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Full-Text Articles in Mechanical Engineering

Evaluation Of Thermal Radiation Effects On Apparent Propagation Rates Of High Pressure Spherical Flames, Jeffrey S. Santner, Francis M. Haas, Yiguang Ju, Frederick L. Dryer Sep 2013

Evaluation Of Thermal Radiation Effects On Apparent Propagation Rates Of High Pressure Spherical Flames, Jeffrey S. Santner, Francis M. Haas, Yiguang Ju, Frederick L. Dryer

Francis (Mac) Haas

Thermal radiation is usually not considered in the interpretation of laminar burning rates measured by the outwardly propagating spherical flame method. However, it may contribute significantly to measurement uncertainty, especially for model-constraining conditions at lower flame temperatures and higher pressures. The present work derives a conservative analytical estimate of the effects of radiation heat loss, which include radiation-induced burned gas motion, decreasing flame temperature due to conduction to the radiating burned gas, and radiation loss from the flame zone. Detailed numerical simulations covering a range of burning conditions serve to validate this analytical tool. Modeling results from both detailed simulation …


Measurements Of Nh3 Linestrengths And Collisional Broadening Coefficients In N2, O2, Co2, And H2o Near 1103.46 Cm−1, Kyle Owen, Et-Touhami Es-Sebbar, Aamir Farooq Feb 2013

Measurements Of Nh3 Linestrengths And Collisional Broadening Coefficients In N2, O2, Co2, And H2o Near 1103.46 Cm−1, Kyle Owen, Et-Touhami Es-Sebbar, Aamir Farooq

Dr. Et-touhami Es-sebbar

Laser-based ammonia gas sensors have useful applications in many fields including combustion, atmospheric monitoring, and medical diagnostics. Calibration-free trace gas sensors require the spectroscopic parameters including linestrengths and collisional broadening coefficients to be known. Ammonia's strong ν2 vibrational band between View the MathML source has the high absorption strength needed for sensing small concentrations. Within this band, the 1103.46 cm−1 feature is one of the strongest and has minimal interference from CO2 and H2O. However, the six rotational transitions that make up this feature have not been studied previously with absorption spectroscopy due to their small line spacing ranging from …


Effects Of N2o And O2 Addition To Nitrogen Townsend Dielectric Barrier Discharges At Atmospheric Pressure On The Absolute Ground-State Atomic Nitrogen Density, Et. Es-Sebbar, N. Gherardi, F. Massines Jan 2013

Effects Of N2o And O2 Addition To Nitrogen Townsend Dielectric Barrier Discharges At Atmospheric Pressure On The Absolute Ground-State Atomic Nitrogen Density, Et. Es-Sebbar, N. Gherardi, F. Massines

Dr. Et-touhami Es-sebbar

Absolute ground-state density of nitrogen atoms N (2p3 4S3/2) in non-equilibrium Townsend dielectric barrier discharges (TDBDs) at atmospheric pressure sustained in N2/N2O and N2/O2 gas mixtures has been measured using Two-photon absorption laser-induced fluorescence (TALIF) spectroscopy. The quantitative measurements have been obtained by TALIF calibration using krypton as a reference gas. We previously reported that the maximum of N (2p3 4S3/2) atom density is around 3 × 1014 cm−3 in pure nitrogen TDBD, and that this maximum depends strongly on the mean energy dissipated in the gas. In the two gas mixtures studied here, results show that the absolute N …


Mechaniczny Rozdział Faz Proj., Wojciech M. Budzianowski Jan 2013

Mechaniczny Rozdział Faz Proj., Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.


Challenges And Prospects Of Processes Utilising Carbonic Anhydrase For Co2 Separation, Patrycja Szeligiewicz, Wojciech M. Budzianowski Jan 2013

Challenges And Prospects Of Processes Utilising Carbonic Anhydrase For Co2 Separation, Patrycja Szeligiewicz, Wojciech M. Budzianowski

Wojciech Budzianowski

This article provides an analysis of processes for separation CO2 by using carbonic anhydrase enzyme with particular emphasis on reactive-membrane solutions. Three available processes are characterised. Main challenges and prospects are given. It is found that in view of numerous challenges practical applications of these processes will be difficult in near future. Further research is therefore needed for improving existing processes through finding methods for eliminating their main drawbacks such as short lifetime of carbonic anhydrase or low resistance of reactive membrane systems to impurities contained in flue gases from power plants.


Determination Of Kinetic Parameters From The Thermogravimetric Data Set Of Biomass Samples, Karol Postawa, Wojciech M. Budzianowski Dec 2012

Determination Of Kinetic Parameters From The Thermogravimetric Data Set Of Biomass Samples, Karol Postawa, Wojciech M. Budzianowski

Wojciech Budzianowski

This article describes methods of the determination of kinetic parameters from the thermogravimetric data set of biomass samples. It presents the methodology of the research, description of the needed equipment, and the method of analysis of thermogravimetric data. It describes both methodology of obtaining quantitative data such as kinetic parameters as well as of obtaining qualitative data like the composition of biomass. The study is focused mainly on plant biomass because it is easy in harvesting and preparation. Methodology is shown on the sample containing corn stover which is subsequently pyrolysed. The investigated sample show the kinetic of first order …


Temperature-Dependent Absorption Cross-Section Measurements Of 1-Butene (1-C4h8) In Vuv And Ir, Et-Touhami Es-Sebbar, Yves Benilan, Aamir Farooq Dec 2012

Temperature-Dependent Absorption Cross-Section Measurements Of 1-Butene (1-C4h8) In Vuv And Ir, Et-Touhami Es-Sebbar, Yves Benilan, Aamir Farooq

Dr. Et-touhami Es-sebbar

Vacuum ultraviolet (VUV) and infrared (IR) absorption cross-section measurements of 1-butene (1-C4H8; CH2=CHCH2CH3; Butylene) are reported over the temperature range of 296–529 K. The VUV measurements are performed between 115 and 205 nm using synchrotron radiation as a tunable VUV light source. Fourier Transform Infrared (FTIR) spectroscopy is employed to measure absorption cross-section and band strengths in the IR region between 1.54 and 25 μm (∼6500–400 cm−1). The measured room-temperature VUV and IR absorption cross-sections are compared with available literature data and are found to be in good agreement. The oscillator strength for the electronic transition (A1A′→X1A′) around 150–205 nm …