supercapacitor Applications, Punya A. Basnayaka

USF Tampa Graduate Theses and Dissertations

The developments in mobile/portable electronics and alternative energy vehicles prompted engineers and researchers to develop electrochemical energy storage devices called supercapacitors, as the third generation type capacitors. Most of the research and development on supercapacitors focus on electrode materials, electrolytes and hybridization. Some attempts have been directed towards increasing the energy density by employing electroactive materials, such as metal oxides and conducting polymers (CPs). However, the high cost and toxicity of applicable metal oxides and poor long term stability of CPs paved the way to alternative electrode materials. The electroactive materials with carbon particles in composites have been used substantially …

Static And Dynamic Components Of Droplet Friction, Peter Robert Griffiths

USF Tampa Graduate Theses and Dissertations

As digital microfluidics has continued to mature since its advent in the early 1980's, an increase in new and novel applications of this technology have been developed. However, even as this technology has become more common place, a consensus on the physics and force models of the motion of the contact line between the fluid, substrate, and ambient has not been reached. This uncertainty along with the dependence of the droplet geometry on the force to cause its motion has directed much of the research at specific geometries and droplet actuation methods.

The goal of this thesis is to help …

Human Intention Recognition Based Assisted Telerobotic Grasping Of Objects In An Unstructured Environment, Karan Hariharan Khokar

USF Tampa Graduate Theses and Dissertations

In this dissertation work, a methodology is proposed to enable a robot to identify an object to be grasped and its intended grasp configuration while a human is teleoperating a robot towards the desired object. Based on the detected object and grasp configuration, the human is assisted in the teleoperation task. The environment is unstructured and consists of a number of objects, each with various possible grasp configurations. The identification of the object and the grasp configuration is carried out in real time, by recognizing the intention of the human motion. Simultaneously, the human user is assisted to preshape over …

Analytical And Numerical Modeling Of Assembly Procedures Of Steel Fulcra Of Bascule Bridges, Sriharsha Garapati

USF Tampa Graduate Theses and Dissertations

To model shrink-fitting in metal components, an analytical model for two long compound cylinders with temperature dependent material properties and interference between them is developed for calculating transient temperatures and stresses. A finite element model is developed for the same geometry which incorporated the temperature dependent material properties. A convergence study is performed on the finite element and analytical model. The finite element model is validated by comparing the approximations of finite element model with the analytical solution.

In an assembly procedure of fulcrums for bascule bridges, called AP1, the trunnion is shrink-fitted into a hub, followed by shrink fitting …

Shield Design For Maximum Deformation In Shape-Shifting Surfaces, Daniel Eduardo Perez

USF Tampa Graduate Theses and Dissertations

This research presents the initial studies and results on shield design for Shape-Shifting Surfaces (SSSs) seeking maximum compression and maximum expansion of a unit-cell. Shape-Shifting Surfaces (SSSs) are multilayered surfaces that are able to change shape while maintaining their integrity as physical barriers. SSSs are composed of polygonal unit-cells, which can change side lengths and corner angles. These changes are made possible by each side and corner consisting of at least two different shields, or layers of material. As the layers undergo relative motion, the unit-cell changes shape. In order for the SSS to retain its effectiveness as a barrier, …

An Acoustic-Based Microfluidic Platform For Active Separation And Mixing, Myeong Chan Jo

USF Tampa Graduate Theses and Dissertations

Particle separation is of great interest to many biological and biomedical applications. Flow-based methods have been used to sort particles and cells. However, the main challenge with flow based particle separation systems is the need for a sheath flow for successful operation. Existence of the sheath liquid dilutes the analyte, necessitates precise flow control between sample and sheath flow, requires a complicated design to create sheath flow and separation efficiency depends on the sheath liquid composition. In addition, current gold standard active separation techniques are only capable of separation based on particle size; hence, separation cannot be achieved for same-size …

Continuous Electrowetting In Passivating And Non-Passivating Systems, Mehdi Khodayari

USF Tampa Graduate Theses and Dissertations

Electrowetting is an electromechanical response that can be used to change the equilibrium

shape of droplets on a surface through the application of an electric potential. By applying this potential asymmetrically to a droplet, the droplet can be moved. Typical electrowetting devices use an electrode covered by a dielectric to reduce electrochemical interactions. Successful electrowetting requires electrodes and dielectric layers that can resist damage through many cycles of voltage.

Continuous Electrowetting (CEW) is performed on high resistivity silicon wafers. In this process, when an electric potential difference is applied between the substrate ends, the droplet on the substrate moves towards …

Design, Manufacturing, And Assembly Of A Flexible Thermoelectric Device, Christopher Anthony Martinez

USF Tampa Graduate Theses and Dissertations

This thesis documents the design, manufacturing, and assembly of a flexible thermoelectric device. Such a device has immediate use in haptics, medical, and athletic applications. The governing theory behind the device is explained and a one dimensional heat transfer model is developed to estimate performance. This model and consideration for the manufacturing and assembly possibilities are the drivers behind the decisions made in design choices. Once the design was finalized, manufacturing methods for the various components were explored. The system was created by etching copper patterns on a copper/polyimide laminate and screen printing solder paste onto the circuits. Thermoelectric elements …

A Wearable Motion Analysis System To Evaluate Gait Deviations, Amanda Lynn Martori

USF Tampa Graduate Theses and Dissertations

A Wearable Motion Analysis System (WMAS) was developed to evaluate gait, particularly parameters that are indicative of mild traumatic brain injury. The WMAS consisted on six Opal IMUs attached on the sternum, waist, left and right thigh and left and right shank. Algorithms were developed to calculate the knee flexion angle, stride length and cadence parameters during slow, normal and fast gait speeds. The WMAS was validated for repeatability using a robotic arm and accuracy using the Vicon motion capture system, the gold standard for gait analysis. The WMAS calculated the gait parameters to within a clinically acceptable range and …

Aspect Ratio Effect On Melting And Solidification During Thermal Energy Storage, Prashanth Sridharan

USF Tampa Graduate Theses and Dissertations

The present work investigates, numerically, the process of melting and solidification in hollow vertical cylinders, filled with air and phase change material (PCM). The PCM used is sodium nitrate, which expands upon melting. Therefore, a void must be present within the cylinder, which is filled with air. The influence of cylinder shape on melting time is determined. The numerical model takes both conductive and convective heat transfer into account during the melting process. The Volume-of-Fluid (VOF) model is used to track the interface between the PCM and air as the PCM melts. Three dimensionless numbers represent the characteristics of the …

Effect Of Bolted Joint Preload On Structural Damping, Weiwei Xu

USF Tampa Graduate Theses and Dissertations

Bolted joints are integral parts of mechanical systems, and bolt preload loss is one of the major failure modes for bolted joint structures. Understanding the damping and frequency response to a varying preload in a single-bolted lap-joint structure can be very helpful in predicting and analyzing more complicated structures connected by these joints.

In this thesis, the relationship between the bolt preload and the natural frequency, and the relationship between the bolt preload and the structural damping, have both been investigated through impact hammer testing on a single-bolted lap-joint structure. The test data revealed that the bolt preload has nonlinear …

A Simplified Model Of The Internal Combustion Engine, Christofer Neff

Undergraduate Journal of Mathematical Modeling: One + Two

This project further investigates a model of a simplified internal combustion engine considered by Kranc in 1977. Using Euler’s method for ordinary differential equations, we modeled the interaction between the engine’s flywheel and thermodynamic power cycle. Approximating with sufficiently small time intervals (0.001 seconds over a period of 12 seconds) reproduced Kranc’s results with the engine having an average angular velocity of 72/sec.