Mechanical Engineering Commons^™

Modeling Of Chemical-Mechanical Couplings In Solid Oxide Cells And Reliability Analysis, Xinfang Jin

Theses and Dissertations

Solid oxide fuel cell (SOFC) has been well demonstrated as a promising clean energy conversion technology. For practical applications, the SOFC systems should have both good electrochemical performance and high reliability. The SOFCs are usually operated under very aggressive conditions, e.g., high temperatures (600-1000oC) and extremely low oxygen partial pressures (anode electrode). These aggressive operating conditions could lead to a variety of material system degradations, imposing great challenges on meeting lifetime requirement of SOFC commercial applications. It is therefore essential to increase the understanding of fundamental SOFC degradation mechanisms.

The basic structure of SOFCs is a positive electrode-electrolyte-negative electrode (PEN) …

Multi-Physicochemical Modeling Of Solid Oxide Fuel Cells And Electrolyzer Cells, Yuanyuan Xie

Theses and Dissertations

Multi-physicochemical models are developed for solid oxide fuel cells and electrolysis cells. The models describe the complicated transport processes of charge (electron/ion) conservation, mass/species conservation, momentum conservation, and energy conservation. Transport processes are coherently coupled with chemical reforming processes, surface elementary reaction processes, as well as electro-oxidation processes of both hydrogen and carbon monoxide. The models are validated with experimental data and utilized for fundamental mechanism studies of SOFCs fueled with different type of fuels, such as hydrogen, hydrocarbon, e.g., methane, H2S, and their mixtures. The fundamental mechanisms associated with syngas generation using electrolysis cell are also extensively investigated using …