Mechanical Engineering Commons^™

Micro/Nanostructured Mnco2o4.5 Anodes With High Reversible Capacity And Excellent Rate Capability For Next Generation Lithium-Ion Batteries, Bin Wang, Shifeng Wang, Yuanyuan Tang, Chi-Wing Tsang, Jinchuan Dai, Michael K.H. Leung, Xiao-Ying Lu

Faculty of Science & Technology (THEi)

Lithium-ion batteries have already achieved great success in consumer electronics. However, the electrochemical characteristics of the existing electrodes have constrained their widespread applications in electric vehicles, which need technical demands of high energy density and fast charging. Thus, it is highly desirable to explore high-performance electrodes with high reversible capacity and excellent rate capability. In this study, micro/nanostructured MnCo2O4.5 anodes were synthesized by hydrothermal treatment with the presence of positively charged poly(diallyldimethylammonium chloride). Physicochemical property studies suggested that the as-prepared MnCo2O4.5 of 2–5 µm in diameter was mainly composed of numerous nanoneedles, which were further comprised of many inter-connected nanoparticles. …