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Mercuric Ionic Liquids: [Cnmim][Hgx3], Where N = 3, 4 And X = Cl, Br, Bert Mallick, Andreas Metlen, Mark Nieuwenhuyzen, Robin D. Rogers, Anja V. Mudring
Mercuric Ionic Liquids: [Cnmim][Hgx3], Where N = 3, 4 And X = Cl, Br, Bert Mallick, Andreas Metlen, Mark Nieuwenhuyzen, Robin D. Rogers, Anja V. Mudring
Anja V. Mudring
A series of mercury(II) ionic liquids, [Cnmim][HgX3], where [Cnmim] = n-alkyl-3-methylimidazolium with n = 3, 4 and X = Cl, Br, have been synthesized following two different synthetic approaches, and structurally characterized by means of single-crystal X-ray structure analysis ([C3mim][HgCl3] (1), Cc (No. 9), Z = 4, a = 16.831(4) Å, b = 10.7496(15) Å, c = 7.4661(14) Å, β = 105.97(2)°, V = 1298.7(4) Å3 at 298 K; [C4mim][HgCl3] (2), Cc (No. 9), Z = 4, a = 17.3178(28) Å, b = 10.7410(15) Å, c = 7.4706(14) Å, β = 105.590(13)°, V = 1338.5(4) Å3 at 170 K; [C3mim][HgBr3] …