Mechanical Engineering Commons^™

Highly Efficient Electrochemical Reforming Of Ch4/Co2 In A Solid Oxide Electrolyser, Jinhai Lu, Changli Zhu, Changchang Pan, Wenlie Lin, John P. Lemmon, Fanglin Chen, Chunsen Li, Kui Xie

Faculty Publications

Reforming CH₄ into syngas using CO₂ remains a fundamental challenge due to carbon deposition and nanocatalyst instability. We, for the first time, demonstrate highly efficient electrochemical reforming of CH₄/CO₂ to produce syngas in a solid oxide electrolyser with CO₂ electrolysis in the cathode and CH₄ oxidation in the anode. In situ exsolution of an anchored metal/oxide interface on perovskite electrode delivers remarkably enhanced coking resistance and catalyst stability. In situ Fourier transform infrared characterizations combined with first principle calculations disclose the interface activation of CO₂ at a transition state between a CO …