Mechanical Engineering Commons^™

Improving Tribological Properties Of Polydopamine/Polytetrafluoroethylene Coatings Through Incorporating Core-Shell Nanoparticles And Laser Surface Texturing, Firuze Soltani-Kordshuli

Graduate Theses and Dissertations

Polytetrafluoroethylene (PTFE) is a widely used polymer that has unique properties such as chemical and temperature resistance, corrosion resistance, low maintenance cost, and a very low coefficient of friction (COF). These distinctive properties have made PTFE a promising candidate for industrial applications where surfaces are in relative motion. PTFE can be utilized as a thin film solid lubricant to significantly reduce the friction between moving surfaces. However, PTFE coatings have low cohesion and poor adhesion to the substrate resulting in its low wear resistance. This fact limits the application of PTFE coatings in load-bearing situations. To address these limitations, an …

Tribological Studies Of Thick Polytetrafluoroethylene Coatings Enhanced By Polydopamine And Nanoparticles, Sujan Kumar Ghosh

Graduate Theses and Dissertations

Polytetrafluoroethylene (PTFE) is a popular low friction solid lubricant with high chemical and thermal stability. Thick PTFE coatings have the potential for many tribological applications, such as replacing Tin-based Babbitt materials in journal bearings. However, the weak bonding strength to the substrate and the high wear rate of PTFE coatings are current limiting factors. The lack of understanding of their tribological properties and wear mechanisms in oil-lubricated conditions and how coating thickness affects the tribological performance further hindered the use of PTFE coatings. In this dissertation, polydopamine (PDA), a bio-inspired adhesive, is used as an underlayer for or as a …

High Temperature Degradation In Gan-Based Hall Effect Sensors, Alexis Anne Krone

Graduate Theses and Dissertations

This research focuses on understanding the effects of accelerated aging through temperature and environment on novel gallium nitride-based Hall effect magnetic field sensors and determining device reliability under electric vehicle operating conditions. The device reliability was modeled using accelerated aging for the temperatures of 200 °C, 350 °C, 450 °C, and 600 °C under various time steps unique to each temperature and either air, which is identical to operating circumstances, or argon, which would model the hermetic packaging environment. Using a high temperature furnace and oven, devices underwent high temperature storage tests at a chosen temperature and time step. Afterwards, …

An Investigation Of Testing Parameters On The Frictional Properties Of Patterned Core-Shell Nanostructures, Colin Phelan

Graduate Theses and Dissertations

Friction tests are a beneficial means to analyze the tribological characteristics and advantages of materials and textured surfaces. However, the selected test parameters can significantly influence the results. This work explores the significance of the friction testing parameters on the frictional performances of core-shell nanostructure-textured surfaces (CSNTSs). Several applied normal loads (10 μN, 100 μN, and 500 μN) and diamond counterface indenter tip radii (1 μm, 5 μm, and 20 μm) were selected for the testing of Al/diamond-like-carbon (DLC) and Al/amorphous silicon (a-Si) CSNTSs. The measured friction values of the CSNTSs were then compared to a matching Al/DLC film and …

Mechanical And Frictional Behavior Of Textured And Non-Textured Surfaces, Raghuram R. Santhapuram

Graduate Theses and Dissertations

Tribology is the study of surfaces where two objects are sliding against another. Significant energy is lost due to friction between the sliding surfaces. Therefore, developing or designing surfaces to minimize friction is critical for the durability and reliability of the mechanical components. Several researchers have identified that surface texturing at the nanoscale (nanotexture) would reduce the friction between the contacting surfaces. The nanotextured surfaces have several applications in microelectromechanical systems and nanoelectromechanical systems. This dissertation employs molecular dynamics simulations to investigate the frictional and mechanical response of nanotextured aluminum (Al) and Al/amorphous silicon (a-Si) composite surfaces.

This study determines …

Photochemical Etching Of Nitrided Stainless Steel Piston Rings, Steven Sonntag

Mechanical Engineering Undergraduate Honors Theses

Piston rings are designed to provide a seal between the piston and the cylinder wall of internal combustion engines, keeping oil from the crankcase from getting into the combustion chamber. This means piston rings are the main point of contact between the piston and the cylinder wall, which causes the piston to experience high amounts of friction and wear. By texturing the surfaces of the cylinder wall and/or the piston ring, the amount of contact area can be reduced, allowing for less friction, slower wear, and better gas mileage. In this thesis experiments, photochemical etching processes were developed to etch …

Incorporation Of Silica Nanoparticles Into The Underlayer Of Pda/Ptfe Thin Coatings, Adedoyin Abe

