Mechanical Engineering Commons^™

Synthesis Of Tin Oxide Nanostructures With Controlled Particle Size Using Mesoporous Frameworks, A. Cabot, J. Arbiol, E. Rossinyol, J. R. Morante, Fanglin Chen, Meilin Liu

Faculty Publications

Tin oxide nanostructures with controlled narrow particle size distribution were synthesized inside silica mesoporous templates. In this way, particle growth was blocked by physically corseting the tin compound inside the silica frameworks, the pore diameter of which determines the final tin oxide crystallite size distribution. Template structures were subsequently eliminated by chemical methods to collect the unsupported semiconductor nanoparticles. Thus obtained tin oxed nanopowders, with particle sizes in the range between 6 and 10 nm, were structurally, chemically, and electically characterized. The results are compared with those obtained from the characterization of larger crystallite materials.