Mechanical Engineering Commons^™

Interfacial Engineering Of Nickel-Rich Layered Oxide Cathodes Via Atomic Layer Deposition (Ald), Xin Wang

Graduate Theses and Dissertations

Layered nickel-rich cathodes LiNixMnyCozO2 (NMCs, x + y + z =1, x ≥ 0.6) are regarded as one of the most promising cathode materials for next-generation lithium-ion batteries (LIBs), given their remarkably reduced cost and increased capacity compared to the conventional LiCoO2 cathode. However, the deployment of these Ni-rich cathodes has been hindered by the continuous loss of practical capacity and reduction in average working voltage, inherently due to their interfacial, structural, and thermodynamic instability. To address these issues, interfacial engineering via surface modification has been well-recognized as an effective strategy and a large number of coating materials have been …