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Full-Text Articles in Mechanical Engineering
Synchrotron X-Ray Diffraction And Piezospectroscopy Used For The Investigation Of Individual Mechanical Effects From Environmental Contaminants And Oxide Layer Undulations In Thermal Barrier Coatings, Sanna Siddiqui
Electronic Theses and Dissertations
The durability of Thermal Barrier Coatings (TBCs) used on the turbine blades of aircraft and power generation engines has been known to be affected by sand particle ingression comprised of Calcium-Magnesium-Alumina-Silicate (CMAS). Previous studies have shown that these effects present themselves through variations in the thermomechanical and thermochemical properties of the coating. This study investigated the impact of CMAS ingression on the Yttria Stabilized Zirconia Topcoat (YSZ) and Thermally Grown Oxide (TGO) strain in sprayed Thermal Barrier Coating (TBC) samples of varying porosity with and without CMAS ingression. In-Situ Synchrotron X-ray Diffraction measurements were taken on the sample under thermal …
Nanocomposite Coating Mechanics Via Piezospectroscopy, Gregory Freihofer
Nanocomposite Coating Mechanics Via Piezospectroscopy, Gregory Freihofer
Electronic Theses and Dissertations
Coatings utilizing the piezospectroscopic (PS) effect of alpha alumina could enable on the fly stress sensing for structural health monitoring applications. While the PS effect has been historically utilized in several applications, here by distributing the photo-luminescent material in nanoparticle form within a matrix, a stress sensing coating is created. Parallel to developing PS coatings for stress sensing, the multi-scale mechanics associated with the observed PS response of nanocomposites and their coatings has been applied to give material property measurements, providing an understanding of particle reinforced composite behavior. Understanding the nanoparticle-coating-substrate mechanics is essential to interpreting the spectral shifts for …
Piezospectroscopic Calibration Of Alumina-Nanocomposites For The Development Of Stress-Sensing Structures, Daniela Fugon-Dessources
Piezospectroscopic Calibration Of Alumina-Nanocomposites For The Development Of Stress-Sensing Structures, Daniela Fugon-Dessources
Electronic Theses and Dissertations
Alpha-alumina is known to exhibit photo-luminescent (PL) properties, mainly characteristic R-lines that shift according to applied stress. In addition to showing excellent PL properties, polymers with embedded alumina nanoparticles have been shown to improve the overall composite mechanical properties. While the use of the PL properties to develop stress-sensing materials using an alumina-epoxy material has been success- fully shown in compression, the properties have not been developed for tension. In this study, the PL response of variable volume fraction alumina-epoxy composites will be determined under tensile conditions. It is expected that increasing the volume fraction of alumina nanoparticles will increase …
Low Strain Rate Studies Of Alumina Epoxy Composites Using Piezospectroscopy, Ashley Jones
Low Strain Rate Studies Of Alumina Epoxy Composites Using Piezospectroscopy, Ashley Jones
Electronic Theses and Dissertations
Particulate composites are widely used in many aerospace and military applications as energetic materials, armor materials or coatings and their behavior under dynamic loads have gained increasing significance. The addition of modifiers such as alumina nanoparticles generally facilitates the improvement of the mechanical strength to density ratio due to high specific area and particle rigidity. This allows for sufficient particlematrix bonding and therefore improved stiffness and load transfer in the composite. Photo-luminescent α-alumina nanoparticles when embedded in an epoxy matrix allow for the added benefit of in situ measurements at low strain rates to provide stress-sensitive information using the particle …