Mechanical Engineering Undergraduate Honors Theses

Polytetrafluoroethylene (PTFE) is one of the most low friction and corrosion resistant solid lubricants. Prior studies have shown that a polydopamine (PDA) underlayer enhances the durability of PTFE thin coating. In this study, 100, 200, and 300 µL of aqueous silica nanoparticle (NP) solutions were added to the PDA deposition solution. The durability and coefficient of friction of PDA/PTFE thin coatings on stainless steel substrates are investigated with and without incorporating the silica NPs. The coatings were tested in dry contact conditions using a Universal Mechanical Tester (UMT) with a ball-on-flat configuration in a reciprocating motion. It was found that …

Understanding The Evolution Of Surface Texture Under Boundary Lubrication, Salil T. Bapat

Graduate Theses and Dissertations

The objective of this research was to understand the evolution of surface texture under boundary/mixed lubrication (BL). Significant material/energy losses occur during BL because of direct contact between the two surfaces. Traditionally, tribofilms have been studied extensively for BL while textures have been used as a static engineering design parameter to enhance lubricant film properties. However, texture is dynamic at the tribological mating interface, where both physical and chemical interactions are continuously modulated. The evolution and the interplay between the tribofilm and texture is least studied in the literature, which is the focus of this research.

MoS2-based lubricants, known for …

A Nanoindentation Study Of The Fatigue Properties Of Al/A-Si Core-Shell Nanostructures, Jason Steck

Mechanical Engineering Undergraduate Honors Theses

Nanostructure-textured surfaces can reduce friction and increase the reliability of micro- and nanoelectromechanical systems (NEMS/MEMS). For MEMS incorporating moving parts, the fatigue properties of nanostructures pose a challenge to their reliability in long-term applications. In this study, the fatigue behavior of hemispherical Al/a-Si core-shell nanostructures (CSNs), bare hemispherical Al nanodots, and a flat Al/a-Si layered thin film have been studied using nanoindentation and nano-scale dynamic mechanical analysis (nano-DMA) techniques. Fatigue testing with nano-DMA shows that the deformation resistance of CSNs persists through 5.0 × 10⁴ loading cycles at estimated contact pressures greater than 15 GPa. When the a-Si shell …

Polytetraflouroethylene Thin Coatings For Tribological Applications, Samuel L. Jenkins

Mechanical Engineering Undergraduate Honors Theses

Mechanical components with lower coefficients of friction decrease the amount of energy dissipated by the system due to friction. Coating these components would decrease the coefficients of friction between surfaces without sacrificing the strength of the components. A polytetrafluoroethylene (PTFE) layer adhered through a polydopamine (PDA) layer on a steel substrate will reduce the coefficient of friction on the substrate surface. This paper discusses different methods for attempting to increase the uniformity of the PDA layer as well as decrease the PDA coating time. Methods for increasing uniformity include using a particle disperser instead of a magnet stir rod, changing …

Characterization Of Nano-Porous Si-Cu Composites To Enhance Lubricant Retention Impacting The Tribological Properties Of Sliding Surfaces, Julius Sheldon Morehead

Graduate Theses and Dissertations

As the expectations for modern machinery's tribological and thermal performances continue to rise, the retention of lubricant on the contact surfaces of their sliding components becomes an increasingly important issue. Friction and wear cause heat-related failures which lead to catastrophic damage to machinery. Evaporation of a lubricant's volatile constituents as well as lubricant migration leads not only to a reduction in lubricant quantity but also in its quality, thus facilitating component failures. In order to enhance component reliability, the surface should incorporate features that actively retain lubricants. The unique properties of nano-porous topographies such as their high surface area-to-volume ratio …

Wear Resistant Polydopamine/Ptfe Nanoparticle Composite Coating For Dry Lubrication Applications, Samuel George Beckford

Graduate Theses and Dissertations

This dissertation presents an investigation into the effect of nanoparticle fillers and a polydopamine adhesive primer on the tribological performance of thin PTFE films. The principal objective of this investigation was to reduce wear in PTFE films, an issue which precludes the use of PTFE films in tribological applications requiring high durability. The friction and wear of the composite films were evaluated using a ball-on-flat configuration in linear reciprocating motion. It was found that the use of a polydopamine adhesive primer reduces the wear of PTFE films more than 600 times. X-ray photoelectron spectroscopy (XPS) results show that a tenacious …

Phase Transformation In Monolayer Molybdenum Disulphide With And Without Defects Under Tension Predicted By Atomistic Simulations, Khanh Quoc Dang

Graduate Theses and Dissertations

In addition to its use as a solid lubricant, molybdenum disulphide (MoS2) has gained recent attention as a possible substitute for silicon as it is increasingly difficult to keep shrinking down electronic devices made of silicon, the conventional electronic material. When thinned down to atomic thickness, monolayer MoS2 possesses very unique and promising electronic and electrical properties. Unlike electronic and electrical properties, knowledge of the mechanical properties and role of structural defects on these properties of monolayer MoS2 is unexplored. For this thesis, the two main objectives are (1) to gain insight about the failure mechanism of monolayer MoS2 by …